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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of organic chemistry 16 (1951), S. 1405-1413 
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 76 (1954), S. 4970-4974 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 73 (1951), S. 2590-2594 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 74 (1952), S. 1109-1109 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry research 28 (1989), S. 785-793 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry research 29 (1990), S. 1894-1900 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY : American Institute of Physics (AIP)
    Physics of Fluids 5 (1993), S. 1602-1613 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The interaction and coalescence of small spherical drops in dilute, homogeneous dispersions are considered theoretically under conditions, where drop motion results from gravity settling and thermocapillary migration acting simultaneously. A trajectory analysis is used to predict pairwise collision rates, and population dynamics equations are solved to predict the time evolution of the droplet size distribution. The rate of droplet collisions and growth may be reduced dramatically by antiparallel alignment of the gravitational and thermocapillary velocities. For such antiparallel alignment with the gravitational relative velocity exceeding the thermocapillary relative velocity for two widely separated drops, there is a "collision-forbidden region'' in parameter space. This occurs because the gravitational relative velocity decays more rapidly with decreasing separation distance between the drops than does the thermocapillary relative velocity, and so the resultant relative velocity along the line-of-centers from these two sources combined becomes zero at a finite separation and the drops are unable to collide. As a result, small drops which initially collide and coalesce due to thermocapillary motion will only grow until they reach a critical size for which the oppositely directed gravitational motion balances the thermocapillary motion.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Fluids 31 (1988), S. 1324-1329 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Experiments were performed in order to delineate the conditions under which small metal and plastic spheres rebound, as opposed to stick, when dropped upon a smooth quartz surface overlaid with a thin layer of a viscous fluid. The parameters that were varied include the fluid layer thickness and viscosity, and the ball size, density, and elastic properties. The minimum drop height that allowed the ball to rebound out of the fluid layer was determined. The results are in very good agreement with the recent elastohydrodynamic theory of Davis et al. [J. Fluid Mech. 163, 479 (1986)]. Additional experiments were performed for which the quartz surface was made artificially rough by adhering fine glass spheres to it. For these experiments, the resistance to rebound caused by the fluid layer was significantly reduced, in close agreement with the recent theory for rough surfaces developed by Davis [Phys. Chem. Hydro. 9, 41 (1987)].
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Fluids 13 (2001), S. 1178-1190 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A trajectory analysis is used to determine the effect of small deformations and van der Waals attractions on the collision efficiency of two non-Brownian drops freely suspended in a linear flow at small Reynolds number. Simple shear flow and uniaxial compressional and extensional flow are considered. Treating the capillary number (Ca) as a small parameter permits an approach similar to matched asymptotic expansions. For Ca(very-much-less-than)1, the analysis shows that the deformation is mainly axisymmetric and that the tangential motion of the drops in apparent contact is unaffected to leading order by the small deformation. A comparison with full three-dimensional boundary-integral calculations confirms the accuracy of the asymptotic approach. In the dimensionless parameter space, results for the collision efficiency are mapped for four parameters: Ca, size ratio, drop-to-medium viscosity ratio, and a dimensionless Hamaker parameter. For spherical drops in uniaxial compression and extension, the collision efficiencies are identical due to the reversibility of Stokes flow. When small deformation is introduced, however, the collision efficiencies are lower for compression than for extension. For slightly deformable drops in simple shear flow, the critical capture cross section upstream is no longer a circle, in contrast to the behavior of spherical drops in the absence of van der Waals forces. For all flow types, a key result is that the collision efficiency decreases rapidly from the corresponding value for spherical drops, as the capillary number increases beyond a critical value, due to small deformations. Consequently, droplet growth by coalescence will be arrested when the drops reach a prescribed size, as shown by population dynamics simulations for a model physical system. © 2001 American Institute of Physics.
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Fluids 11 (1999), S. 1016-1028 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: An axisymmetric boundary-integral method was developed and used to study the interaction of two deformable drops (or bubbles) rising (or settling) due to gravity in a viscous medium under conditions of small Reynolds number. The focus is on cases where the smaller drop trails behind the larger drop. When the Bond number is small, interfacial tension keeps the drops nearly spherical, and they separate with time. At higher Bond numbers, however, deformation is significant and the trailing drop is stretched due to the flow created by the leading drop; it may form one or more necks and break when one of these pinches off. The leading drop is flattened due to the flow created by the trailing drop; it may form a depression on its underside which evolves into a plume that rises through its center. Moreover, at sufficiently high Bond numbers, the larger leading drop does not leave the trailing drop behind, but instead may entrain and engulf it within the depression or plume. Systematic results for the parameter ranges which demarcate impending breakup and coalescence are presented. © 1999 American Institute of Physics.
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