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  • 1
    Electronic Resource
    Electronic Resource
    Autocatalysis and bistability in the reaction between nitric acid and thiocyanate (1985)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 601-612 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The reaction between nitric acid and thiocyanate has been studied both in batch and flow configurations. The batch reaction is autocatalytic with an induction period which is decreased by the addition of HNO2. At the nitric acid concentrations employed (1-10 M), a red NOSCNH+ intermediate is formed. The reaction in a flow reactor exhibits bistability. A model involving competitive reactions of SCN- and NOSCNH+ with NO2 is suggested, and computer simulations with this model give good agreement with both the batch and flow experiments.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550170606
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