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  • 1
    Series available for loan
    Series available for loan
    S-Isotopengeochemie in der KTB-Verbohrung und Beziehungen zu den Spurenelementmustern der Pyrite (1992)
    Karlsruhe : Institut für Petrographie und Geochemie, Universität Karlsruhe
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    Call number: AWI G6-18-91532
    In: Karlsruher geochemische Hefte, Nr. 2
    Description / Table of Contents: Der Einfluß metamorpher und hydrothermaler Überprägung auf primär angelegte magmatische und sedimentäre Schwefel-Isotopensignaturen wurden am Beispiel des 4000 m mächtigen Kristallinprofils der KTB-Vorbohrung systematisch untersucht und dargestellt. Der Einfluß der polymetamorphen Überprägung erwies sich dabei als so gering, daß die Variation der S-Isotopenverhältnisse teilweise im Rahmen prämetamorpher Prozesse interpretiert werden kann. Um Hinweise auf die Natur der Bildungs- und Isotopen-Fraktionierungsmechanismen schwefelführender Minerale zu erhalten, wurde ein chemisches Trennverfahren erarbeitet und angewendet. Die Schwefelisotopenuntersuchungen werden durch einen Beitrag zur Spurenelementgeochemie des Pyrits ergänzt. Aufgrund der Auswertung der Meßdaten mittels multivariater Methoden konnten die Pyrite in verschiedene genetische Typen klassifiziert und Beziehungen zur Isotopensignatur des Schwefels identifiziert werden.
    Type of Medium: Series available for loan
    Pages: 168 S. , Ill., graph. Darst., Kt.
    Series Statement: Karlsruher geochemische Hefte 2
    Language: German
    Note: Zugl.: Karlsruhe, Univ., Diss., 1992. , Inhaltsverzeichnis: 1 Einleitung. - 1.1 Zielsetzungen. - 1.2 Geologischer Rahmen. - 1.3 Das geologische Profil der Vorbohrung. - 1.4 Sulfidische Erzminerale in der Vorbohrung. - 2 Schwefelisotope in der Vorbohrung. - 2.1 Untersuchungsmethodik. - 2.1.1 Probennahme und Aufbereitung. - 2.1.1.1 Proben aus Bohrkern und Bohrklein. - 2.1.1.2 Spülungsproben. - 2.1.2 Messung der S-Isotopenverhältnisse. - 2.1.3 Bestimmung der S-und C-Gehalte. - 2.2 Ergebnisse. - 2.2.1 Das S-Isotopenprofil der Vorbohrung. - 2.2.2 Beziehungen zwischen S-Isotopenmuster und Geochemie der Paragneise. - 2.2.3 Schwefelisotope in fluiden Phasen. - 2.2.3.1 Tiefenwässer. - 2.2.3.2 Bohrspülung. - 2.3 Interpretation des Isotopenprofils. - 2.3.1 Fraktionierungsmechanismen der S-Isotope. - 2.3 .1.1 Thermodynamische Fraktionierung. - 2.3.1.2 Kinetische Fraktionierung. - 2.3.2 Relikte prämetamorpher Isotopenmuster. - 2.3.2.1 Sedimentäre Relikte. - 2.3.2.1.1 Fraktionierungsmechanismen in Sedimentgesteinen. - 2.3.2.1.2 Sedimentäre Pyritbildung. - 2.3.2.1.3 S/C-Verhältnisse in Paragneisen der Vorbohrung. - 2.3.2.1.4 Interpretation des S-Isotopenmusters der Paragneise. - 2.3.2.2 Magmatische Relikte. - 2.3.3 Die metamorphe Überprägung. - 2.3.3.1 Thermodynamische Fraktionierungsprozesse. - 2.3.3.1.1 Sulfid-Sulfid Systeme. - 2.3.3.1.2 Sulfid-Sulfat Systeme. - 2.3.3.2 Kinetische Fraktionierungsprozesse durch metamorphe Reaktionen. - 2.3.3.2.1 Thermische Dissoziation von Pyrit. - 2.3.3.2.2 Sulfurisation und Sulfid / Silikat-(/Oxid-)Reaktionen. - 2.3.3.2.3 Hydratation von Sulfiden. - 2.3.3.2.4 Sulfatreaktionen. - 2.3.3.2.4.1 Isomorpher SO4 2- Einbau. - 2.3.3.2.4.2 Nichtbakterielle Sulfatreduktion. - 2.3.4 Die postmetamorphe hydrothermale Überprägung. - 2.3.4.1 Die Isotopensignatur der hydrothermalen Mineralisation. - 2.3.4.2 S-Isotopenverhältnisse in hydrothermalen Fluiden. - 3 Spurenelementsystematik der Pyrite. - 3.1 Allgemeine Charakteristika der Spurenelemente in Pyriten. - 3.2 Untersuchungsmethodik. - 3.2.1 Bestimmungen im Pyrit (ICP-MS). - 3.2.2 Bestimmungen im Nebengestein (ED-RFA und INAA). - 3.3 Ergebnisse und Auswertung der Daten. - 3.3.1 Erscheinungsformen des Pyrits. - 3.3.2 Spurenelementmuster der Pyrite. - 3.3.2.1 Grundlagen der Faktoren- und Clusteranalyse. - 3.3.2.2 Die Auswertung der Meßergebnisse. - 3.3.2.3 Geochemie ausgewählter Spurenelemente. - 3.3.2.3.1 Kobalt und Nickel. - 3.3.2.3.2 Das S:Se-Verhältnis. - 3.3.2.3.3 Die Seltenen Erden. - 3.3.2.4 Beziehungen zwischen dem Spurenelementgehalt der Pyrite und dem der Nebengesteine. - 3.3.2.4.1 Anreicherungen. - 3.3.2.4.2 Korrelationen. - Zusammenfassung. - Literaturverzeichnis. - Anhang. - Tabelle 1 - Durchgeführte Analysen. - Tabelle 2 - Spurenelementgehalte der analysierten Pyritpräparate. - Tabelle 3- Schwefel, Kohlenstoff, Fe2O3- und Spurenelementgehalte im Nebengestein. - Tabelle 4 - Gehalte von Co, Cr, Sc, Sb, Th, U und SEE im Nebengestein (INA-Analysen). - Tabelle 5 - Vergleich zwischen den Soll- und Istwerten der Standardproben die mit den Pyritproben mitgemessen wurden (ICP-MS). - Tabelle 6 -Vergleich zwischen den Soll- und Istwerten der Standardproben die mit den Proben aus dem Nebengestein mitgemessen wurden (ED-RFA). - Fortran-Programm DELHYD.
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  • 2
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    (Table A1) Stable isotope ratios and paleotemperature calculation of selected planktonic foraminifera from late Campanian and Maastrichtian sediments of DSDP Hole 74-525A from the Walvis Ridge, South Atlantic
    PANGAEA
    Details
    Publication Date: 2023-06-27
    Keywords: 74-525A; Abathomphalus mayaroensis, δ13C; Abathomphalus mayaroensis, δ18O; Calculated from stable oxygen isotopes; Deep Sea Drilling Project; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP; DSDP/ODP/IODP sample designation; Globigerinelloides aff. ultramicrus, δ13C; Globigerinelloides aff. ultramicrus, δ18O; Globigerinelloides aspera, δ13C; Globigerinelloides aspera, δ18O; Globotruncana aegyptiaca, δ13C; Globotruncana aegyptiaca, δ18O; Globotruncana arca, δ13C; Globotruncana arca, δ18O; Globotruncana bulloides, δ13C; Globotruncana bulloides, δ18O; Globotruncana falsostuarti, δ13C; Globotruncana falsostuarti, δ18O; Globotruncana linneiana, δ13C; Globotruncana linneiana, δ18O; Globotruncana mariei, δ13C; Globotruncana mariei, δ18O; Globotruncanella havanensis, δ13C; Globotruncanella havanensis, δ18O; Globotruncanita stuarti, δ13C; Globotruncanita stuarti, δ18O; Globotruncanita stuartiformis, δ13C; Globotruncanita stuartiformis, δ18O; Glomar Challenger; Gublerina acuta, δ13C; Gublerina acuta, δ18O; Gublerina cuvillieri, δ13C; Heterohelix globulosa, δ13C; Heterohelix globulosa, δ18O; Heterohelix planata, δ13C; Heterohelix planata, δ18O; Heterohelix rajagopalani, δ13C; Heterohelix rajagopalani, δ18O; Isotope ratio mass spectrometry; Laeviheterohelix glabrans, δ13C; Laeviheterohelix glabrans, δ18O; Leg74; Planoglobulina acervulinoides, δ13C; Planoglobulina acervulinoides, δ18O; Planoglobulina brazoensis, δ13C; Planoglobulina brazoensis, δ18O; Planoglobulina carseyae, δ13C; Planoglobulina carseyae, δ18O; Pseudoguembelina costulata, δ13C; Pseudoguembelina costulata, δ18O; Pseudoguembelina hariaensis, δ13C; Pseudoguembelina hariaensis, δ18O; Pseudoguembelina palpebra, δ13C; Pseudoguembelina palpebra, δ18O; Pseudotextularia deformis, δ13C; Pseudotextularia deformis, δ18O; Pseudotextularia elegans, δ13C; Pseudotextularia elegans, δ18O; Racemiguembelina fructicosa, δ13C; Racemiguembelina fructicosa, δ18O; Racemiguembelina intermedia, δ13C; Racemiguembelina intermedia, δ18O; Racemiguembelina powelli, δ13C; Racemiguembelina powelli, δ18O; Rosita plummerae, δ13C; Rosita plummerae, δ18O; Rosita walfischensis, δ13C; Rosita walfischensis, δ18O; Rugoglobigerina hexacamerata, δ13C; Rugoglobigerina hexacamerata, δ18O; Rugoglobigerina pennyi, δ13C; Rugoglobigerina pennyi, δ18O; Rugoglobigerina rugosa, δ13C; Rugoglobigerina rugosa, δ18O; Sample code/label; South Atlantic/CREST; Temperature, calculated
    Type: Dataset
    Format: text/tab-separated-values, 204 data points
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  • 3
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    (Table A1) Stable isotope ratios and paleotemperature calculation of selected planktonic foraminifera from late Campanian and Maastrichtian sediments of DSDP Hole 86-577A from the Shatsky Rise, North Pacific
    PANGAEA
    Details
    Publication Date: 2023-06-27
    Keywords: 86-577A; Abathomphalus mayaroensis, δ13C; Abathomphalus mayaroensis, δ18O; Calculated from stable oxygen isotopes; Deep Sea Drilling Project; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP; DSDP/ODP/IODP sample designation; Globigerinelloides aspera, δ13C; Globigerinelloides aspera, δ18O; Globigerinelloides subcarinatus, δ13C; Globigerinelloides subcarinatus, δ18O; Globotruncana aegyptiaca, δ13C; Globotruncana aegyptiaca, δ18O; Globotruncana arca, δ13C; Globotruncana arca, δ18O; Globotruncana dupeublei, δ13C; Globotruncana dupeublei, δ18O; Globotruncana falsostuarti, δ13C; Globotruncana falsostuarti, δ18O; Globotruncana mariei, δ13C; Globotruncana mariei, δ18O; Globotruncana orientalis, δ13C; Globotruncana orientalis, δ18O; Globotruncana rosetta, δ13C; Globotruncana rosetta, δ18O; Globotruncana ventricosa, δ13C; Globotruncana ventricosa, δ18O; Globotruncanella havanensis, δ13C; Globotruncanella havanensis, δ18O; Globotruncanita angulata, δ13C; Globotruncanita angulata, δ18O; Globotruncanita stuarti, δ13C; Globotruncanita stuarti, δ18O; Globotruncanita stuartiformis, δ13C; Globotruncanita stuartiformis, δ18O; Glomar Challenger; Gublerina acuta, δ13C; Gublerina acuta, δ18O; Gublerina cuvillieri, δ13C; Gublerina cuvillieri, δ18O; Heterohelix globulosa, δ13C; Heterohelix globulosa, δ18O; Heterohelix labellosa, δ13C; Heterohelix labellosa, δ18O; Isotope ratio mass spectrometry; Leg86; North Pacific; Planoglobulina acervulinoides, δ13C; Planoglobulina acervulinoides, δ18O; Planoglobulina brazoensis, δ13C; Planoglobulina brazoensis, δ18O; Planoglobulina carseyae, δ13C; Planoglobulina carseyae, δ18O; Planoglobulina multicamerata, δ13C; Planoglobulina multicamerata, δ18O; Pseudoguembelina costulata, δ13C; Pseudoguembelina costulata, δ18O; Pseudoguembelina excolata, δ13C; Pseudoguembelina excolata, δ18O; Pseudoguembelina kempensis, δ13C; Pseudoguembelina kempensis, δ18O; Pseudoguembelina palpebra, δ13C; Pseudoguembelina palpebra, δ18O; Pseudotextularia deformis, δ13C; Pseudotextularia deformis, δ18O; Pseudotextularia elegans, δ13C; Pseudotextularia elegans, δ18O; Racemiguembelina fructicosa, δ13C; Racemiguembelina fructicosa, δ18O; Racemiguembelina intermedia, δ13C; Racemiguembelina intermedia, δ18O; Racemiguembelina powelli, δ13C; Racemiguembelina powelli, δ18O; Rosita patelliformis, δ13C; Rosita patelliformis, δ18O; Rosita walfischensis, δ13C; Rosita walfischensis, δ18O; Rugoglobigerina hexacamerata, δ13C; Rugoglobigerina hexacamerata, δ18O; Rugoglobigerina macrocephala, δ13C; Rugoglobigerina macrocephala, δ18O; Rugoglobigerina milamensis, δ13C; Rugoglobigerina milamensis, δ18O; Rugoglobigerina rotundata, δ13C; Rugoglobigerina rotundata, δ18O; Rugoglobigerina rugosa, δ13C; Rugoglobigerina rugosa, δ18O; Rugoglobigerina scotti, δ13C; Rugoglobigerina scotti, δ18O; Sample code/label; Temperature, calculated
    Type: Dataset
    Format: text/tab-separated-values, 186 data points
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  • 4
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    (Table 2) Estimated ages and plankronic foraminiferal biostratigraphy of the late Campanian and Maastrichtian section of DSDP Hole 62-463 from the Mid-Pacific mountains
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    Publication Date: 2023-06-27
    Keywords: 62-463; Age model; Comment; Deep Sea Drilling Project; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP; DSDP/ODP/IODP sample designation; Epoch; Glomar Challenger; Leg62; Nannofossil zone; North Pacific/SEAMOUNT; Sample code/label
    Type: Dataset
    Format: text/tab-separated-values, 22 data points
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  • 5
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    (Table 2) Estimated ages and plankronic foraminiferal biostratigraphy of the late Campanian and Maastrichtian section of DSDP Hole 74-525A from the Walvis Ridge, South Atlantic
    PANGAEA
    Details
    Publication Date: 2023-06-27
    Keywords: 74-525A; Age model; Comment; Deep Sea Drilling Project; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP; DSDP/ODP/IODP sample designation; Epoch; Glomar Challenger; Leg74; Nannofossil zone; Sample code/label; South Atlantic/CREST
    Type: Dataset
    Format: text/tab-separated-values, 21 data points
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  • 6
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    (Table 2) Estimated ages and plankronic foraminiferal biostratigraphy of the late Campanian and Maastrichtian section of DSDP Hole 86-577A from the Shatsky Rise, North Pacific
    PANGAEA
    Details
    Publication Date: 2023-06-27
    Keywords: 86-577A; Age, maximum/old; Age, minimum/young; Comment; Deep Sea Drilling Project; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP; DSDP/ODP/IODP sample designation; Epoch; Glomar Challenger; Leg86; Nannofossil zone; North Pacific; Sample code/label
    Type: Dataset
    Format: text/tab-separated-values, 10 data points
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  • 7
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    (Table A1) Stable isotope ratios and paleotemperature calculation of selected planktonic foraminifera from late Campanian and Maastrichtian sediments of DSDP Hole 62-463 from the Mid-Pacific mountains
    PANGAEA
    Details
    Publication Date: 2023-06-27
    Keywords: 62-463; Calculated from stable oxygen isotopes; Deep Sea Drilling Project; DEPTH, sediment/rock; DRILL; Drilling/drill rig; DSDP; DSDP/ODP/IODP sample designation; Gansserina gansseri, δ13C; Gansserina gansseri, δ18O; Globigerinelloides aff. ultramicrus, δ13C; Globigerinelloides aff. ultramicrus, δ18O; Globigerinelloides aspera, δ13C; Globigerinelloides aspera, δ18O; Globotruncana aegyptiaca, δ13C; Globotruncana aegyptiaca, δ18O; Globotruncana arca, δ13C; Globotruncana arca, δ18O; Globotruncana bulloides, δ13C; Globotruncana bulloides, δ18O; Globotruncana insignis, δ13C; Globotruncana insignis, δ18O; Globotruncana linneiana, δ13C; Globotruncana linneiana, δ18O; Globotruncana ventricosa, δ13C; Globotruncana ventricosa, δ18O; Globotruncanita angulata, δ13C; Globotruncanita angulata, δ18O; Globotruncanita calcarata, δ13C; Globotruncanita stuarti, δ13C; Globotruncanita stuarti, δ18O; Globotruncanita stuartiformis, δ13C; Globotruncanita stuartiformis, δ18O; Globotruncanita subspinosa, δ13C; Glomar Challenger; Gublerina acuta, δ13C; Gublerina acuta, δ18O; Heterohelix globulosa, δ13C; Heterohelix globulosa, δ18O; Heterohelix planata, δ13C; Heterohelix planata, δ18O; Heterohelix punctulata, δ13C; Heterohelix punctulata, δ18O; Isotope ratio mass spectrometry; Leg62; North Pacific/SEAMOUNT; Pseudoguembelina costulata, δ13C; Pseudoguembelina costulata, δ18O; Pseudoguembelina excolata, δ13C; Pseudoguembelina excolata, δ18O; Pseudoguembelina kempensis, δ13C; Pseudoguembelina kempensis, δ18O; Pseudotextularia deformis, δ13C; Pseudotextularia deformis, δ18O; Pseudotextularia elegans, δ13C; Pseudotextularia elegans, δ18O; Rosita fornicata, δ13C; Rosita fornicata, δ18O; Rosita plicata, δ13C; Rosita plicata, δ18O; Rosita plummerae, δ13C; Rosita plummerae, δ18O; Rosita walfischensis, δ13C; Rosita walfischensis, δ18O; Rugoglobigerina hexacamerata, δ13C; Rugoglobigerina hexacamerata, δ18O; Rugoglobigerina macrocephala, δ13C; Rugoglobigerina macrocephala, δ18O; Rugoglobigerina rugosa, δ13C; Rugoglobigerina rugosa, δ18O; Sample code/label; Temperature, calculated
    Type: Dataset
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  • 8
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    Characterization of late Campanian and Maastrichtian planktonic foraminiferal depth habitats and vital activities based on stable isotopes
    PANGAEA
    In:  Supplement to: Abramovich, Sigal; Keller, Gerta; Stüben, Doris; Berner, Zsolt (2003): Characterization of late Campanian and Maastrichtian planktonic foraminiferal depth habitats and vital activities based on stable isotopes. Palaeogeography, Palaeoclimatology, Palaeoecology, 202(1-2), 1-29, https://doi.org/10.1016/S0031-0182(03)00572-8
    Details
    Publication Date: 2023-06-27
    Description: Depth habitats of 56 late Cretaceous planktonic foraminiferal species from cool and warm climate modes were determined based on stable isotope analyses of deep-sea samples from the equatorial Pacific DSDP Sites 577A and 463, and South Atlantic DSDP Site 525A. The following conclusions can be reached: Planoglobulina multicamerata (De Klasz) and Heterohelix rajagopalani (Govindan) occupied the deepest plankton habitats, followed by Abathomphalus mayaroensis (Bolli), Globotruncanella havanensis (Voorwijk), Gublerina cuvillieri Kikoine, and Laeviheterohelix glabrans (Cushman) also at subthermocline depth. Most keeled globotruncanids, and possibly Globigerinelliodes and Racemiguembelina species, lived at or within the thermocline layer. Heterohelix globulosa (Ehrenberg) and Rugoglobigerina, Pseudotextularia and Planoglobulina occupied the subsurface depth of the mixed layer, and Pseudoguembelina species inhabited the surface mixed layer. However, depth ranking of some species varied depending on warm or cool climate modes, and late Campanian or Maastrichtian age. For example, most keeled globotruncanids occupied similar shallow subsurface habitats as Rugoglobigerina during the warm late Campanian, but occupied the deeper thermocline layer during cool climatic intervals. Two distinct types of „vital effect“ mechanisms reflecting photosymbiosis and respiration effects can be recognized by the exceptional delta13C signals of some species. (1) Photosymbiosis is implied by the repetitive pattern of relatively enriched delta13C values of Racemiguembelina (strongest), Planoglobulina, Rosita and Rugoglobigerina species, Pseudoguembelina excolata (weakest). (2) Enriched respiration 12C products are recognized in A. mayaroensis, Gublerina acuta De Klasz, and Heterohelix planata (Cushman). Isotopic trends between samples suggest that photosymbiotic activities varied between localities or during different climate modes, and may have ceased under certain environmental conditions. The appearance of most photosymbiotic species in the late Maastrichtian suggests oligotrophic conditions associated with increased water-mass stratification.
    Keywords: 62-463; 74-525A; 86-577A; Deep Sea Drilling Project; DRILL; Drilling/drill rig; DSDP; Glomar Challenger; Leg62; Leg74; Leg86; North Pacific; North Pacific/SEAMOUNT; South Atlantic/CREST
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    Format: application/zip, 6 datasets
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  • 9
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    (Table S2) Characteristics of analysed apatite grains from rapidly cooled samples (2009)
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    Details
    Publication Date: 2024-01-09
    Keywords: 121-755A; 129-800A; 43-386; 47-397; AGE; Age, standard deviation; Area/locality; Chlorine; Deep Sea Drilling Project; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; Description; Description 2 (continued); DRILL; Drilling/drill rig; DSDP; DSDP/ODP/IODP sample designation; Elevation of event; Epoch; Event label; Glomar Challenger; Joides Resolution; Latitude of event; Leg121; Leg129; Leg43; Leg47; Lithology/composition/facies; Longitude of event; North Atlantic/CONT RISE; North Pacific Ocean; Ocean Drilling Program; ODP; Samarium/Uranium ratio; Sample code/label; Sample code/label 2; Sample ID; South Indian Ridge, South Indian Ocean; Thorium/Uranium ratio; Uranium
    Type: Dataset
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  • 10
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    (Table 2) U, Th, and Sm of apatite from rapidly cooled samples (2009)
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    Publication Date: 2024-02-02
    Keywords: 121-755A; 129-800A; 43-386; 47-397; AGE; Age, dated; Age, dated standard deviation; Age, standard deviation; Area/locality; Deep Sea Drilling Project; Depth, bottom/max; DEPTH, sediment/rock; Depth, top/min; DRILL; Drilling/drill rig; DSDP; DSDP/ODP/IODP sample designation; Elevation of event; Epoch; Event label; Factor; Glomar Challenger; Grain size, mean radius; Helium-4; Identification; Joides Resolution; Latitude of event; Leg121; Leg129; Leg43; Leg47; Lithology/composition/facies; Longitude of event; Mass; North Atlantic/CONT RISE; North Pacific Ocean; Ocean Drilling Program; ODP; Samarium; Sample amount; Sample code/label; Sample code/label 2; Sample comment; Sample ID; South Indian Ridge, South Indian Ocean; Standard deviation; Thorium; Thorium/Uranium ratio; Uranium; Uranium, effective
    Type: Dataset
    Format: text/tab-separated-values, 1832 data points
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