ISSN:
1572-8854
Keywords:
Ruthenium
;
1,4,7-trithiacyclononane
;
sandwich complex
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract The isolation and characterization of [CpRu(9S3)](O3SCF3), where 9S3 = 1,4,7-trithiacyclononane, is reported. The title compound crystallizes in the orthorhombic space group Pbca: a = 10.2542(18), b = 14.8991(13), c = 22.4832(18) Å, and Z = 8. The Ru atom is sandwiched between the π-bound cyclopentadienyl ligand and the 9S3 ligand, bonding to all three of the sulfur atoms in the 9S3. The Ru—S distances are 2.2991(10), 2.2979(11), and 2.3055(10) Å. The C—S distances range from 1.819(4) to 1.852(5) Å in the trithiacyclononane ring.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1009561531985
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