ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The crystal structure of the title compound, tris(1,10-phenanthroline-N,N′)iron(II) bis[1,2-benzisothiazol-3(2H)-onate 1,1-dioxide] 1,2-benzisothiazol-3(2H)-one 1,1-dioxide hexahydrate, [Fe(C12H8N2)3](C7H4NO3S)2·C7H5NO3S·6H2O, at 120 K consists of slightly distorted octahedral [Fe(phen)3]2+ cations (phen is 1,10-phenanthroline), two saccharinate anions and a free saccharin molecule, as well as six waters of crystallization. The compound has been confirmed as diamagnetic low-spin iron(II) by magnetic measurements. There is extensive hydrogen bonding leading to a three-dimensional network.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270100013093
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