ISSN:
1434-1948
Keywords:
Thermochemistry
;
Alkaline-Earth Alkoxides
;
Enthalpy of Formation
;
Calcium
;
Magnesium
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The enthalpies of formation of some alkaline-earth alkoxides were determined by reaction-solution calorimetry (ΔfHo[Mg(OMe)2] = -792.6±1.2 kJ/mol; ΔfHo[Mg(OEt)2] = -847.9±2.7 kJ/mol; ΔfHo[Ca(OMe)2] = -890.8±6.4 kJ/mol; ΔfHo[Ca(OEt)2] = -924.5±2.6 kJ/mol; ΔfHo[Ca(OBu)2] =-989.8±5.4 kJ/mol) and allowed us to extend a previously developed model for predicting the enthalpies of formation of Be, Sr and Ba alkoxides.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
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