ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Electronic Resource
    Electronic Resource
    Laboratory measurement of the permanent electric dipole moment of gas-phase CuO in its X 2Π state (1987)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 87 (1987), S. 5670-5673 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A sub-Doppler optical Stark measurement of the P1(1.5) branch feature of the A 2Σ−(v′=0)–X 2Π3/2(v″=0) subband system of gas phase copper monoxide, CuO, has been performed. The observed Stark shifts have been analyzed and a permanent electric dipole moment of 4.45±0.30 D (1σ error estimate) for the X 2Π3/2 state determined. The results are discussed in terms of the various bonding models proposed for CuO.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.453541
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    An analysis of the A˜ 2Π–X˜ 2Σ+ band system of isotopically substituted calcium isocyanide CaNC (1994)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 101 (1994), S. 7255-7261 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The strong visible band systems of a supersonic molecular beam sample of isotopically substituted CaNC (13C and 15N individually) have been recorded at high resolution by laser-induced fluorescence spectroscopy. The spectra have the general appearance of the expected A˜ 2Π–X˜ 2Σ+ band systems, but the energy levels of both the ||Ω||=1/2 and 3/2 excited substates have localized perturbations. Spectroscopic parameters for the X˜ 2Σ+ state of the isotopomers were extracted from a least-squares fit to the appropriate combinations differences of the observed transitions frequencies. Excited state effective parameters were extracted by directly fitting the unperturbed portions of the optical spectra. The rs-structure bond lengths for the ground electronic state were determined to be Ca–N=2.2065(58) A(ring) and N–C=1.1186(58) A(ring). The permanent electric dipole moments for the Ca15NC isotopomer were determined to be 5.93(8) and 6.69(9) D for the A˜ 2Π and X˜ 2Σ+ states, respectively.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.468283
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 3
    Electronic Resource
    Electronic Resource
    A hierarchical response to differences in ration size in the reproductive performance of female three-spined sticklebacks (1995)
    Oxford, UK : Blackwell Publishing Ltd
    Journal of fish biology 46 (1995), S. 0 
    Details
    ISSN: 1095-8649
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology
    Notes: The response of female three-spined sticklebacks (Gasterosteus aculeatus) to differences in food ration during the breeding season was quantified for several variables related to reproductive performance. The measured protein and lipid contents (mg g−1) of eggs were unaffected by ration. Egg size increased with an increase in both ration and female size, but the proportional increase in egg size was much smaller than the proportional increase in ration. The best predictor of mean batch (clutch) fecundity and weight was female size. There was a small but significant increase in batch fecundity with ration, but the increase was not directly proportional to the increase in ration. The rate of spawning, total breeding season fecundity and total weight of eggs spawned over the breeding season were sensitive to ration with breeding season fecundity and weight increasing in direct proportion to ration. Thus, in female sticklebacks, there is a hierarchy of sensitivity to ration in the response of variables related to reproduction.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1111/j.1095-8649.1995.tb01102.x
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 4
    Electronic Resource
    Electronic Resource
    Millimeter-wave spectroscopy of vibrationally excited ground state alkaline-earth hydroxide radicals (X 2Σ+) (1995)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 102 (1995), S. 4334-4339 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Pure rotational spectra of the alkaline-earth monohydroxides have been recorded for vibrationally excited states (0 1 0), (0 2 0), (0 3 0), and (1 0 0) of the ground electronic state (X 2Σ+) using millimeter-wave absorption spectroscopy. The radicals MgOH, CaOH, SrOH, and BaOH were studied. The data for CaOH, SrOH, and BaOH were analyzed with a linear 2Σ+ model, but with the addition of two terms to account for contamination of the v2=1 2Π and v2=2 2Δ vibronic levels with 2Π and 2Δ electronic states. The data for MgOH, however, did not fit well to this linear model and is additional evidence that this species is quasilinear. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.469482
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 5
    Electronic Resource
    Electronic Resource
    Erratum: "Molecular beam optical Stark spectroscopy of MoN" [J. Chem. Phys. 99, 901 (1993)] (1998)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 108 (1998), S. 10327-10327 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.476493
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 6
    Electronic Resource
    Electronic Resource
    Molecular beam optical Stark spectroscopy of MoN (1993)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 99 (1993), S. 901-905 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A high resolution optical spectroscopic study of a molybdenum mononitride, MoN, supersonic molecular beam sample has been performed. The Ree (0.5) branch feature of the (0,0) A 4Π3/2–X 4Σ1/2− band system for 98MoN was recorded as a function of static electric field strengths of up to 3.5 kV/cm. The splittings and shifts were analyzed to produce values of the permanent electric dipole moment of 4.56(9) and 3.38(7)D for the A 4Π3/2 and X 4Σ1/2− states, respectively. The field free splittings for the95MoN and 97MoN isotopic forms were interpreted as arising from X 4Σ1/2− magnetic hyperfine effects and the resulting spin density of 5.09(8) a.u.−3 was determined. Comparisons with predictions from theoretical models are given.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.466232
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 7
    Electronic Resource
    Electronic Resource
    The permanent electric dipole moment of NbN (1993)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 99 (1993), S. 9324-9325 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A high resolution optical Stark study of a niobium nitride (NbN) supersonic molecular beam sample has been performed. The F'=2.5–F‘=3.5 hyperfine component of the R(1) branch feature of the (0,0) B 3F2–X 3D1 subband system was recorded as a function of static electric field strengths up to 2.7 kV/cm. The permanent electric dipole moment of 3.26(6) D and 4.42(9) D for the X 3D1 and B 3F2 states, respectively. The properties of the X 3D1 state were calculated ab initio using a complete active space multiconfiguration self-consistent-field approach followed by first-order configuration interactions plus multireference singles+doubles configuration interaction treatment. The calculated dipole moment for the X 3D1 state at the experimentally determined equilibrium bond distance is 3.65 D.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.465503
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 8
    Electronic Resource
    Electronic Resource
    Molecular beam pump/probe microwave-optical double resonance using a laser ablation source (1993)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 98 (1993), S. 1837-1842 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The first successful pump/probe microwave-optical double resonance experiment using a laser ablation/reaction scheme for molecular beam production has been performed. Pure rotational transitions at frequencies up to 52 GHz have been recorded for the transient refractory compounds YF, YO, and SrOH at a resolution of 〈30 kHz [full-width at half- maximum (FWHM)]. The observed three lowest pure rotational transition frequencies of YF (X 1Σ+) were analyzed to produce an improved set of rotational constants, B=8683.6156(11) MHz and D=0.007 521(74) MHz. The three lowest pure rotational transitions of SrOH (X 2Σ+) were analyzed to give the spectroscopic parameters (in MHz), B=7470.8180(4), D=0.006 25(3), γ=72.706(1), γD=−0.0021(2); bF (H)=1.713(2) and c (H)=1.673(5). The proton magnetic hyperfine interactions were interpreted in terms of a molecular orbital description for the X 2Σ+ state.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.464218
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 9
    Electronic Resource
    Electronic Resource
    Hyperfine interactions in the ground states of titanium monoxide and mononitride (1993)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 99 (1993), S. 4288-4299 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A comparative study of the hyperfine interactions in the X 2Σ+ state of TiN and the X 3Δ state of TiO has been performed. The 48Ti14N(I=1) hyperfine structure was determined from the analysis of 19 components of the N=1–0 and N=2–1 pure rotational transitions recorded using the pump/probe microwave-optical double resonance technique. The 47Ti(I=5/2) hyperfine structure of X 2Σ+ TiN was determined from an analysis of the high resolution optical spectrum of the (0,0) A 2Π3/2–X 2Σ+ band system. The resulting parameters are (in MHz) B(48Ti14N)=18 589.3513(13), D(48Ti14N)=0.026 31(18), γ(48Ti14N)=−52.2070(13), bF(N)=18.480(3), c(N)=0.166(7), eQq0(N)=−1.514(8), CI(N)=0.0137(12), bF(47Ti) =−558.8(11), c(47Ti)=−15(5), and eQq0(47Ti)=62(16). An analysis of the (0,0) band of the B 3Π–X 3Δ system of 47Ti16O produced the X 3Δ hyperfine parameters (in MHz): a(47Ti) =−54.7(21), (bF+2c/3)(47Ti)=−231.6(60), and eQq0(47Ti)=−49(31). An interpretation based upon the predicted nature of the bonding in TiO and TiN is given.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.466082
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 10
    Electronic Resource
    Electronic Resource
    A supersonic molecular beam optical Stark study of CaOH and SrOH (1992)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 96 (1992), S. 2556-2564 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The permanent electric dipole moments of CaOH and SrOH in their X 2Σ+, A 2Π3/2, A 2Π1/2, and B 2Σ+ states have been measured using the technique of supersonic molecular beam optical Stark spectroscopy. For CaOH the values obtained were μ(X 2Σ+)=1.465(61)D, μ(A 2Π1/2)=0.836(32)D, μ(A 2Π3/2)=0.766(24)D, and μ(B 2Σ+)=0.744(84)D, while for SrOH the values were μ(X 2Σ+)=1.900(14)D, μ(A 2Π1/2)=0.590(45)D, μ(A 2Π3/2)=0.424(5)D, and μ(B 2Σ+)=0.396(61)D. The results are compared with values from a recent ab initio calculation for CaOH and with the predictions of a semiempirical electrostatic polarization model.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.462007
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...