ISSN:
1436-2449
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Summary Copolymerizations of (S)-3,3′-dimethyl-2,2′-bis[2-(2-vinyloxyethoxy)ethoxy]-1, 1′-binaphthyl (S-MVN) or 1,3:4,6-di-O-benzylidene-2,5-bis-O-[2-(2-vinyloxyethoxy)ethyl]-d-mannitol (D-BVM) with isobutyl vinyl ether (IBVE) were carried out with BF3·OEt2 in CH2Cl2 at 0 °C. The copolymers obtained were soluble in CHCl3 and THF, and consited of (S)-binaphtho-21-crown-6 or d-manno-21-crown-6 units and IBVE, i.e., poly(S-DVN-co-IBVE) and poly(D-BVM-co-IBVE). These host copolymers dominantly formed complexes with l-phenylglycine methyl ester, whose properties were similar to those for homopolymers of S-MVN and D-BVM.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00298761
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