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  • 1
    facet.materialart.12
    [Cham] : Springer
    Call number: 9783319540542 (e-book)
    Description / Table of Contents: Do you know silica, the tetrahedra of silicon and oxygen constituting the crystals of New Agers and the desiccant in a box of new shoes? It's no mere mundane mineral. As chemically reacting silicate rocks, silica set off the chain of events known as the origin of life. As biomineralized opal, it is the cell wall, skeleton, spicules, and scales of organisms ornamenting numerous lobes of the tree of life. Cryptocrystalline silica made into stone tools helped drive the evolution of our hands and our capability for complex grammar, music, and mathematics. As quartz crystals, silica is impressively electric and ubiquitous in modern technology (think sonar, radios, telephones, ultrasound, and cheap but precise watches). Silica is inescapable when we take a drink or mow the lawn and it has already started to save the Earth from the carbon dioxide we're spewing into the atmosphere. This book tells these scientific tales and more, to give dear, modest silica its due.
    Type of Medium: 12
    Pages: 1 Online-Ressource (xi, 201 Seiten) , Illustrationen
    ISBN: 9783319540542 , 978-3-319-54054-2
    Language: English
    Note: Contents 1 A Brief Introduction to the Players 1.1 Silicon 1.2 Silica 1.3 Silicic Acid 1.4 Silicate 1.5 Silicone 2 The Origin of Life Was Brought to You in Part by Silicate Rocks 2.1 Setting the Stage 2.2 A Flight of Fancy 2.3 The Early Earth Was Not Hellacious 2.4 A Fly in the Soup 2.5 The Lost City 2.6 Generating Organic Compounds 2.7 Inventing Metabolism 2.8 The World’s Earliest Biological Carbon Fixation 2.9 Replication Further Reading 3 The Making of Humankind: Silica Lends a Hand (and Maybe a Brain) 3.1 Stone Tools and Their Makers 3.1.1 The Earliest Stone Tools 3.1.2 The Oldowan Industry and Its Practitioners 3.1.3 The Acheulean Industry and Its Practitioners 3.1.4 Neanderthals and the Levallois Technique 3.1.5 Homo sapiens 3.2 Hands and Brains 3.2.1 Give Us a Hand 3.2.2 If I Only Had a Brain Further Reading 4 Mystical Crystals of Silica 4.1 What Is a Crystal? 4.2 Pyroelectricity 4.3 Piezoelectricity 4.4 Sonar 4.5 Quartz Oscillators 4.6 But Why Is There a Piezoelectric Effect? Further Reading 5 Glass Houses and Nanotechnology 5.1 Silica-Centric Musings on the Origin of Biomineralization 5.2 The Early Fossil Record of Silica Biomineralization 5.3 Not All Biomineralization Is Silica Biomineralization 5.4 The World’s First Arms Race 5.5 How to Make a Glass House: Man Versus Nature 5.5.1 Man 5.5.2 Nature 5.6 Some Silica Biomineralizing Organisms that We Are Learning From 5.6.1 Choanoflagellates 5.6.2 Siliceous Sponges 5.6.3 Diatoms 5.7 Siliceous Nanotechnology Further Reading 6 Chicks Need Silica, Too 6.1 It’s All About the Chicks 6.2 Silicosis 6.3 The Dog Days of Silica Medical Research 6.4 Collagen 6.5 Do Human Beings Require Silica? 6.6 To Supplement or not to Supplement 6.7 Silica, Aluminum, and Alzheimer’s Disease Further Reading 7 Of Fields, Phytoliths, and Sewage 7.1 All Plants Have Silica 7.2 Opal Phytoliths 7.3 The Benefits of Opal Phytoliths and of Dissolved Silica 7.4 Is Silica an Essential Plant Nutrient? 7.5 Impact of Agriculture on the Silica Cycle 7.6 The Growing Creep of Silica Removal 7.7 Let’s Go for a Walk Through Time 7.8 Silica in Sewage 7.9 A Plea for Hardy Souls Further Reading 8 Silica, Be Dammed! 8.1 To Put It in a Nutshell 8.2 A Brief History of Human Damming, or How Long Has This Been Going on 8.3 Dams and Silica 8.4 Dams, Eutrophication, and Silica 8.5 Case Study #1: The Laurentian Great Lakes 8.6 Case Study #2: The Baltic Sea 8.7 Case Study #3: The Black Sea 8.8 The Global View Further Reading 9 The Venerable Silica Cycle 9.1 The Silica Cycle 9.2 Silicate Weathering 9.3 Getting Silica from Continent to Ocean 9.4 The Weathering of Oceanic Crust 9.5 Silica Biomineralization in the Ocean 9.6 Silica’s Return to the Mantle 9.7 The Earth’s Early Ocean Was a Tremendously Siliceous Place 9.8 Silica, Cyanobacteria, and Banded Iron Formations 9.9 And then Along Came True Silica Biomineralization Further Reading 10 Silica Saves the Day 10.1 The Goldilocks Zone 10.2 Most of Us Can Model 10.2.1 The Warmth of the Sun 10.2.2 Albedo, Which Is Not a Pasta Sauce 10.2.3 Emissivity 10.3 The Importance of Greenhouse Gases 10.4 Silicate Weathering Consumes Carbon Dioxide 10.5 The Temperature Dependence of Silicate Weathering 10.6 The Paleocene-Eocene Thermal Maximum 10.7 Enhanced Weathering Further Reading
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  • 2
    Publication Date: 2023-06-20
    Description: Coastal waters have strong gradients in dissolved organic matter (DOM) quantity and characteristics, originating from terrestrial inputs and autochthonous production. Enclosed seas with high freshwater input therefore experience high DOM concentrations and gradients from freshwater sources to more saline waters. The brackish Baltic Sea experiences such salinity gradients from east to west and from river mouths to the open sea. Furthermore, the catchment areas of the Baltic Sea are very diverse and vary from sparsely populated northern areas to densely populated southern zones. Coastal systems vary from enclosed or open bays, estuaries, fjords, archipelagos and lagoons where the residence time of DOM at these sites varies and may control the extent to which organic matter is biologically, chemically or physically modified or simply diluted with transport off-shore. Data of DOM with simultaneous measurements of dissolved organic (DO) nitrogen (N), carbon (C) and phosphorus (P) across a range of contrasting coastal systems are scarce. Here we present data from the Roskilde Fjord, Vistula and Öre estuaries and Curonian Lagoon; four coastal systems with large differences in salinity, nutrient concentrations, freshwater inflow and catchment characteristics. The C:N:P ratios of DOM of our data, despite high variability, show site specific significant differences resulting largely from differences residence time. Microbial processes seemed to have minor effects, and only in spring did uptake of DON in the Vistula and Öre estuaries take place and not at the other sites or seasons. Resuspension from sediments impacts bottom waters and the entire shallow water column in the Curonian Lagoon. Finally, our data combined with published data show that land use in the catchments seems to impact the DOC:DON and DOC:DOP ratios of the tributaries most.
    Description: Academy of Sciences of Finland
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: BONUS COCOA and Bundesministerium für Bildung und Forschung
    Description: Academy of Finland
    Description: Danish Research Council for Independent Research
    Description: BONUS COCOA Project
    Description: Leibniz-Institut für Ostseeforschung Warnemünde (IOW) (3484)
    Keywords: ddc:551.9 ; Coastal systems ; Dissolved organic matter ; Riverine input ; Baltic Sea
    Language: English
    Type: doc-type:article
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  • 3
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 438 (2005), S. 1078-1078 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Sir As an oceanographer I enjoyed your recent Insight on Bio-oceanography (Nature 437, 335–368; 2005). But the only female author in this section was the senior editor who wrote the introduction. This is quite ...
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Biogeochemistry 6 (1988), S. 161-179 
    ISSN: 1573-515X
    Keywords: biogenic silica ; diatoms ; Great Lakes ; sediments
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Biogenic silica concentration (BSi) in sediment cores from the Great Lakes is evaluated as an estimate of siliceous microfossil abundance. A significant linear relationship was found between measured BSi and diatom valve abundance for sediment cores from the Bay of Quinte, Lake Ontario, Lake Erie, Lake Michigan and Lake Superior and between measured BSi and diatom biovolume for Lake Erie, Lake Michigan, and Lake Superior but not for Lake Ontario. Diatom silica predicted from diatom species abundance and an estimated silica content per cell in the Lake Erie cores accounted for 117% and 103% of measured BSi, respectively. By contrast, predicted diatom silica could only account for 28% of measured BSi in the Lake Michigan core and only 25% in the Lake Superior core. A few large diatoms with a large silica content per cell comprised a major portion of predicted diatom silica in all cores. The discrepancy between chemically measured BSi and the silica predicted from diatoms in the Lake Michigan and Lake Superior cores was partially due to the inability of the regression model, used to estimate diatom silica content, to account for different degrees of silicification in the diatom asemblages from the more dissolved silica rich Lake Michigan and Lake Superior.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Hydrobiologia 410 (1999), S. 87-96 
    ISSN: 1573-5117
    Keywords: eutrophication ; nutrient limitation ; nitrogen ; phosphorous ; silicate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Nutrient loading by riverine input into estuarine systems has increased by 6–50 times for the N load from pristine conditions to present, whereas a 18–180 times increase has been observed in the P load. Reductions in the ratio of N to P delivery has also occurred with time. In a review of nutrient limitation in estuarine systems, it is shown that many estuarine systems display P limitation in the spring, switching to N limitation in the summer with some estuaries displaying dissolved silicate limitation of the spring diatom bloom. Historical and recent changes in nutrient loading and their effect on nutrient limitation have intensified the debate on the control of nutrient delivery to estuaries from both agricultural and point sources, and as to what nutrient (N or P) should be managed for in estuarine systems. It is hypothesized that potential reductions in P may help oxygen depletion especially in deep estuaries and reduce fast growing macrophytes such as Ulva sp., although P reductions probably will have little effect on summer chlorophyll concentrations, an important recreational management goal. Reductions in N loading should reduce summer chlorophyll concentrations and improve the conditions for submerged aquatic vegetation and thus improve ecosystem functioning. Finally, if only P reductions are pursued, that is if we are able to reduce P such that it is limiting year around in estuarine systems, it is likely that the export of N from estuarine systems would increase to the bordering N-limited marine systems, thus only exporting the problem of enhanced production with eutrophication.
    Type of Medium: Electronic Resource
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  • 6
    facet.materialart.
    Unknown
    PANGAEA
    In:  Supplement to: Lenz, Conny; Jilbert, Tom; Conley, Daniel J; Slomp, Caroline P (2015): Hypoxia-driven variations in iron and manganese shuttling in the Baltic Sea over the past 8 kyr. Geochemistry, Geophysics, Geosystems, 16(10), 3754-3766, https://doi.org/10.1002/2015GC005960
    Publication Date: 2023-01-13
    Description: The Baltic Sea has experienced three major intervals of bottom water hypoxia following the intrusion of seawater ca. 8 kyrs ago. These intervals occurred during the Holocene Thermal Maximum (HTM), Medieval Climate Anomaly (MCA) and during recent decades. Here, we show that sequestration of both Fe and Mn in Baltic Sea sediments generally increases with water depth, and we attribute this to shelf-to-basin transfer ("shuttling") of Fe and Mn. Burial of Mn in slope and basin sediments was enhanced following the lake-brackish/marine transition at the beginning of the hypoxic interval during the HTM. During hypoxic intervals, shelf-to-basin transfer of Fe was generally enhanced but that of Mn was reduced. However, intensification of hypoxia within hypoxic intervals led to decreased burial of both Mn and Fe in deep basin sediments. This implies a non-linearity in shelf Fe release upon expanding hypoxia with initial enhanced Fe release relative to oxic conditions followed by increased retention in shelf sediments, likely in the form of iron sulfide minerals. For Mn, extended hypoxia leads to more limited sequestration as Mn carbonate in deep basin sediments, presumably because of more rapid reduction of Mn oxides formed after inflows and subsequent escape of dissolved Mn to the overlying water. Our Fe records suggest that modern Baltic Sea hypoxia is more widespread than in the past. Furthermore, hypoxia-driven variations in shelf-to-basin transfer of Fe may have impacted the dynamics of P and sulfide in the Baltic Sea thus providing potential feedbacks on the further development of hypoxia.
    Type: Dataset
    Format: application/zip, 10 datasets
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  • 7
    facet.materialart.
    Unknown
    PANGAEA
    In:  Supplement to: Lenstra, Wytze K; Egger, Matthias; van Helmond, Niels A G M; Kritzberg, Emma; Conley, Daniel J; Slomp, Caroline P (2018): Large variations in iron input to an oligotrophic Baltic Sea estuary: impact on sedimentary phosphorus burial. Biogeosciences, 15(22), 6979-6996, https://doi.org/10.5194/bg-15-6979-2018
    Publication Date: 2023-01-13
    Description: Estuarine sediments are key sites for removal of phosphorus (P) from rivers and the open sea. Vivianite, an Fe(II)-P mineral, can act as a major sink for P in Fe-rich coastal sediments. In this study, we investigate the burial of P in the Öre Estuary in the northern Baltic Sea. We find much higher rates of P burial at our five study sites (up to ∼ 0.145mol m−2 yr−1) when compared to more southern coastal areas in the Baltic Sea with similar rates of sedimentation. Detailed study of the sediment P forms at our site with the highest rate of sedimentation reveals a major role for P associated with Fe and the presence of vivianite crystals below the sulfate methane transition zone. By applying a reactive transport model to sediment and porewater profiles for this site, we show that vivianite may account for up to ∼ 40% of total P burial. With the model, we demonstrate that vivianite formation is promoted in sediments with a low bottom water salinity and high rates of sedimentation and Fe oxide input. While high rates of organic matter input are also required, there is an optimum rate above which vivianite formation declines. Distinct enrichments in sediment Fe and sulfur at depth in the sediment are attributed to short periods of enhanced input of riverine Fe and organic matter. These periods of enhanced input are linked to variations in rainfall on land and follow dry periods. Most of the P associated with the Fe in the sediment is likely imported from the adjacent eutrophic Baltic Proper. Our work demonstrates that variations in land-to-sea transfer of Fe may act as a key control on burial of P in coastal sediments. Ongoing climate change is expected to lead to a decrease in bottom water salinity and contribute to continued high inputs of Fe oxides from land, further promoting P burial as vivianite in the coastal zone of the northern Baltic Sea. This may enhance the role of this oligotrophic area as a sink for P imported from eutrophic parts of the Baltic Sea.
    Type: Dataset
    Format: application/zip, 4 datasets
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  • 8
    Publication Date: 2023-02-07
    Keywords: Acid volatile sulfur; Chromium reducible sulfur; DEPTH, sediment/rock; Iron; Iron oxides; MULT; Multiple investigations; Ore_estuary_20150425_NB8; Ore Estuary; Phosphorus, authigenic; Phosphorus, detrital; Phosphorus, exchangeable; Phosphorus, iron-bound; Phosphorus, organic; Sulfur
    Type: Dataset
    Format: text/tab-separated-values, 414 data points
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  • 9
    Publication Date: 2023-02-07
    Keywords: Aluminium; Date/Time of event; DEPTH, sediment/rock; Event label; Iron, total; Latitude of event; Longitude of event; Manganese, total; MULT; Multiple investigations; Ore_estuary_20150421_NB1; Ore_estuary_20150422_N6_1; Ore_estuary_20150423_N10; Ore_estuary_20150424_N7; Ore_estuary_20150425_NB8; Ore Estuary; Phosphorus, total; Porosity; Sulfur, total
    Type: Dataset
    Format: text/tab-separated-values, 848 data points
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  • 10
    Publication Date: 2023-02-07
    Keywords: Aluminium; Baltic Sea; Calcium; Carbon, organic, total; DEPTH, sediment/rock; Element analyser, Fisons NA 1500 NCS; F80-A; GC; Gravity corer; ICP-OES, Perkin-Elmer, Optima 3000; Iron/Aluminium ratio; Manganese; Molybdenum; Sulfur, total
    Type: Dataset
    Format: text/tab-separated-values, 1569 data points
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