ISSN:
1022-1336
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
This paper describes the polymerization of 2-methyl-(3,6-di-O-benzyl- 1,2-dideoxy-α-D-glucopyrano)-[2,1-d]-2-oxazoline (1) with an acid catalyst. The polymerization proceeds involving stereoregular glycosylation to give polysaccharide 2. The polymer structure, 2-acetamido-3,6-di-O-benzyl-2-deoxy-(l→4)-β-D-glucopyranan was determined by means of 1H NMR, 13C NMR, and IR spectra as well as elemental analysis. The molecular weight was at most 4900 (degree of polymerization ≈ 13).
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/marc.1996.030170601
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