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  • 1
    ISSN: 1573-1561
    Keywords: Lepidoptera ; Lymantriidae ; white-spotted tussock moth ; Orgyia thyellina ; (Z)-6-heneicosen-11-one ; (Z)-6-heneicosen-9-one ; (Z)-6,(E)-8-heneicosadien-11-one ; sex pheromone ; synergism ; quarantine insect ; international trade ; eradication ; Bacillus thuringiensis ; microbial insecticide
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract In 1996, the exotic white-spotted tussock moth (WSTM), Orgyia thyellina (Lepidoptera: Lymantriidae), was discovered in Auckland, New Zealand. Because establishment of WSTM would threaten New Zealand's orchard industry and international trade, eradication of WSTM with microbial insecticide was initiated. To monitor and complement eradication of WSTM by capture of male moths in pheromone-baited traps, pheromone components of female WSTM needed to be identified. Coupled gas chromatographic–electroantennographic detection analysis of pheromone gland extract revealed several compounds that elicited responses from male moth antennae. Mass spectra of the two most EAD-active compounds suggested, and comparative GC-MS of authentic standards confirmed, that they were (Z)-6-heneicosen-11-one (Z6–11-one) and (Z)-6-heneicosen-9-one, the latter termed here “thyellinone.” In field experiments in Japan, Z6–11-one plus thyellinone at a 100:5 ratio attracted WSTM males, whereas either ketone alone failed to attract a single male moth. Addition of further candidate pheromone components did not enhance attractiveness of the binary blend. Through the 1997–1998 summer, 45,000 commercial trap lures baited with 2000 μg of Z6–11-one and 100 μg of thyellinone were deployed in Auckland towards eradication of the residual WSTM population.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical ecology 23 (1997), S. 1621-1633 
    ISSN: 1573-1561
    Keywords: All-glass volatile collecting system ; volatiles ; aeration period ; vapor pressure ; polar effects ; surface adhesion ; volatiles breakthrough ; insect sex pheromones
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract Airborne volatiles of saturated and unsaturated acetates and alcohols with the dodecane, tetradecane, and hexadecane chains released from fresh polyethylene pheromone dispensers were collected in Pasteur pipets attached to an all-glass collecting system. A maximum of 300–500 ng of pheromone in the first pipet (in a row of three or four) could be accumulated. The total amount that can be collected from an active rich source in 10–15 min of aeration (at 40–50 ml/min/cage) can reach 0.5–1 μg. Breakthrough from a pipet starts after an accumulation of 40–50 ng. There is a direct relationship among airflow rate in the system, the period of collection, and the vapor pressure of the chemicals on the amount adsorbed on the glass surface of the pipets. Polar functionalities, such as hydrogen bonding and π electrons play a significant role in the strength of adsorption to the glass surface. The system and technique are simple, fast, and easy to handle for collection of airborne volatiles from plants, animals, and nonliving sources.
    Type of Medium: Electronic Resource
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