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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Biology and fertility of soils 18 (1994), S. 1-6 
    ISSN: 1432-0789
    Keywords: Ammonium ; Denitrification ; Nitrification ; Nitrous oxide ; Organic carbon ; Acetylene
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract We observed that soil cores collected in the field containing relatively high NH inf4 sup+ and C substrate levels produced relatively large quantities of N2O. A series of laboratory experiments confirmed that the addition of NH inf4 sup+ and glucose to soil increase N2O production under aerobic conditions. Denitrifying enzyme activity was also increased by the addition of NH inf4 sup+ and glucose. Furthermore, NH inf4 sup+ and glocose additions increased the production of N2O in the presence of C2H2. Therefore, we concluded that denitrification was the most likely source of N2O production. Denitrification was not, however, directly affected by NH inf4 sup+ in anaerobic soil slurries, although the use of C substrate increased. In the presence of a high substrate C concentration, N2O production by denitrifiers may be affected by NO inf3 sup- supplied from NH inf4 sup+ through nitrification. Alternatively, N2O may be produced during mixotrophic and heterotrophic growth of nitrifiers. The results indicated that the NH inf4 sup+ concentration, in addition to NO inf3 sup- , C substrate, and O2 concentrations, is important for predicting N2O production and denitrification under field conditions.
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Biology and fertility of soils 7 (1989), S. 303-309 
    ISSN: 1432-0789
    Keywords: Volatile fatty acids ; Water-soluble C ; Nitrate ; Nitrite ; Fermentative nitrate reduction
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Nitrous oxide production (denitrification) during anaerobic incubation of ground-alfalfa-, red-clover-, wheat-straw-, and cornstover-amended soil was positively related to the initial water-soluble C content of the residue- amended soil. The water-soluble C concentration decreased in all treatments during the first 2 days, then increased in the alfalfa-, red-clover-, and wheat-straw-amended soil until the end of the experiment at 15 days. An accumulation of acetate, propionate, and butyrate was partly responsible for the increased water-soluble C concentration. Denitrification rates were much higher in the alfalfa-and red-clover-amended soil, but NO 3 − was not fully recovered as N2O in these treatments. Supported by earlier experiments in our laboratory, we conclude that some of the NO 3 − was reduced to NH 4 + through fermentative NO 3 − reduction, otherwise known as dissimilatory NO 3 − reduction to NH 4 + . Acetate, the primary product of anaerobic fermentation, accumulated in the alfalfa- and red-clover-amended soil in the presence of NO 3 − , supporting previous observations that the processes of denitrification and fermentation occur simultaneously in C-amended soil. The partitioning of NO 3 − between denitrification and fermentative NO 3 − reduction to NH 4 + depends on the activity of the denitrifying and fermentative bacterial populations. NO2 concentration may be a key in the partitioning of NO 3 − between these two processes.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Biology and fertility of soils 10 (1990), S. 188-193 
    ISSN: 1432-0789
    Keywords: Denitrification ; Dry-sieved ; Wet-sieved ; Aggregates ; Carbon availability ; Water-soluble carbon
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The spatial variability of denitrification in soil was studied further by comparing dry-sieved and wetsieved aggregates of different sizes. It was observed that the denitrification rate generally decreased as the drysieved aggregate size increased. In contrast, the denitrification rate increased as the wet-sieved aggregate size increased. In both cases, however, the denitrification rate was positively related to aerobically mineralizable C. Oven-warming of the wet-sieved aggregates at 105°C for 30 min increased the denitrification rate, apparently due to the release of C substrate. Nevertheless, the positive relationship between the denitrification rate and the wetsieved aggregate size persisted. There was no clear relationship between water-soluble C and the denitrification rate. There may have been a contribution from C in microbial polysaccharides in aggregates of different sizes. The results demonstrated that there was a large spatial variability in denitrification over short distances in soil, which was associated with aggregates of different sizes and water stability.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Biology and fertility of soils 12 (1991), S. 195-198 
    ISSN: 1432-0789
    Keywords: Supercooled unfrozen soil ; Acetate ; Propionate ; Butyrate ; Glucose ; Alfalfa
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary A laboratory study was done to determine how, if at all, temperatures affect the production of volatile fatty acids and the rate of denitrification in soil. Glucose and alfalfa were compared as C substrates at temperatures of -2, 10, and 25°C under anaerobic conditions. At -2°C (soil not frozen), the denitrification rate was slow but was as rapid with alfalfa as glucose. This indicated that the production of volatile fatty acids by fermenters or other C substrates from alfalfa were adequate to sustain denitrifiers. No volatile fatty acids were apparently produced with glucose at -2°C whereas acetate and propionate were produced with alfalfa during the 26-day incubation period. During the 8-day incubation period at 10°C, there were also greater accumulations of acetate and propionate with alfalfa than with glucose. At 25°C, there was no major difference in the denitrification rate between glucose and alfalfa over a 4-day period. In a contrast to the other temperatures, more butyrate than propionate was produced at 25°C, especially with alfalfa. Acetate was the dominant volatile fatty acid produced and generally increased with temperature, especially after NO3 exhaustion at 10 and 25°C. This indicated that acetate was a source of C for denitrifiers.
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Biology and fertility of soils 1 (1985), S. 183-187 
    ISSN: 1432-0789
    Keywords: Denitrification rates ; Carbon substrate ; N2O production ; Water-extractable carbon
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary Soil was amended with a variety of carbon sources, including four soluble compounds (glucose, sucrose, glycerol and mannitol) and two plant residues (straw and alfalfa).. Potential denitrification rates, measured both as N2O accumulation and NO3 − disappearance, were compared, and the predicted values of available C, measured as CO2 production and water-extractable C, were assessed. The two measures of denitrification agreed well although N2O accumulation was, found to be most sensitive. Soil treated with the four soluble C compounds resulted in the same rate of denitrification although glycerol was not as rapidly oxidized. Alfalfa-amended soil produced a significantly higher rate of denitrification than the same amount of added straw. CO2 evolution was found to be a good predictor of denitrification over the first 2 days of sampling, but neither measure of available substrate C correlated well with denitrification rate beyond 4 days, when NO3 − was depleted in most treatments. The data with alfalfa-amended soil suggested that denitrifiers used water-extractable C. materials produced by other organisms under anaerobic conditions.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 21 (1986), S. 1963-1966 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The fracture toughness of Ocala chert, as measured with short rod specimens and with the microhardness indenter, decreases to 60% of its original value as a result of heat treatment to 500° C while the elastic modulus increases 22%. The change in fracture toughness is associated with a transition from crack propagation around particles in the porous boundaries of densely packed zones in the chert to propagation through the zones. The transition is related to an increase in particle/particle bonding within the porous boundaries. Consolidation of a silica gel in the boundary regions, which resulted in a loss of water of 1.12% by weight, is apparently responsible for the increased bonding.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Nutrient cycling in agroecosystems 18 (1988), S. 201-212 
    ISSN: 1573-0867
    Keywords: Dicyandiamide ; large urea granule ; urea hydrolysis ; nitrite accumulation ; liming ; nitrification inhibitor
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract A laboratory incubation experiment was conducted to gain a better understanding of N transformations which occur near large urea granules in soil and the effects of dicyandiamide (DCD), nitrifier activity and liming. Soil cores containing a layer of urea were used to provide a one-dimensional approach and to facilitate sampling. A uniform layer of 2 g urea or urea + DCD was placed in the centre of a 20 cm-long soil core within PVC tubing. DCD was mixed with urea powder at 50 mg kg−1 urea and enrichment of soil with nitrifiers was accomplished by preincubating Conestogo silt loam with 50 mg NH 4 + -N kg−1 soil. Brookston clay (pH 5.7) was limited with CaCO3 to increase the pH to 7.3. The cores were incubated at 15°C and, after periods of 10, 20, 35 and 45 days, were separated into 1-cm sections. The distribution of N species was similar on each side of the urea layer at each sampling. The pH and NH 4 + (NH3) concentration were very high near the urea layer but decreased sharply with distance from it. DCD did not influence urea hydrolysis significantly. Liming of Brookston clay increased urea hydrolysis. The rate of urea hydrolysis was greater in Conestogo silt loam than limed Brookston clay. Nitrite accumulate was relatively small with all the treatments and occurred near the urea layer (0–4 cm) where pH and NH 4 + (NH3) concentration were high. The nitrification occurred in the zone where NH 4 + (NH3) concentration was below 1000µgN g−1 and soil pH was below 8.0 and 8.7 in Brookston and Conestogo soils, respectively. DCD reduced the nitrifier activity (NA) in soil thereby markedly inhibiting nitrification of NH 4 + . Nitrification was increased significantly with liming of the Brookston soil or nitrifier enrichment of the Conestogo soil. There was a significant increase in NA during the nitrification of urea-N. The (NO 2 − + NO 3 − )-N concentration peaks coincided with the NA peaks in the soil cores. A practical implication of this work is that large urea granules will not necessarily result in NO 2 − phytotoxicity when applied near plants. A placement depth of about 5 cm below the soil surface may preclude NH3 loss from large urea granules. DCD is a potential nitrification inhibitor for use with large urea granules or small urea granules placed in nests.
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  • 8
    ISSN: 1573-0867
    Keywords: Band placement ; barley ; cereal grains ; fall-applied N ; fertilizer efficiency ; large urea granules ; LUG ; method of placement ; nest placement ; nitrification ; time of application ; urea fertilizer ; wheat
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract In North America where the climate is cool enough only one crop is grown yearly, N fertilizers are sometimes applied in the previous fall rather than in the spring for fall- or spring-sown cereal grains. However, in areas where snow accumulates in winter, fall application of N fertilizers is generally inferior to spring application. Substantial nitrification takes place in winter and subsequent N loss occurs primarily in early spring by denitrification after the snow melt. Immobilization of N is also greater with fall- than spring-applied N fertilizers. Nitrogen is more efficiently retained in the soil as NH4 and thus more effectively used by plants if formation of nitrite (NO2) and NO3 is reduced or prevented by inhibiting nitrification. The nitrification is reduced when urea is placed in bands, because of high pH, ammonia concentration and osmotic pressure in the soil. The rate of nitrification is further reduced when urea is placed in widely-spaced nests (a number of urea prills placed together at a point below the soil surface) or as large urea granules (LUG) by reducing contact between the nitrifying bacteria and the NH4 released upon urea hydrolysis. A further reduction in nitrification from LUG can be obtained by addition of chemical nitrification inhibitors (such as dicyandiamide (DCD)) to LUG. The concentration of a chemical inhibitor required to suppress nitrification decreases with increasing granule size. The small soil-fertilizer interaction zone with placement of urea in nests or as LUG also reduces immobilization of fertilizer N, especially in soils amended with crop residues. The efficiency of fall-applied N is improved greatly by placing urea in nests or as LUG for small cereal grains. Yields of spring-sown barley from nests of urea or LUG applied in the fall are close to those obtained with spring-applied urea prills incorporated into the soil. Delaying urea application until close to freeze-up is also improved the efficiency of fall-applied N. This increased effectiveness of urea nests or LUG is due to slower nitrification, lower N loss over the winter by denitrification, and reduced immobilization of applied N. Fall application of LUG containing low rates of DCD slows nitrification, reduces over-winter N loss, and causes further improvement in yield and N uptake of winter wheat compared to urea as LUG alone in experiments in Ontario; in other experiments in Alberta there is no yield advantage from using a nitrification inhibitor with LUG for barley. Placement of LUG or nests of urea in soil is an agronomically sound practice for reducing N losses. This practice can eliminate or reduce the amount of nitrification inhibitor necessary to improve the efficiency of fall-applied urea where losses of mineral N are a problem. The optimum size of urea nest or LUG, and optimum combination of LUG and an efficient nitrification inhibitor need to be determined for different crops under different agroclimatic conditions. The soil (texture, CEC, N status), plant (winter or spring crop, crop geometry, crop growth duration and cultivar) and climatic (temperature, amount and distribution of precipitation) factors should be taken into account during field evaluation of LUG. There is a need to conduct region-specific basic research to understand mechanisms and magnitudes of N transformations and N losses in a given ecosystem. Prediction of nitrification from LUG or urea nests in various environments is needed. In nitrification inhibition studies with LUG and chemical nitrification inhibitors, measurements of nitrifier activity will be useful. Finally, there is need for development of applicators for mechanical placement of LUG or urea prills in widely-spaced nests in soil.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of agricultural and environmental ethics 3 (1990), S. 89-98 
    ISSN: 1573-322X
    Keywords: domestic animals ; soil productivity ; crop rotations ; manures ; desertification
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Philosophy
    Notes: Abstract Domestic livestock animals and soils must be considered together as part of an agroecosystem which includes plants. Soil sustainability may be simply defined as the maintenance of soil productivity for future generations. There are both positive and negative aspects concerning the role of animals in soil sustainability. In a positive sense, agroecosystems which include ruminant animals often also include hay forage-or pasture-based crops in the humid regions. Such crops stabilize the soil by decreasing erosion, improving soil structure and usually require fewer chemical inputs. Monogastric animal culture is based on an agroecosystem consisting of mainly grain crops. These crops can result in the soil being exposed to water and wind erosion although soil conservation practices that significantly reduce soil losses may be followed. The management of animal manures is not always compatible with soil conservation practices. Careful management of the nutrients in manure is absolutely necessary to avoid nitrate contamination of ground water or phosphorus loading of streams and lakes. In a negative sense, increases in animal livestock populations in association with human population growth are promoting desertification in the arid and semi-arid regions of the world. The key component for a fully compatible and acceptable association between domestic animals and soil productivity is proper management. Careful management of the components of an animal-based agroecosystem is required if soil productivity and environmental quality are to be maintained. Although we have much to learn, technologies are available to move a considerable way towards this ideal state.
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  • 10
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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