ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Mononuclear and binuclear copper(II) complexes with four 4-acetamidobenzaldehyde N(4)-substituted thiosemicarbazones have been prepared in EtOH solution and characterized by physical and spectral methods. I.r., electronic, and e.s.r. spectra of the complexes, as well as i.r., electronic, and n.m.r. spectra of the thiosemicarbazones, have been obtained. These thiosemicarbazones coordinate as anionic or neutral ligands via the thiosemicarbazone moiety's imine nitrogen and thiolate/thione sulfur, the former on loss of the hydrazido hydrogen, N(2)H.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1006967802158
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