ISSN:
0025-116X
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Poly(1,4-phenylenevinylene) was obtained by reacting dibromoarenes with ethylene in a palladium-catalyzed reaction. Defects of the polymer structure were elucidated by model reactions. Side reactions in the reaction of halogenated arenes and ethylene or styrene, catalyzed by Pd, could be minimized by low catalyst concentrations and low reaction temperatures. The Pdcatalyzed reaction of aroyl chlorides with ethylene or styrene was probed by model reactions.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/macp.1990.021910511
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