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  • 1
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    PANGAEA
    In:  Supplement to: Partin, C A; Bekker, A; Planavsky, Noah J; Lyons, Timothy W (2015): Euxinic conditions recorded in the ca. 1.93Ga Bravo Lake Formation, Nunavut (Canada): Implications for oceanic redox evolution. Chemical Geology, 417, 148-162, https://doi.org/10.1016/j.chemgeo.2015.09.004
    Publication Date: 2024-02-16
    Description: The composition of seawater changed dramatically during the initial rise of atmospheric oxygen in the earliest Paleoproterozoic, but the emerging view is that atmosphere-ocean system did not experience an irreversible transition to a well-oxygenated state. Instead, it has been suggested that the oxygen content of the atmosphere-ocean system decreased considerably after ca. 2.06 billion years ago (Ga), which resulted in a crash in marine sulfate concentrations. The end of the deposition of major granular iron formations at ca. 1.85 Ga has been linked either to the development of extensive euxinic conditions along continental shelves or a decrease in hydrothermal flux. The record of oceanic redox state is not well constrained for the period between ca. 2.06 Ga, the end of the Lomagundi positive carbon isotope excursion, and ca. 1.88 Ga when major granular iron formations appeared. We address this gap by presenting new iron-speciation, major and trace element data, as well as sulfur, organic carbon, and molybdenum isotopic data for greenschist facies organic matter-rich mudrocks (ORMs) of the ca. 1.93 Ga Bravo Lake Formation, Piling Group, Baffin Island. The iron speciation data suggest deposition of the Bravo Lake Formation under a euxinic (anoxic and sulfidic) water column. Trace metal enrichments and Mo isotope data suggest extensive marine euxinia ca. 90 million years before the disappearance of large-scale, economic granular iron formations. The addition of new Mo data in this time interval is important, as it contributes to filling in the sparse Proterozoic record. Lastly, this work provides further support for the idea that there was widespread anoxia shortly after the end of the Lomagundi Event.
    Type: Dataset
    Format: application/zip, 3 datasets
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  • 2
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Free Radical Biology and Medicine 9 (1990), S. 124 
    ISSN: 0891-5849
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology , Medicine
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [s.l.] : Macmillian Magazines Ltd.
    Nature 427 (2004), S. 117-120 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Several lines of geological and geochemical evidence indicate that the level of atmospheric oxygen was extremely low before 2.45 billion years (Gyr) ago, and that it had reached considerable levels by 2.22 Gyr ago. Here we present evidence that the rise of atmospheric oxygen had occurred by ...
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1573-0867
    Keywords: crop response ; leaching ; liming ; nonexchangeable potassium ; nutrient retention
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Effects of coralline lime and leaching on dry matter production and nutrient uptake by maize (Zea mays) were studied in 21 cm deep leaching columns/pots filled with an Oxic Inceptisol (12 kg) from Alafua, Western Samoa. Ground (〈0.25mm) coralline material containing approximately 80% CaCO3 was used as lime. There were 12 treatments, factorially arranged: 4 liming rates (0, 10.5, 21.0 and 31.5 g pot−1) which were applied to the top 5 cm of the pots, and 3 K applications (0, 0.69 1.38 g pot−1) which were applied after the initial leaching period of 10 days (3 1 pot−1 day−1) following the lime applications. Leaching continued for 15 more days, using 1 1 pot−1 day−1, after K fertilizations. During the initial leaching period, liming intensified K losses. The applied Ca-ions displaced the exchangeable K which was subsequently leached out of the pots. During the second leaching period, liming increased K retention only when K concentrations in the soil were high (treatment receiving 1.38 g K pot−1). These effects of liming and leaching on K retention were not detectable in the nutrient uptake of maize grown for 50 days after the second leaching period. This may have been because the leaching losses made up only approximately 2 % of the K-turnover in the pots. A calculated nutrient balance for the pots showed that a large portion of K taken up by maize came out of a pool of nonexchangeable K. The Alafua soil had 0.45 % (11.5 cmol(+)kg−1) total-K, indicating a relatively large K reserve. Since mineralogical studies failed to detect the presence of any known 2:1 minerals, the K reserve of the Alafua soil might be located in amorphous material.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1573-5036
    Keywords: Ca deficiency ; critical Ca level ; crop response ; liming ; Mn toxicity nutrient interaction
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Effects of coralline lime, in combination with 3 kg Cu ha−1 plus 3 kg Zn ha−1, on yield and nutrient uptake by peanut (Arachis hypogea) were studied at three locations in Western Samoa. Coarse (0–10 mm) coralline lime material containing 31.1% Ca and 1.7% Mg was used as lime at 0, 555, 2222 and 5000 kg ha−1. In the Togitogiga soil, which had the lowest level of exchangeable Ca, peanut yield increased by 6 fold after liming with 555 kg ha−1, relative to the unamended control. This yield increase was associated with reduced Mn toxicity as well as reduced Ca deficiency. The alleviation of Mn toxicity was not likely due to decreased Mn solubility because the lime application (555 kg ha−1) increased soil pH by 〈0.1 unit. Rather it was the increased Ca availability which reduced the Mn toxicity through a Ca/Mn antagonism. The critical range of exchangeable Ca for peanut growth was found to be about 1.5–1.6 cmol 1/2Ca2+ kg−1. A Ca/Mn-ratio 〉80 was required for a desirable Ca/Mn balance in peanut tissue. On the other two locations (with exchangeable Ca levels of 1.5–1.6 cmol 1/2Ca2+ kg−1), liming increased peanut yields by 15–20%. Additions of Cu plus Zn also increased the yields, although the increases were small (7%) and not significant at the 95% probability level.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Nutrient cycling in agroecosystems 36 (1993), S. 211-219 
    ISSN: 1573-0867
    Keywords: banding ; broadcasting ; Ca deficiency ; crop response ; liming ; Mn toxicity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Effects of coralline lime on yield and nutrient uptake by sweet corn (Zea mays saccharata Sturt.) and peanut (Arachis hypogea) were studied at three locations in Western Samoa. Coarse (0-10 mm) coralline material containing 31.1% Ca and 1.67% Mg was used as lime. There were two modes of application: band and broadcast, and three rates: 6, 12 and 18 ton ha−1. In the highest rainfall location, marketable yields were increased by 250% for peanut and 160% for sweet corn by liming at 6 ton ha−1, relative to the unamended control. Peanut yield increases were associated with reduced Mn toxicity and/or with Ca and Mg deficiency. Sweet corn was less susceptible to Mn toxicity, but more responsive to exchangeable Ca. The critical level of exchangeable Ca was found to be about 2.0 cmol(+)kg−1. Applying lime to a band of 0.25-m wide did not reduce yield relative to broadcast. Soil cultivation caused the lime to spread over a wider band, diluting the applied calcium with a larger soil volume, suggesting that less than 6 ton ha−1 broadcast coarse coralline lime could still be adequate for most Samoan soils.
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  • 7
    ISSN: 1573-9171
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Conclusions 1. The PMR spectra of ketocyanines and diene-δ-aminoketones are not very sensitive to a change in the π-electron structure of the polymethine chain as a function of the type of solvent and temperature. 2. The difference in the chemical shifts of the neighboring C atoms in the polymethine chain (Δδ) in the13C NMR spectra of the ketocyanines can serve as a criterion of the approach of the structure of the ketocyanine to an intraionic structure (the values of Δδ are maximum for the corresponding polymethine salt). 3. The thermochromic shift of the absorption spectra of solutions of ketocyanines on cooling and the solvatochromic shift with an increase in the solvating capacity of the solvent are determined by an increase in the contribution of the intraionic structure to the electronic structure of the ketocyanine.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Chemistry of natural compounds 22 (1987), S. 476-477 
    ISSN: 1573-8388
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
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  • 9
    ISSN: 1573-9031
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1573-9031
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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