ISSN:
1042-7163
Keywords:
Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Upon irradiation, 9-anthrylmethyl phosphite (2) undergoes the photo-Arbuzov rearrangement to give the corresponding phosphonate 3. Prolonged irradiation led to the clean formation of the centrosymmetric, head to tail, [4 + 4] photocycloaddition product 4 as indicated by X-ray crystallographic analysis. The same photodimer results on irradiation of phosphonate 3 itself in solution or in the solid phase. Phosphite 2 does not undergo photodimerization to 6. © 1998 John Wiley & Sons, Inc. Heteroatom Chem 9:155-160, 1998
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
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