ISSN:
0009-2940
Keywords:
Photosynthesis models
;
Photoinduced electron transfer
;
Porphyrin-quinone cyclophanes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
To study the structure dependence of photoinduced electron transfer between porphyrins and quinones the concept of a new family of porphyrin-quinone cyclophanes with vertical arrangements of porphyrin and quinone units is presented. The syntheses of the quinone-porphyrin-quinone cyclophane 1, the prototype of this series, and of the quinone-porphyrindonor cyclophanes 12 and 14 are described. Spectroscopic data are discussed with regard to the structures involved and in relation to electron-transfer reactions occurring in these systems.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19921251016
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