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  • 1
    Electronic Resource
    Electronic Resource
    Synthesis of polycarbonates using a cationic zirconocene complex (1998)
    Weinheim : Wiley-Blackwell
    Macromolecular Rapid Communications 19 (1998), S. 601-604 
    Details
    ISSN: 1022-1336
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The cationic alkyl zirconocene complex Cp2Zr+Me[CH3B-(C6F5)3] is found to initiate the ringopening polymerization of 1,5,7,11-tetraoxaspiro[5,5]undecane under mild condition to give poly(oxypropylenepropylenecarbonate) with low polydispersity. The rate of the polymerization is first-order with respect to monomer and catalyst concentration. At high monomer concentration, the initial rate of polymerization becomes zero-order with respect to monomer concentration.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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