ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Crystal Structure of Dichloromethylsulfonium-hexafluoroarsenateDichloromethylsulfonium-hexafluoroarsenate crystallized in the monoclinic space group P21/c with a = 867.5(9) pm, b = 792.7(5) pm, c = 1200.8(10) pm, β = 96.99(8)°, Z = 4. A distorted octahedral coordination around sulfur is formed by three short interionic sulfur-fluorine contacts. In addition chlorine-fluorine contacts are observed in the solid.
Notes:
Dichlormethylsulfonium-hexafluoroarsenat kristallisiert in der monoklinen Raumgruppe P21/c mit a = 867,5(9) pm, b = 792,7(5) pm, c = 1200,8(10) pm, β = 96,99(8)°, Z = 4. Durch drei kurze interionische Schwefel-Fluor-Kontakte ergibt sich eine verzerrt oktaedrische Koordination am Schwefel. Weiterhin werden im Festkörper Chlor-Fluor-Kontakte beobachtet.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19905800114
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