ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The CuI atom in the title complex, [Cu(NH2SO3)2(C3H8N)(H2O)], is coordinated by the C=C bond of the allylammonium cation, two N atoms of the sulfamate anions and the O atom of the H2O molecule in the apical position. Thus, the central atom is in a distorted trigonal–pyramidal environment. Strong N—H...O and O—H...O contacts connect separate moieties of the complex into a three-dimensional framework. The title compound is representative of hitherto unknown copper(I)–sulfamate π-complexes.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270100016218
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