ISSN:
0098-1273
Keywords:
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Quantitative comparison of previously published NMR spin-relaxation data for polydiethylsiloxane with theoretical predictions for a variety of motional processes allowed both the nature and time scale of molecular motions to be identified. At the lowest temperatures, methyl reorientation produced a T1 minimum and was found to proceed with an activation energy of 2.4 kcal/mole in both amorphous and crystalline phases. Reorientation of the ethyl groups in the amorphous phase was observed at a higher temperature with an activation energy of 9.3 kcal/mole. Relaxation in the melting region was influenced by flexing and stretching of the helical polymer chain. The maximum angular displacement of the chain was estimated to be 24°, with an activation energy for this process of 2.6 kcal/mole.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1980.180180205
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