ALBERT

Notes: Abstract The quartz-fuchsite vein at the Dome mine, Timmins area, Canada, is characterized by a consistent spatial association of gold and galena. A lead isotope study was carried out to trace the source of the lead in the galenas, and to evaluate possible source reservoirs for the gold. Although other sources cannot be entirely ruled out, the lead isotope composition of most of the galenas and of local quartz-feldspar porphyries suggests that most of the lead in the vein-galenas was derived from the Dome mine porphyries. However, lead isotope systematics do not allow unique constraints to be placed on the gold source. Conceptual genetic models commonly advocate gold source reservoirs such as shallow to deep seated igneous intrusions, the middle to lower crust or the mantle for Archean lode gold deposits. A likely scenario is that ore-bearing hydrothermal fluids originated at depth, and were preferentially channeled along the porphyries to the site of ore deposition. The hydrothermal fluids leached lead from the porphyries, and deposited gold and galena together in the quartz-fuchsite vein. Two galena samples have “anomalous” lead compositions and are colinear with the main galena cluster suggesting one or more contamination episodes, broadly between 1250 and 2480 Ma, resulting in further addition of radiogenic lead to the galenas.

Notes: [Auszug] Cerium undergoes fractionation in the marine environment relative to the other rare-earth elements, such that it undergoes relative depletion in deep ocean water and pelagic sediment, but enrichment in ocean-floor manganese nodules8. This fractionation is attributed to the removal of dissolved ...

Notes: [Auszug] Physical determinations of the La decay constants are hampered by the very low abundance of the radioactive isotope, the long half-life, and the difficulty of making accurate measurements on low-energy particles. Thus early values, particularly for the ft-decay branch, are variable. Nevertheless, a ...

Notes: [Auszug] Rock samples were collected from sea cliffs at Portnahaven (PHI and PH2) and at Port Wemyss (PW1, PW2 and PW3) (Fig. 1); these consist of fine- to medium-grained alkali feldspar, plagioclase, quartz, hornblende, chlorite, biotite and muscovite. PW2 is a highly altered sample and contains very ...

Notes: [Auszug] Fractures which formed fluid conduits for the Skye hydro-thermal system have been plugged by secondary mineral growth, and now form veins which cut through the rocks. The analysed sample is cut by such a hydrothermal vein, and comes from near the centre of an acid/basic composite sill. This was ...

Notes: [Auszug] Corals record only the highest sea stands; speleothem complement the coral record in that they record a much larger fraction of the total range of sea level. Coral has the advantages of high U content (approximately 3 p.p.m.), easy recognition of alteration of the primary aragonite to calcite, and ...

Notes: Abstract Products of Pliocene (2–4 Ma) mafic to intermediate volcanism in the northwestern Cerros del Rio, a dominantly mafic volcanic field in the Española Basin of the Rio Grande Rift (RGR), range from 49% to 63% SiO2 and exhibit diversity in silica saturation, trace-element patterns, and isotopic compositions. Tholeiites, which are largely confined to west of the Rio Grande, have trace-element abundances that resemble those of oceanic basalts, but with mild depletions in Nb and Ta, and high 87Sr/86Sr, low 143Nd/144Nd, and high δ18O compared to typical OIB. They are regarded as asthenospherically-derived magmas contaminated with continental crust. Alkali basalts and hawaiites erupted from vents east of the Rio Grande are geochemically distinct, having generally higher overall incompatible-element abundances, but with pronounced depletions in K, Rb, Nb and Ta with respect to Th and LREE. Spatially-associated benmoreites, mugearites and latites (collectively termed “evolved” lavas) have similar trace-element characteristics to the mafic mildly-alkaline compositions, but are typically not as depleted in K. Hawaiites and evolved lavas exhibit a good negative correlation of 143Nd/144Nd with SiO2, due to interaction with lower continental crust. The most silicic “evolved” lavas carry the highest proportions of crustal material, and consequently have higher K/Th than the related hawaiites. Several (mostly mafic) lavas contain abundant crustally-derived resorbed quartz xenocrysts in O-isotope disequilibrium with the host magma. The δ18O values of xenocrystic quartz range over 4‰, indicating a variety of quartz-bearing crustal contaminants beneath the Española Basin. The hawaiites, with their unusual combination of trace-element enrichments and depletions, cannot be generated by any process of fractionation or crustal contamination superposed on a common mantle source type (oceanic or arc-source). It is a regional mantle source type, inasmuch as it was also present beneath NW Colorado during the mid-late Cenozoic. We argue that the hawaiite source must have originally existed as arc-source mantle enriched in LILE, generated during Mesozoic to early Cenozoic subduction at the western margin of North America. This arc-source mantle lost K, Rb and Ba, but not Th or LREE, prior to magmagenesis. Selective element loss may have occurred during lithospheric thinning and uprise of hydrated phlogopitebearing peridotite-possibly as a thermal boundary layer between lithosphere and asthenosphere — to shallow mantle depths, with consequent conversion of phlogopite to amphibole (an inferior host for K, Rb and Ba). We suggest that this occurred during the early extensional phase of the northern RGR. Further extension was accompanied by partial melting and release of magma from this source and the underlying asthenosphere, which by the Pliocene was of oceanic type. The hawaiite source mantle is the product of a long history of subduction succeeded by lithospheric extension of the formerly overriding plate. Similar chemical signatures may have developed in the mantle beneath other regions with comparable histories.

Notes: Abstract One of the major puzzles presented by the geochemistry of the Palaeocene plateau lavas of Skye and Mull (N.W. Scotland) is that, although a very strong case can be made that the magmas are variably isotopically contaminated by Archaean Lewisian continental crust, little evidence has been gleaned to date from their major- and trace-element compositions to illuminate this hypothetical process. The combined results of published Sr-, Nd- and Pb-isotope studies of these lavas allow the basalts and hawaiites to be divided into three broad groups: essentially uncontaminated; contaminated with granulite-facies Archaean crust; contaminated with amphibolite-facies Archaean crust. Members of each group show distinctive chondrite-normalised incompatible-element patterns. The processes which gave rise to isotopic contamination of these lavas also affected the abundances and ratios of Ba, Rb, Th, K, Sr and light REE in the magmas, whilst having negligible effects on their abundances and ratios of Nb, Ta, P, Zr, Hf, Ti, Y and middle-heavy REE. Because such a wide range of elements were affected by the contamination process, it is postulated that the contaminant was a silicate melt of one or more distinctive crustal rock types, rather than an aqueous or similar fluid causing selective elemental movements from wall rocks into the magmas. As previous experimental and isotopic studies have shown that the Skye and Mull basic magmas were not constrained by cotectic equilibria at the time when they interacted with sial, the compositions of the contaminated lavas have been modelled in terms of simple magma-crust mixtures. Very close approximations to both the abundances and ratios of incompatible elements in the two groups of contaminated basalts may be obtained by adding 15% to 20% of Lewisian leucogneisses to uncontaminated Palaeocene basalt. Nevertheless, major-element constraints suggest that the maximum amount of granitic contaminant which has been added to these magmas lies between 5% and 10%. These estimates may be reconciled by postulating that the contaminants were large-fraction cotectic partial melts of Lewisian leucogneisses, leaving plagioclase residua. A corollary of this hypothesis is that it is necessary to postulate that the “magma chambers” where the sialic contamination occurred were, in fact, dykes or (more probably) sills. The very large surface-to-volume ratios of such magmas bodies would permit the systematic stripping, by partial melting, of the most-easily-fusible leucogneisses and pegmatites from the Lewisian crust, whilst failing to melt its major rock types. A present-day analogue to this situation may be the extensive sill-like magma bodies detected by geophysical methods within the continental crust beneath the Rio Grande Rift, southwestern U.S.A.

Notes: Abstract In Sconser quarry, Isle of Skye, a thin Tertiary basic sill is cut by vertical veins which formed fluid conduits in a major meteoric-hydrothermal system. In order to study the relative mobility of different elements during hydrothermal metamorphism, sill material adjacent to a large (6 mm wide) vein was cut into slices and subjected to geochemical and isotopic analysis. Isotopic evidence indicates that the basic magma which formed the sill was contaminated by Lewisian (Archaean) gneisses at depth, while material from Torridonian (Proterozoic) sandstone country rocks was introduced by hydrothermal fluids after crystallisation. The behaviour of the different elements during hydrothermal metamorphism divides them into 4 groups. 1. Large-ion low-charge elements Ba, K, Rb and Cs were strongly leached from the wall rock in the vicinity of the vein. 2. Other elements including Sr and Pb were depleted near the vein, but isotopic evidence indicates addition of some material from the fluids. This two-way nuclide transport forms an exchange process. 3. Many high-field-strength elements including the REE are slightly enriched near the vein, but Nd isotope evidence reveals no addition of material from fluids. These elements must have been relatively enriched by the removal of other elements (mainly Si and Al). 4. Ca and Na were added to the wall rock from fluid. The variable mobility of these elements is explained by the differing ease with which they could be incorporated into a new albite-calcite-chlorite-epidote mineralogy. The constitution of this hydrothermal mineralogy was largely determined by the primary igneous mineralogy, though the composition of hydrothermal fluids had a subordinate influence.