ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
DF-CL studies using NO2 chemiluminescence detection of O yielded a rate constant k1 for O + SiH4 of (2.6 ± 0.5)×10-13 cm3 s-1 at 295 K, where the 95% confidence interval reflects accuracy. FP-RF studies using flash photolysis of SO2 followed by time-resolved vuv fluorescence detection of O at 295 K yielded k1 = (3.0 ± 0.5) ×10-13 cm3 s-1. These results are in good accord with most previous measurements and lead to a combined best estimate of k1 = (3.2 ± 0.4) × 10-13 cm3 s-1. The DF-CL and FP-RF methods appear to have little unrecognized systematic error. © 1993 John Wiley & Sons, Inc.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550250306
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