ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary The reactions of TiX4 (X=Cl or Br) with the bidentate ligands, L, (Figure 1), yield hexacoordinate complexes TiX4·L, whereas similar reactions with VOCl3 lead to reduction of vanadium and give rise to vanadium(IV) pentacoordinate complexes, VOCl2·L. All the compounds have been characterized by elemental analyses, i.r., visible and e.p.r. spectra. The occupation of the sixth coordination position in pentacoordinate complexes, VOCl4·L, by different donor solvents, has been studied by means of visible and e.p.r. spectra.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00618584
Permalink