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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : International Union of Crystallography (IUCr)
    Acta crystallographica 39 (1983), S. 192-192 
    ISSN: 1600-5724
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 78 (1995), S. 7304-7312 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Hydrogenated amorphous silicon (a-Si:H) films having a thickness of 7 μm were deposited on molybdenum by dc glow discharge and then capped with a 0.1-μm-thick aluminum (Al) layer by thermal evaporation. Subsequent vacuum annealing at 500–725 °C resulted in the formation of crystalline Si, as observed by Raman scattering and x-ray diffraction. This was in contrast to the uncapped a-Si:H films which were still amorphous at the same annealing temperatures, except at (approximately-greater-than)700 °C. That the Al capped films were crystalline caused a ten-fold increase in the dark conductivity in comparison to the uncapped film annealed at the same temperature. The capped films annealed at 500 °C showed a photoresponse (the ratio of the photoconductivity to dark conductivity) of 30, a photoconductivity of 2×10−4 (Ω cm)−1, and a carrier diffusion length of 5.3 μm—values much higher than those of the uncapped films (heated or not). This was due to a large grain size combined with the retention of hydrogen, which passivated the grain boundaries. On the other hand, a significant loss of hydrogen from the capped film at 580 °C, as observed by in situ evolved gas analysis, resulted in the diffusion length reducing to 1.8 μm and ten-fold decreases of the photoconductivity and photoresponse. All three parameters increased slightly with a further increase in the annealing temperature from 600 to 680 °C, due to the increase in the grain size. At 695 °C, further hydrogen evolution caused a sharp decrease in the values of these parameters. © 1995 American Institute of Physics.
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 1569-1577 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The deposition temperature of hydrogenated amorphous silicon films deposited by dc glow discharge was found to affect the crystallinity, hydrogen content, and silicon–hydrogen bonding after laser crystallization of the film. This in turn affected the electrical properties of the crystallized film. The crystallinity of the film after laser annealing was always higher than that of the corresponding furnace-crystallized films, for the same deposition temperature, and it increased with decreasing deposition temperature, similar to that observed in furnace crystallized films (650 °C, 30 h). However, the dark and photoconductivity, photoresponse (defined as the ratio of photo to dark conductivity), and the carrier diffusion length increased with increasing deposition temperature (150–350 °C). This was due to both an increase in hydrogen content and the SiH and SiH2 bonding, as shown by evolved gas analysis and infrared spectroscopy. Carrier transport measurements indicated that the dominant transport mechanism changed from localized hopping to extended state transport with increasing deposition temperature for the laser-crystallized films. © 1996 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 32 (1997), S. 2873-2882 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Copper–matrix composites were made by powder metallurgy (PM). The reinforcements were molybdenum particles, silicon carbide whiskers and titanium diboride platelets. The coated filler method, which involves a reinforcement coated with the matrix metal, was used. In contrast, conventional PM uses the admixture method, which involves a mixture of matrix powder and reinforcement. For all the composite systems, the coated filler method was found to be superior to the admixture method in providing composites with lower porosity, greater hardness, higher compressive yield strength, lower coefficient of thermal expansion (CTE), higher thermal conductivity and lower electrical resistivity, though the degree of superiority was greater for high than low reinforcement contents. In the coated filler method, the coating on the reinforcement separated reinforcement units from one another and provided a cleaner interface and stronger bond between reinforcement and matrix than the admixture method could provide. The highest reinforcement content attained in dense composites (〈5% porosity) made by the coated filler method was 70 vol% Mo, 60 vol% TiB2 and 54 vol% SiC. The critical reinforcement volume fraction above which the porosity of composites made by the admixture method increases abruptly is 60% Mo, 42% TiB2 and 33% SiC. This fraction increases with decreasing aspect ratio of the reinforcement. Among Cu/Mo, Cu/TiB2 and Cu/SiC at the same reinforcement volume fraction (50%), Cu/Mo gave the lowest CTE, highest thermal conductivity and lowest electrical resistivity, while Cu/SiC gave the greatest hardness and Cu/TiB2 and Cu/SiC gave the highest compressive yield strength. Compared to Cu/SiC, Cu/TiB2 exhibited much higher thermal conductivity and much lower electrical resistivity.
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 32 (1997), S. 3113-3121 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Anodization is an effective surface treatment for improving the corrosion resistance of aluminium-matrix composites. For SiC particle-filled aluminium, anodization was performed successfully in an acid electrolyte, as usual. However, for AlN particle-filled aluminium, anodization needed to be performed in an akaline (0.7 N NaOH) electrolyte instead of an acid electrolyte, because NaOH reduced the reaction between AlN and water, whereas an acid enhanced this reaction. The concentration of NaOH in the electrolyte was critical; too high a concentration of NaOH caused the dissolution of the anodizing product (Al2O3) by the NaOH, whereas too low a concentration of NaOH did not provide sufficient ions for the electrochemical process. The corrosion properties and anodization characteristic of pure aluminium, Al/AlN and Al/SiC were compared. Without anodization, pure aluminium had better corrosion resistance than the composites and Al/SiC had better corrosion resistance than Al/AlN. After anodization, the corrosion resistance of Al/AlN was better than Al/SiC and both composites were better than pure aluminium without anodization, but still not as good as the anodized pure aluminium.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 9 (1988), S. 279-282 
    ISSN: 1572-9567
    Keywords: bromine ; exfoliation ; graphite ; intercalation ; phase transition ; stress ; temperature ; thermal stress
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The thermal stress of graphite intercalated with bromine was found to increase from zero at about 100°C to about 1.3 MPa at 200°C. The effect was reversible with hysteresis. The thermal stress increase had a sharp temperature dependence due to its association with the exfoliation phase transition.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 31 (1996), S. 399-406 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Copper-matrix SiC whisker composites containing 33–54 vol % SiC whiskers and with 〈 5 vol % porosity were fabricated by hot pressing SiC whiskers that had been coated with copper by electroless plating followed by electroplating. The highest Brinell hardness of 260 was attained at 50 vol % SiC whiskers. The lowest coefficient of thermal expansion (CTE) of 9.6 × 10−6°C−1 (at 25–150°C) was attained at 54 vol % SiC whiskers. The composites exhibited lower porosity, higher hardness, higher compressive yield strength, lower CTE, lower electrical resistivity and higher thermal conductivity than the corresponding composites made by hot pressing mixtures of copper powder and bare SiC whiskers.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 32 (1997), S. 5321-5333 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The addition of short, bare, carbon fibres to a silver-based active brazing alloy (63Ag–34Cu–2Ti–1Sn) resulted in up to 30% improvement in the shear/tensile joint strength of brazed joints between stainless steel and alumina. The optimum fibre volume fraction in the brazing material was 12%. This improvement is attributed to the thinning and microstructural simplification of the alumina/braze reaction product (titanium-rich) layer, the softening of the brazing alloy matrix, the strengthening of the braze and the reduction of the coefficient of thermal expansion. The depth of titanium diffusion into the alumina was decreased by the fibre addition. The first two effects are due to the absorption of titanium by the fibres. This absorption resulted in less titanium in the brazing alloy matrix, a braze/fibre particulate reaction product (titanium-rich) on the fibres and the diffusion of titanium into the fibres. In contrast, the use of an active brazing alloy with a lower titanium content but without carbon fibres gave much weaker joints.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 31 (1996), S. 407-412 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Al-matrix SiC whisker composites were fabricated by pressureless infiltration of liquid Al-Mg or Al-Si-Mg alloys at 830–950°C in the presence of N2 into a preform of nickel coated SiC whiskers. The nickel coating on the whiskers was obtained by electroless plating and made pressureless infiltration possible. The composite made by pressureless infiltration exhibited slightly lower tensile strength and modulus and slightly higher coefficient of thermal expansion than the corresponding composite made by pressure infiltration. However, the differences were small in spite of the lack of prior evacuation in the pressureless infiltration case. On the other hand, the hardness decreased with increasing distance from the preform-melt interface much more significantly in composites made by pressureless infiltration than those made by pressure infiltration. The hardness decrease, which was attributed to a porosity increase, was larger for composites made by pressureless infiltration without prior evacuation than those made by pressureless infiltration with prior evacuation. The Al-SiC reactivity was larger for composites made by pressureless infiltration than those made by pressure infiltration, because the infiltration time was longer in pressureless infiltration.[/p]
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 31 (1996), S. 5961-5973 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A TiB2 particle (61 vol%, 4 μm mean size) reinforced aluminium fabricated by liquid-aluminium infiltration was subjected to unlubricated rolling wear and was found from the weight loss to be 1.5 times more wear resistant than 17-4 ph stainless steel, twice as wear resistant as 1020 steel, 7.5 times more wear resistant than 2024 aluminium, and 12.8 times more wear resistant than the aluminium matrix. This wear resistance is attributed to the lack of particle pull-out and the ability of the TiB2 particles to protect the softer underlying matrix from abrasion. This composite was approximately three times more wear resistant than AlN particle (50 vol%)-reinforced aluminium. The greater wear resistance of Al/TiB2 compared to Al/AlN is due to the slow wear of the TiB2 particles and the AlN particle pull-out. A slight decline in tensile strength and no effect on the modulus was observed in Al/TiB2 after heating at 300 or 600°C for 240 h. This high-temperature stability is attributed to the lack of reactivity between TiB2 and the aluminium matrix.
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