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  • 1
    Publication Date: 2024-02-12
    Description: Spinifex-textured olivine plates hosted in sulfides are usually named “interspinifex ore” in komatiite-hosted sulfide deposits. This ore type is rare but provides important genetic information on sulfide deposits, komatiite volcanology and thermomechanical erosion processes. Occurrences in Victor South-McLeay and Moran South (Kambalda, Western Australia) differ significantly from previously reported occurrences in their stratigraphic location, position within the ore profile and textural appearance. Thus, their formation process has to be reconsidered. Interspinifex ore reported here is situated in the lower portion of the basal lava flow between massive and net-textured sulfides in the centre of the embayment and between massive sulfides and older basalt in a “pinchout” where the sulfides melted sideways into older basalt on the embayment edge. Interspinifex ore is composed of up to 10-cm-long aggregates of parallel plates in the upper portion of massive sulfides and is overlain by barren komatiite. The texture does not allow for a classic single explanation. Thus, two possible formation mechanisms are envisaged: (1) A younger komatiite melt intrudes into its own olivine and sulfide liquid cumulate pile, while the sulfides are still liquid. The injection on top of the sulfides causes the formation of an emulsion, from which the spinifex forms due to the temperature gradient between the melts. (2) Interspinifex ore is a relic of an early komatiite flow formed in a series of successive pulses of komatiite and sulfide liquid. The spinifex of the komatiite is invaded by a younger batch of sulfide liquid replacing interstitial silicate melt.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Keywords: ddc:549 ; Interspinifex ore ; Kambalda ; Komatiite-hosted Ni sulfide deposit ; Emulsion ; Sulfide infiltration
    Language: English
    Type: doc-type:article
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 105 (1990), S. 704-714 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Spinifex-textured komatiites at Honeymoon Well, Western Australia, show evidence of partial melting and recrystallization of original igneous textures. Their textures and mineral compositions differ markedly from those typical of komatiites. Spinifex olivine plates are bent and broken, while interstitial space between spinifex and cumulus olivine is occupied by polygonal aggregates of clinopyroxene, orthopyroxene, minor olivine and plagioclase. Similar granular pyroxene-plagioclase aggregates occur as diffuse veins cutting spinifex zones and cumulate zones of the flows and, in places, form the matrix to a breccia containing corroded fragments of spinifex rock. Thermometry based on the two pyroxene assemblages yields temperatures of 1055° to 1141° C, just below the low-pressure komatiite solidus. Mineral compositions are different from those of typical komatiites: clinopyroxenes are Al-poor and Cr-rich, olivines are unusually iron-rich and depleted in Cr and Ca, and the low-Ca pyroxene is bronzite rather than the more typical pigeonite. We interpret these observations as the results of thermal metamorphism, partial remelting and subsequent slow crystallization of originally normal spinifex-textured komatiite flows. The rocks in question occupy a 40–70 m interval sandwiched between two olivine-rich units: an underlying 90 m-thick olivine adcumulate layer, forming part of the cumulate zone of a basal 160 m-thick flow, and an overlying 1 km-thick extrusive body composed mostly of olivine mesocumulate and adcumulate and capped in turn by spinifex-textured flows. Thermal modelling shows that a sinusoidal temperature profile of cool flow tops and hot flow centres would exist within this sequence shortly after eruption. Conductive thermal relaxation of this profile could reheat spinifex zones to the extent of inducing partial melting and textural reconstitution. Such reheating is largely dependent on the time interval between the emplacement of successive flows. Calculations suggest that at Honeymoon Well the emplacement interval must have been of the order of 10 years or less. Textural reconstitution may have contributed to the development of the thick orthocumulate sequences characteristic of komatiites in the Agnew-Wiluna belt.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 101 (1989), S. 447-457 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Three distinct categories of magmas — Bushveld “U-type” parent magmas, boninites, and siliceous high magnesium basalts from Archaean greenstone belts —share the distictive geochemical characteristics of high MgO (9%–19%), low TiO2(less than 1%) and high SiO2(greater than 52%). Boninites are generally thought to form by hydrous melting of metasomatized, previously depleted upper mantle, while siliceous high magnesium basalts (SHMB) in greenstone belts have recently been recognized as the products of combined fractionation and crustal contamination of komatiites. Both these mechanisms can apparently give rise to similar end products, and both mechanisms have been proposed for the petrogenesis of Bushveld U-type magmas. A detailed comparison of the three magma types, using data drawn from the literature, shows a broad area of overlap in major elements and most trace elements. U-type magmas are generally intermediate in composition between SHMB and boninites. U-type magmas differ significantly from boninites, and are more similar to SHMB, in three important respects: their relatively high abundances of rare earth elements and degree of light rare earth enrichment; higher FeO/MgO ratio for a given MgO content; and Sm/Nd isotopic systematics indicative of crustal contamination. BU magmas are therefore more likely to be extreme examples of contaminated komatiitic parents than primary “boninitic” mantle melts. The striking similarity in major element chemistry of the three groups may be due to the near-coincidence in compositional space of the mediumpressure, hydrous olivine-orthopyroxene phase boundary, which controls the composition of boninites, with the lowpressure anhydrous phase boundary which controls differentiated SHMB and U-type magmas.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 93 (1986), S. 524-531 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract A series of calculations have been carried out to evaluate the effect on cumulus mineral compositions of solidification of trapped intercumulus liquid in orthocumulates. The calculation assumes local equilibrium between phases, and that the system remains chemically closed during crystallization of the trapped liquid. The latter assumption is held to be valid on a scale of tens to hundreds of centimeters. It is not necessary to know the composition of the trapped liquid, as the calculation only requires an estimate of FeO content and trapping temperature. The change in composition of a mineral from that of the initially precipitated cumulus crystals to the final composition after complete solidification is termed the “trapped liquid shift”. Its magnitude depends on the modal proportions of cumulus phases and the initial porosity, and is only weakly dependent on initial phase compositions. Trapped liquid shifts are significant when compared with mineral composition changes occurring during fractional crystallization. Crystallization of 30% trapped liquid gives rise to shifts of up to 10 mol. percent in Mg number of olivine or pyroxene. The size of the shift becomes greater when the initial cumulus assemblage has a lower total FeO+MgO content, and vice versa. As a result of the relationship between trapped liquid shift and cumulus mode, mineral composition variations and trends may be generated in sequences of cumulates which originally had constant compositions of cumulus minerals. For example, in a cyclic unit grading from a pyroxenitic base to an anorthositic top, crystallization of a uniform proportion of trapped liquid will result in an apparent iron enrichment trend from bottom to top of the cycle, as has been observed in the Upper Critical Zone of the Bushveld Complex.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 96 (1987), S. 151-162 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The Agnew nickel sulfide deposit is spatially associated with a lenticular body of ultramafic rocks which shows a concentric zonation in metamorphic mineralogy. Olivine + tremolite + chlorite + cummingtonite ±enstatite assemblages occur at the margin of the ultramafic lens, giving way to olivine + anthophyllite, olivine + talc and olivine + antigorite assemblages successively inwards. These rocks are interpreted as having crystallized from komatiitic lavas, and exhibit a spectrum of compositions from those of original flow tops to pure olivine adcumulates. The relative modal abundances of metamorphic olivine, tremolite and chlorite reflect original proportions of cumulus olivine and komatiite liquid in the protolith. Peak metamorphic conditions are estimated at 550° C, based on garnet-biotite thermometry, at a maximum pressure of 3 kb. This temperature falls within the narrow range over which metamorphic olivine may co-exist with enstatite, anthophyllite, talc or antigorite depending upon the fugacity of water in the metamorphic fluid. The observed mineralogical zonation is therefore attributed to infiltration by CO2-rich fluids, generated by decarbonation of talc-carbonate rocks formed during pre-metamorphic marginal alteration of the ultramafic lens. Metamorphic fluids were essentially binary mixtures of water and CO2, with minor H2S having a maximum partial pressure less than 1 percent of total pressure. Enstatite-bearing assemblages formed in the presence of CO2-rich fluids at fluid: rock volume ratios close to one, while anthophyllite, talc and antigorite bearing assemblages formed in the presence of progressively more water-rich fluids at progressively lower fluid-rock ratios.
    Type of Medium: Electronic Resource
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  • 6
    Publication Date: 2017-02-21
    Description: The largest mass extinction event in Earth's history marks the boundary between the Permian and Triassic Periods at circa 252 Ma and has been linked with the eruption of the basaltic Siberian Traps large igneous province (SLIP). One of the kill mechanisms that has been suggested is a biogenic methane burst triggered by the release of vast amounts of nickel into the atmosphere. A proposed Ni source lies within the huge Noril’sk nickel ore deposits, which formed in magmatic conduits widely believed to have fed the eruption of the SLIP basalts. However, nickel is a nonvolatile element, assumed to be largely sequestered at depth in dense sulfide liquids that formed the orebodies, preventing its release into the atmosphere and oceans. Flotation of sulfide liquid droplets by surface attachment to gas bubbles has been suggested as a mechanism to overcome this problem and allow introduction of Ni into the atmosphere during eruption of the SLIP lavas. Here we use 2D and 3D X-ray imagery on Noril’sk nickel sulfide, combined with simple thermodynamic models, to show that the Noril’sk ores were degassing while they were forming. Consequent “bubble riding” by sulfide droplets, followed by degassing of the shallow, sulfide-saturated, and exceptionally volatile and Cl-rich SLIP lavas, permitted a massive release of nickel-rich volcanic gas and subsequent global dispersal of nickel released from this gas as aerosol particles.
    Print ISSN: 0027-8424
    Electronic ISSN: 1091-6490
    Topics: Biology , Medicine , Natural Sciences in General
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  • 7
    Publication Date: 2020-09-01
    Print ISSN: 0361-0128
    Electronic ISSN: 1554-0774
    Topics: Geosciences
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  • 8
    Publication Date: 2011-11-01
    Description: The Santa Rita ore zone within the Fazenda Mirabela intrusion is an unusual example of high-tonnage magmatic Ni-Cu-PGE sulfide mineralization developed as a stratiform layer within the main cumulus sequence of a layered intrusion. The intrusion as a whole is about 4 x 2.5 km in outcrop dimensions and at least 3 km in original maximum stratigraphic thickness with an original boat-shaped morphology. The ore zone comprises a 50- to 200-m-thick interval containing up to 5 wt percent disseminated sulfides within a sequence of mostly unaltered harzburgites and orthopyroxenites. This orthopyroxene-dominated sequence lies between the dominantly olivine rich cumulates that comprise the lower half of the intrusion and the gabbroic cumulates that make up the upper half. Sulfide tenor variations and silicate host-rock compositions have been derived from a very large database of continuous assays of more than 500 diamond drill cores. Consistent patterns of sulfide tenor--gradually decreasing Ni from over 20 to about 10 wt percent, near-constant Cu and gradually decreasing PGEs with cyclically varying Pt/Pd ratios--are found within the Santa Rita ore zone across the entire intrusion and display relatively little lateral variability. The position of the sulfide mineralization envelope within the harzburgite-orthopyroxenite package migrates to higher stratigraphic levels from the northern to the southern margin of the intrusion. Maximum grades and thicknesses correlate with the maximum thickness of orthopyroxene-bearing cumulates, asymmetrically disposed toward the southern margin of the intrusion. Nickel tenors of the sulfides range from 15 to 25 wt percent, exceptionally high for rocks with relatively low values of MgO/(MgO + FeO) and are closer to the typical values observed in komatiite-hosted deposits, although Cu tenors (typically 5-8 wt %) are much higher than komatiite values. Sulfide PGE tenors range from less than 100 ppb to greater than 10 ppm of both Pt and Pd, with maximum values in S-poor rocks at the base of the sulfide-bearing interval. PGEs become significantly more depleted toward the top of the Santa Rita zone. We attribute these features, along with the localization of the sulfide-bearing interval at the contact between ultramafic and mafic cumulates, to mixing of an initially S-undersaturated, moderately Ni enriched resident magma with a relatively low Ni, PGE-depleted, significantly lower temperature replenishing magma charged with suspended sulfide liquid droplets.
    Print ISSN: 0361-0128
    Topics: Geosciences
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  • 9
    Publication Date: 2012-03-01
    Description: Recent exploration in the Duketon greenstone belt, Yilgarn craton, Western Australia, led to the discovery of a new occurrence of high-grade Ni-PGE (platinum group element) sulfide mineralization associated with komatiite; this is referred to as the Rosie Ni Prospect. The mineralization consists predominantly of disseminated and brecciated semimassive to massive base metal sulfide with 0.5 to 5 cm thick sulfarsenide-bearing lenses. This pilot study focuses on the petrology, mineralogy, and trace element mineral chemistry of sulfides and sulfarsenides, and the mineralogy of minor PGE-rich minerals (sperrylite, melonite, and bismuthotel-lurides) in selected samples representing different parts of the orebody, with a particular emphasis on the sulfarsenide-rich lenses. Our mineral chemistry and mineralogical studies indicate that As-rich phases (either as a melt or as primary minerals) played a critical role in collecting and concentrating PGEs from the komatiitic magma. The concentrations of trace elements within the sulfarsenides and sulfides from the different mineralization types reflect the interaction between the silicate and sulfide liquids. The concentration of PGEs in the As-rich minerals is a function of the volume of sulfide melt with which they have interacted. The smaller the proportion of the sulfarsenide relative to sulfide in the rock is, the higher the PGE concentration in the sulfarsenide will be. In situ Se analysis of the base metal sulfides from the different ore types indicates that Se concentrations in pentlandite and pyrrhotite from sulfarsenide-rich lenses are an order of magnitude higher than those of sulfides found in As-poor samples. This correlation between the Se concentrations in the sulfide minerals and the As concentration in the whole rock indicates that the processes which led to As enrichment at Rosie also contributed to Se enrichment. The particular As-Se enrichment is inferred to have been triggered by the erosion and assimilation of sulfidic sediments enriched in organic matter (now observed as shales and/or black shales) by the komatiitic magma flows, leading to the formation of immiscible S-As-rich melt, where PGEs partition preferentially into the As-rich phases.
    Print ISSN: 0361-0128
    Topics: Geosciences
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  • 10
    Publication Date: 2018-06-08
    Print ISSN: 0026-461X
    Electronic ISSN: 1471-8022
    Topics: Geosciences
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