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  • 1
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Surface Science 70 (1978), S. 566-577 
    ISSN: 0039-6028
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 8 (1997), S. 213-219 
    ISSN: 1573-4838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Technology
    Notes: Abstract Hydroxyapatite powders were prepared by a chemical precipitation method and electrophoretically deposited on Ti6Al4V surgical alloy substrates. The powders were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), particle size distribution and zeta potential measurements. Prior to electrophoretic deposition, anodic films were obtained on Ti6Al4V and studied by the Auger method. It was established that experimental conditions of powder preparation, electric field and stirring have a significant influence on suspension stability and deposit morphology. The deposition yield was studied at various deposition durations and applied voltages. Sintered coatings were studied by SEM and XRD.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 32 (1997), S. 389-400 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Aqueous solutions of xAl(NO3)3+(1−x)ZrO(NO3)2 were used for electrodeposition of ceramic Al2O3–ZrO2 composite on TiC, TiB2 and SiC sunstrates. The weight of the deposit was studied versus the duration of deposition, the current density and the temperature of the bath for Al-rich (x=0.9), Zr-rich (x=0.4) and eutectic (x=0.75) electrolyte compositions. Optimal current densities and durations of deposition were determined to obtain maxima weights of deposits. Amorphous deposits with thicknesses up to 10 μm were formed. The microstructure and microchemical composition of the as-deposited and sintered deposits were characterized. Increase in the temperature of the bath inhibited microcracking due to shrinkage during drying. Coated TiC substrates exhibited enhanced oxidation resistance in air at 1100°C.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 33 (1998), S. 699-705 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Cathodic electrosynthesis of zirconium, lanthanum and lead oxides was performed from aqueous solutions of ZrOCl2 · 8H2O, La(NO3)3 · 6H2O and Pb(NO3)2, respectively. The deposits were characterized by X-ray diffraction, thermogravimetric and differential thermal analyses. Crystallite sizes of zirconia were derived at different temperatures from X-ray broadening data. The influence of hydrogen peroxide on the electrosynthesis process, crystallization and phase evolution of deposits has been studied. A possible mechanism of electrosynthesis and the role of hydrogen peroxide are discussed.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 32 (1997), S. 5205-5213 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Aqueous solutions of xAl(NO3)3+(1−x)Cr(NO3)3 were used for electrodeposition of ceramic Al2O3–Cr2O3 alloy coatings on TiC, TiB2 and SiC substrates. Cell voltage and deposit weight were studied as function of deposition duration, current density and electrolyte composition. It was shown that the electrochemical parameters permit simple control of the deposition process. Optimal current densities and deposition durations were determined to obtain maximal deposit weights for different solutions and substrates. Deposits with thicknesses up to 10 μm were formed. The green deposits revealed a crystalline nature for compositions of 〈 0.3, and an amorphous nature for x≥0.3, independent of the substrate material. Voltage–electrolyte composition dependencies exhibited an ubiquitous minimum at x≈0.3 to 0.4 independent of substrate type and deposition duration. These minima were attributed to the change in the electrical resistance of the deposit with composition and degree of crystallinity.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 30 (1995), S. 5307-5312 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The preparation of films of TiO2, ZrO2 and PbZrO3 by electrodeposition from N,N-dimethylformamide solution, has been performed. A new method of cathodic electrodeposition of ceramic films via peroxoprecursors has been proposed and demonstrated on the deposition of TiO2. The effect of thermal treatment on the phase content of the obtained films and the influence of the solvent used on the deposition process and film morphology were studied.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 29 (1994), S. 6241-6248 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract SiC was electrochemically coated with ZrO2 and with Al2O3 from 0.1 m aqueous solutions of metal-nitrate-hydrates with ethanol added. Amorphous zirconia and alumina coatings were formed with current densities from 10 to 70 mA cm−2, and deposition durations of 1–60 min. The as-deposited coatings contained microcracks caused by drying shrinkage. Sintering of zirconia at 900 °C for 1 h and of alumina at 1200 °C for 2 h in air was accompanied by crystallization to a mixture of tetragonal and monoclinic phases in the former and to α-alumina in the latter. The absence of intermediate phases between the coatings and the substrates and the good adherence of the sintered coatings indicate the high-temperature stability of these coatings.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 13 (1994), S. 487-490 
    ISSN: 1573-4811
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 32 (1997), S. 803-807 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A novel method of cathodic deposition of complex oxide compounds has been demonstrated on the deposition of ferroelectric PZT films. In the proposed approach, PZT film formation on graphite and carbon fibre mat substrates was achieved via a peroxoprecursor. It was established that the atomic ratio of lead, zirconium and titanium in the deposit closely corresponded to that in the starting solutions. Formation of a perovskite PZT phase was observed at 500°C. By variation of current density and deposition time the amount of the deposited material could be controlled. It was established that films obtained from solutions with hydrogen peroxide as an additive showed less tendency to crack.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 14 (1995), S. 807-810 
    ISSN: 1573-4811
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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