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  • 1
    ISSN: 1520-4995
    Source: ACS Legacy Archives
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of medicinal chemistry 30 (1987), S. 1287-1295 
    ISSN: 1520-4804
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 92 (1986), S. 518-529 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract A field, petrologic and stable isotopic investigation of the marbles and calc-silicates of the 1.15 b.y. Valley Spring Gneiss documents the dilution of internally evolved CO2-rich fluids by externally derived aqueous fluids introduced along channelways. Reaction textures within calcsilicates record the evolution through time of initially CO2-rich fluids toward increasingly more aqueous compositions. Assemblage zonations within calc-silicates require equilibration within local gradients of the mole fraction of CO2 in the fluid, and suggest that the infiltration of aqueous fluids was largely channelized along more permeable lithologies. Localized depletions in 13C and 18O corroborate petrologic evidence for channelized infiltration. Isotopic compositions reflect both devolatilization and the introduction of low-δ 18O fluids; estimated minimum oxygen-equivalent fluid-to-rock ratios are near unity. Both mineralogical and stable isotopic systematics document the essential role of infiltration in driving decarbonation reactions during calc-silicate formation. The calc-silicate assemblages which equilibrated with fluids of the lowest mole fraction of CO2 record isotopic exchange equilibrium with fluids of δ 18O typical of those derived from “normal granites”, as do the granitic aplites and pegmatites which transect most calcsilicate occurrences. Thus the infiltrating fluids are believed to be genetically linked to the intrusion of a suite of granitic plutons emplaced after the peak of regional metamorphism.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 103 (1989), S. 1-24 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The spatial disposition, compositional zoning profiles, and size distributions of garnet crystals in 11 specimens of pelitic schist from the Picuris Range of New Mexico (USA) demonstrate that the kinetics of intergranular diffusion controlled the nucleation and growth mechanisms of porphyroblasts in these rocks. An ordered disposition of garnet centers and a significant correlation between crystal radius and near-neighbor distances manifest suppressed nucleation of new crystals in diffusionally depleted zones surrounding pre-existing crystals. Compositional zoning profiles require diffusionally controlled growth, the rate of which increases exponentially as temperature increases with time; an acceleration factor for growth rate can be estimated from a comparison of compositional profiles for crystals of different sizes in each specimen. Crystal size distributions are interpreted as the result of nucleation rates that accelerate exponentially with increasing temperature early in the crystallization process, but decline in the later stages because of suppression effects in the vicinity of earlier-formed nuclei. Simulations of porphyroblast crystallization, based upon thermally accelerated diffusionally influenced nucleation kinetics and diffusionally controlled growth kinetics, quantitatively replicate textural relations in the rocks. The simulations employ only two variable parameters, which are evaluated by fitting of crystal size distributions. Both have physical significance. The first is an acceleration factor for nucleation, with a magnitude reflecting the prograde increase during the nucleation interval of the chemical affinity for the reaction in undepleted regions of the rock. The second is a measure of the relative sizes of the porphyroblast and the diffusionally depleted zone surrounding it. Crystal size distributions for the Picuris Range garnets correspond very closely to those in the literature from a variety of other localities for garnet and other minerals. The same kinetic model accounts quantitatively for crystal size distributions of porphyroblastic garnet, phlogopite, sphene, and pyroxene in rocks from both regional and contact metamorphic occurrences. These commonalities indicate that intergranular diffusion may be the dominant kinetic factor in the crystallization of porphyroblasts in a wide variety of metamorphic environments.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 92 (1986), S. 218-224 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Experiments using V2O5 as a high-temperature solvent have produced compositional reversals defining the miscibility gap between enstatite and diopside on the join Mg2Si2O6-CaMgSi2O6 between 925° and 1,175° C at atmospheric pressure. These experiments locate an equilibrium near 1,000° C among diopside, protoenstatite, and orthoenstatite; they verify the stable coexistence of diopside and protoenstatite above 1,000° C and disprove the hypothesis that orthoenstatite has a stability field which is continuous from temperatures below 1,000° C to the solidus. The phase relations suggest that the orthorhombic low-Ca pyroxene on the solidus in this system (formerly identified as orthoenstatite) is a phase distinct from the orthoenstatite stable with diopside at low subsolidus temperatures. Data locating the orthoenstatite-diopside miscibility gap validate the use at low pressures of symmetric orthopyroxene and asymmetric clinopyroxene solution models in this system.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 92 (1986), S. 89-92 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Molten high-temperature solvents can provide major kinetic advantages in phase equilibrium studies of silicate systems, by markedly enhancing rates of crystal growth and chemical reaction. Experience gained in a study of cation partitioning between ortho-and clinopyroxene at low temperatures and atmospheric pressure suggests that an ideal solvent would combine the following properties: high solubilities for component oxides of silicates, with minimum temperature dependence; no formation of oxide-solvent compounds with melting points above that of the pure solvent; minimal incorporation of solvent components into the crystalline phases of interest; ease of chemical separation of crystalline phases from quenched solvent-rich melt; low volatility and viscosity; density close to that of the crystalline phases; and high surface tension against encapsulation materials, typically platinum. Maximum kinetic benefits of the technique are derived only when the composition of saturated solvent-rich melt is carefully determined as a function of temperature, so that melt-to-crystal ratios in experimental charges can be raised to high values. V2O5 is one solvent suitable for studies involving olivine, pyroxenes, and plagioclase in the system CaO-MgO-Al2O3-SiO2 and its subsystems.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1610-2924
    Keywords: X-ray computed tomography ; textural analysis ; visualization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract High-resolution X-ray computed tomography of igneous rocks provides a rapid, non-destructive means to acquire textural data and imagery in three dimensions. Tomographic images are maps of the spatial variations within a specimen of the average linear attenuation coefficient for the input X-ray spectrum, a quantity that depends strongly on mass density and also on atomic number. Visualization of these data benefits from the ability to view sections through the specimen in any location and orientation, and from the ability to extract features of particular interest and display perspective views of them in arbitrary orientation. These images can then be animated to facilitate comprehension of three-dimensional textural relationships. The numerical character of the method also makes these data sets inherently rich in the metrical information required for quantitative characterization and statistical analysis of the sizes, shapes, locations, and interrelations of textural components in igneous rocks. Examples of the scientific value of tomographic textural analysis are numerous. Images of the distribution of metal veins and particles in a lodranite meteorite define scales and mechanisms of transport during silicate-metal segregation resulting from partial melting of primitive compositions. Diamonds in eclogites are seen in tomographic imagery to have a close spatial association with a network of subplanar alteration zones, implying that the diamond does not have an igneous origin, but is instead a product of later metasomatism. In a slowly cooled basalt flow, tomographic images reveal plagioclase crystals linked in monomineralic chains, forming continuous networks that affect the flow's rheology and its chemical differentiation, and record its compaction history. Comingling of compositionally dissimilar magmas occurs across an interface that exhibits delicate interfingering of the contrasting melts at all observed length scales. Measurement of the size and shape distributions of vesicles in basalts yields information on the principal driving forces for volcanic eruptions by revealing details of bubble growth, nucleation, and coalescence, and permits estimates of paleoelevation at the time of emplacement of the flows. Images of leucosome/melanosome/mesosome relationships in migmatites provide quantitative constraints on the topology of melt flow paths during anatexis.
    Type of Medium: Electronic Resource
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  • 8
    Publication Date: 1983-01-01
    Print ISSN: 0022-1376
    Electronic ISSN: 1537-5269
    Topics: Geosciences
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  • 9
  • 10
    Publication Date: 2010-07-21
    Print ISSN: 0020-6814
    Electronic ISSN: 1938-2839
    Topics: Geosciences
    Published by Taylor & Francis
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