ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary X-ray photoelectron spectra for MgUO4−x, MgU3O8.9, CaUO4−x, Ca2UO5, Ca3UO6, Ca2U3O11, CaU2O7, CaU4O12, SrUO4, SrUO3.67, Sr2U3O11, SrU4O12.8, Sr2UO5, Sr3UO6, BaUO4, Ba3UO6, BaU2O7, Ba2U2O7 and Ba2U3O11 have been recorded. Recorded O(1s) peak positions range from 529.5 to 533.4 eV and certain trends can be related to data obtained from other studies. By contrast, the range of U(4f) peak positions is much smaller totalling 0.7 eV. All compounds show satellite structure to the high binding energy side of the U(4f) peaks. Satellites separated byca. 10 eV from the main peaks are assigned to a transition from the uranium-oxygen bonding band to the U(6d) conduction band.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01393553
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