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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 20 (1982), S. 3271-3283 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A commercially available densimeter with a vibrating stainless steel tube was used as a detector in the GPC analysis of styrene/methyl methacrylate copolymers under normal GPC operational conditions. The densimeter was thermostated to ±0.001°C and sample injection concentrations were 4.0 mg/mL. The copolymer samples were polydisperse in molecular weight but uniform in composition. A refractive index detector and the densimeter detector produced comparable estimates of the parameters of the molecular weight distributions. The densimeter is less sensitive to the effects of variations in copolymer composition than differential refractive index or ultraviolet detectors. The only serious drawback to the densimeter is a relative lack of sensitivity. Variations in composition of styrene/methyl methacrylate copolymers over a fairly wide range have no signficant effect on the relation between gel permeation chromatographic elution volume and copolymer molecular weight. In general, however, conventional means of summarizing these data are not applicable to compositionally heterogeneous mixtures. Instrumental and data-handling solutions to this problem are discussed.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 19 (1981), S. 483-493 
    ISSN: 0360-6384
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 21 (1983), S. 1557-1557 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 2 (1974), S. 593-607 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Raman spectra of neat liquid cis-2-butene and cis-2-butene-benzene mixtures, covering the accessible composition range at 20°C and atomospheric pressure, have been obtained. Parameters of the benzene bands at 605.6, 1178 and 991.6 cm-1 and cis-2-butene bands at 395.5, 871.5 and 1660 cm-1 are reported. Changes in the parameters as a function of concentration are interpreted in terms of a weak dipole-induced dipole interaction and the consequent effect on rotational motions and resonance energy transfer.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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