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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 117 (1984), S. 2275-2286 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Electron Rich Heterocycles as Donor Groups in Fluorescent DyesThe synthesis of N-methylphthalimides substituted with the donor groups pyrazole, triazole, benzotriazole, and naphthotriazole in position 4 is described (17, 18, 14, 12). The substituent constants of these groups are obtained by alkaline hydrolysis of the corresponding phthalimide dyes. Their solvatochromism in absorption and fluorescence gives information about charge distribution in ground- and excited state.
    Notes: Die Darstellung von N-Methylphtalimiden wird beschrieben, die in 4-Stellung die Donorgruppen Pyrazol, Triazol, Benzotriazol und Naphthotriazol tragen (17, 18, 14, 12). über die alkalische Hydrolyse des Imids werden die Substituentenkonstanten der Reste bestimmt. Die Solvatochromie in Absorption und Fluoreszenz gibt Information über die Ladungsverteilung in Grund- und angeregtem Zustand.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 191 (1990), S. 1957-1965 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The microorganism Pseudomonas oleovorans is known to produce polyesters containing 3-hydroxyalkanoate units when grown on n-alkanes and n-alkanoic acids under nutrient limiting conditions, but when 5-phenylvaleric acid was supplied as the only carbon source, poly[3-hydroxy-5-phenylpentanoate], a polyester with a phenyl pendant group, was produced. The optimum substrate concentrations and harvesting times were determined by measuring the change of cell growth and polymer yield during the growth. A 12-L cell culture yielded 222,5 mg polymer/L and 25% polymer per cellular dry weight. This bacterial polymer showed an optical rotation of [α]D25 = -24,5° ± 0,2°. The structure was corroborated by 1H NMR and 13C NMR spectroscopy. The composition of the polymer was also determined by methanolysis to the methyl ester of the repeating unit, which was subsequently analyzed by GC. By this procedure the polyester was found to be a homopolymer to the extent of at least 99%. The polyester has a glass transition at 13°C, a melting range from 54 to 69°C, and a weight-average molecular weight of M̄w = 350000 with a polydispersity M̄w/M̄n of 3,5, as determined by GPC relative to polystyrene standards.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Publication Date: 1988-01-01
    Print ISSN: 0040-4039
    Electronic ISSN: 1873-3581
    Topics: Chemistry and Pharmacology
    Published by Elsevier
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