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  • 1
    Publication Date: 2015-02-10
    Description: The crystallization of hexagonal NdCO 3 OH through hydrothermal synthesis carried out at slow (reaching the desired temperature within 100 min) and quick (50 min) rates of heating but at variable temperatures (165–220°C) are reported here. The formation of NdCO 3 OH occurs via the crystallization of an amorphous precursor. Both the precursor and the crystalline NdCO 3 OH were characterized by X-ray diffraction, infrared spectroscopy and high-resolution electron microscopy. The mechanism of crystallization is very dependent on the experimental conditions (rate of heating and temperature treatment). With increasing temperature, the habit of NdCO 3 OH crystals changes progressively to more complex spherulitic or dendritic morphologies. The development of these crystal morphologies is suggested here to be controlled by the level at which supersaturation was reached in the aqueous solution during the breakdown of the amorphous precursor. At the highest temperature (220°C) and during rapid heating (50 min) the amorphous precursor breaks down rapidly and the fast supersaturation promotes spherulitic growth. At the lowest temperature (165°C) and slow heating (100 min), however, the supersaturation levels are approached more slowly than required for spherulitic growth, and thus more regular, previously unseen, triangular pyramidal shapes form.
    Print ISSN: 0026-461X
    Electronic ISSN: 1471-8022
    Topics: Geosciences
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  • 2
    Publication Date: 2015-02-10
    Description: The formation of crystalline rare earth element ( REE ) (e.g. La, Ce, Pr, Nd) carbonates from aqueous solutions was examined at ambient temperature using UV-Vis spectrophotometry, combined with X-ray diffraction, high-resolution microscopy and infrared spectroscopy. In all experiments REE -lanthanites ( REE 2 (CO 3 ) 3 ·8H 2 O) formed via a highly hydrated, nanoparticulate and poorly-ordered REE -carbonate precursor. The lifetime of this precursor as well as the kinetics of crystallization of the various REE -lanthanites were dependent on the specific REE 3+ ion involved in the reaction. The induction time and the time needed to fully form the crystalline REE -lanthanite end products increase linearly with the ionic potential. The authors show here that the differences in ion size and ionic potential as well as differences in dehydration energy of the REE 3+ ions control the lifetime of the poorly ordered precursor and thus also the crystallization kinetics of the REE -lanthanites; furthermore, they also affect the structural characteristics (e.g. unit-cell dimensions and idiomorphism) of the final crystalline lanthanites.
    Print ISSN: 0026-461X
    Electronic ISSN: 1471-8022
    Topics: Geosciences
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  • 3
    Publication Date: 2021-09-22
    Description: We present the first results of K2-OjOS, a collaborative project between professional and amateur astronomers primarily aimed to detect, characterize and validate new extrasolar planets. For this work, 10 amateur astronomers looked for planetary signals by visually inspecting the 20,427 light curves of K2 campaign 18 (C18). They found 42 planet candidates, of which 18 are new detections and 24 had been detected in the overlapping C5 by previous works. We used archival photometric and spectroscopic observations, as well as new high-spatial resolution images in order to carry out a complete analysis of the candidates found, including a homogeneous characterization of the host stars, transit modeling, search for transit timing variations and statistical validation. As a result, we report four new planets (K2-355 b, K2-356 b, K2-357 b, and K2-358 b) and 14 planet candidates. Besides, we refine the transit ephemeris of the previously published planets and candidates by modeling C5, C16 (when available) and C18 photometric data jointly, largely improving the period and mid-transit time precision. Regarding individual systems, we highlight the new planet K2-356 b and candidate EPIC 211537087.02 being near a 2:1 period commensurability, the detection of significant TTVs in the bright star K2-184 (V = 10.35), the location of K2-103 b inside the habitable zone according to optimistic models, the detection of a new single transit in the known system K2-274, and the disposition reassignment of K2-120 b, which we consider as a planet candidate as the origin of the signal can not be ascertained.
    Print ISSN: 0035-8711
    Electronic ISSN: 1365-2966
    Topics: Physics
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  • 4
    Publication Date: 2020-02-12
    Type: info:eu-repo/semantics/article
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  • 5
    Publication Date: 2020-02-12
    Type: info:eu-repo/semantics/article
    Format: application/pdf
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  • 6
    Publication Date: 2020-02-12
    Description: The crystallization of hexagonal NdCO3OH through hydrothermal synthesis carried out at slow (reaching the desired temperature within 100 min) and quick (50 min) rates of heating but at variable temperatures (165–220°C) are reported here. The formation of NdCO3OH occurs via the crystallization of an amorphous precursor. Both the precursor and the crystalline NdCO3OH were characterized by X-ray diffraction, infrared spectroscopy and high-resolution electron microscopy. The mechanism of crystallization is very dependent on the experimental conditions (rate of heating and temperature treatment). With increasing temperature, the habit of NdCO3OH crystals changes progressively to more complex spherulitic or dendritic morphologies. The development of these crystal morphologies is suggested here to be controlled by the level at which supersaturation was reached in the aqueous solution during the breakdown of the amorphous precursor. At the highest temperature (220°C) and during rapid heating (50 min) the amorphous precursor breaks down rapidly and the fast supersaturation promotes spherulitic growth. At the lowest temperature (165°C) and slow heating (100 min), however, the supersaturation levels are approached more slowly than required for spherulitic growth, and thus more regular, previously unseen, triangular pyramidal shapes form.
    Type: info:eu-repo/semantics/article
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  • 7
    Publication Date: 2020-02-12
    Description: We report the physical properties of α-FeO (hematite), synthesized by dry-heating (350-1,000°C) of a new, poorly ordered iron oxyhydroxide precursor compound that we name carbonated 2-line ferrihydrite. This precursor was characterized by powder X-ray diffraction, Fourier transform infrared spectroscopy, electron microscopy, and thermogravimetric analysis, whereas the α-FeO was studied with X-ray diffraction, scanning and transmission electron microscopy, and magnetic techniques. α-FeO synthesized at 350°C consisted of single-nanocrystal particles (length × width 20 ± 6 nm (L) × 15 ± 4 nm (W)), which at room temperature exhibited very narrow hysteresis loops of low coercivities (〈300 Oe). However, α-FeO synthesized at higher temperatures (1,000°C) was composed of larger nanocrystalline particle aggregates (352 ± 109 nm (L) × 277 ± 103 nm (W)) that also showed wide-open hysteresis loops of high magnetic coercivities (∼5 kOe). We suggest that these synthesis-temperature-dependent coercivity values are a consequence of the subparticle structure induced by the different particle and crystallite size growth rates at increasing annealing temperature.
    Type: info:eu-repo/semantics/article
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  • 8
    Publication Date: 2020-02-12
    Description: The crystallization of amorphous dysprosium carbonate (ADC) has been studied in air (21-750 degrees C) and in solution (21-250 degrees C). This poorly ordered precursor, Dy-2(CO3)(3)center dot 4H(2)O, was synthesized in solution at ambient temperature. Its properties and crystallization pathways were studied by powder X-ray diffraction, Fourier transform infrared spectroscopy, scanning and transmission electron microscopy, thermogravimetric analysis, and magnetic techniques. ADC consists of highly hydrated spherical nanoparticles of 10-20 nm diameter that are exceptionally stable under dry treatment at ambient and high temperatures (〈550 degrees C). However, ADC transforms in solution to a variety of Dy-carbonates, depending on the temperature and reaction times. The transformation sequence is (a) poorly crystalline metastable tengerite-type phase, Dy-2(CO3)(3)center dot 2-3H(2)O; and (b) the orthorhombic kozoite-type phase DyCO3(OH) at 165 degrees C after prolonged times (15 days) or faster (12 h) at 220 degrees C. Both the amorphous phase and the kozoite-type phase DyCO3(OH) are paramagnetic in the range of temperatures measured from 1.8 to 300 K.
    Type: info:eu-repo/semantics/article
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  • 9
    Publication Date: 2020-02-12
    Description: The formation of crystalline rare earth element (REE) (e.g. La, Ce, Pr, Nd) carbonates from aqueous solutions was examined at ambient temperature using UV-Vis spectrophotometry, combined with X-ray diffraction, high-resolution microscopy and infrared spectroscopy. In all experiments REE-lanthanites (REE2(CO3)3·8H2O) formed via a highly hydrated, nanoparticulate and poorly-ordered REE-carbonate precursor. The lifetime of this precursor as well as the kinetics of crystallization of the various REE-lanthanites were dependent on the specific REE3+ ion involved in the reaction. The induction time and the time needed to fully form the crystalline REE-lanthanite end products increase linearly with the ionic potential. The authors show here that the differences in ion size and ionic potential as well as differences in dehydration energy of the REE3+ ions control the lifetime of the poorly ordered precursor and thus also the crystallization kinetics of the REE-lanthanites; furthermore, they also affect the structural characteristics (e.g. unit-cell dimensions and idiomorphism) of the final crystalline lanthanites.
    Type: info:eu-repo/semantics/article
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  • 10
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Energy & fuels 5 (1991), S. 188-192 
    ISSN: 1520-5029
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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