ISSN:
1588-2780
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Energy, Environment Protection, Nuclear Power Engineering
Notes:
Abstract Rate constants for the reaction of the primary species of water radiolysis, viz. e aq' − , H and OH, with picolinic acid have been determined at various pHs. The semi-reduced species exhibits λmax at 305 and 350 nm. It is a strong reductant and has two pKa values of 1 and 5.7. The OH adduct of this compound also exhibits two pKa s at 2.1 and 5.2. H-atom reaction with picolinic acid gives rise to a mixture of species.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02034813
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