ISSN:
0749-1581
Keywords:
11B NMR
;
One-bond 11B, 14N coupling
;
BXn(NCS)4-n- (X = Cl, F; n = 1, 2, 3)
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The reaction B(NCS)4- + BX4- (X = F, Cl, Br) leads to mixed BXn(NCS)4-n- (n = 1, 2, 3) species easily detected in solution by 11B NMR. Further, with X = Cl, 1J(11B, 14N) values could be measured from the 11B NMR spectra (25.6, 24.5 and 21.4 Hz for n = 3, 2 and 1, respectively). For X = F, the relevant 1J(11B, 14N) values (24.3, 25.2 and 28 Hz for n = 3, 2 and 1, respectively) increase in the same order as the related 1J(11B, 19F) (5.5, 12.7 and 20.0 Hz, respectively). No such 1J(11B, 14N) could be resolved for X = Br.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260280807
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