ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The dependences of the shift of the Kα line of sulfur on the effective charge on the S atom, calculated by the CNDO/S method, are decomposed into two linear dependences: one for a compound of thione sulfur, the other for the rest of sulfur-containing systems. The dependences of the shift of the Kα line of P on the effective charge on the P atom, calculated by the CNDO/S method, are also decomposed into two linear dependences; one for compounds of three-coordinate P, the other for compounds of P with coordination number 〉3. In thiophosphoryl compounds, the electron density on the S atom varies symbatically with that for the P atom. In systems containing the P-S bond, the magnitudes of the effective charge on the S atom remain virtually constant.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00962385
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