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  • 1
    Publication Date: 2015-04-11
    Description: We study noisy heterogeneous diffusion processes with a position dependent diffusivity of the form D ( x ) ∼ D 0 | x | α 0 in the presence of annealed and quenched disorder of the environment, corresponding to an effective variation of the exponent α in time and space. In the case of annealed disorder, for which effectively α 0 = α 0 ( t ), we show how the long time scaling of the ensemble mean squared displacement (MSD) and the amplitude variation of individual realizations of the time averaged MSD are affected by the disorder strength. For the case of quenched disorder, the long time behavior becomes effectively Brownian after a number of jumps between the domains of a stratified medium. In the latter situation, the averages are taken over both an ensemble of particles and different realizations of the disorder. As physical observables, we analyze in detail the ensemble and time averaged MSDs, the ergodicity breaking parameter, and higher order moments of the time averages.
    Print ISSN: 0021-9606
    Electronic ISSN: 1089-7690
    Topics: Chemistry and Pharmacology , Physics
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  • 2
    Publication Date: 2015-04-11
    Description: We study noisy heterogeneous diffusion processes with a position dependent diffusivity of the form D ( x ) ∼ D 0 | x | α 0 in the presence of annealed and quenched disorder of the environment, corresponding to an effective variation of the exponent α in time and space. In the case of annealed disorder, for which effectively α 0 = α 0 ( t ), we show how the long time scaling of the ensemble mean squared displacement (MSD) and the amplitude variation of individual realizations of the time averaged MSD are affected by the disorder strength. For the case of quenched disorder, the long time behavior becomes effectively Brownian after a number of jumps between the domains of a stratified medium. In the latter situation, the averages are taken over both an ensemble of particles and different realizations of the disorder. As physical observables, we analyze in detail the ensemble and time averaged MSDs, the ergodicity breaking parameter, and higher order moments of the time averages.
    Electronic ISSN: 1931-9223
    Topics: Chemistry and Pharmacology , Physics
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  • 3
    Publication Date: 2014-04-04
    Description: Author(s): Jaeoh Shin, Andrey G. Cherstvy, and Ralf Metzler Could blowing your nose into a “smart tissue” help detect a viral infection? Theorists say “yes” with a proposal for such a smart tissue: a hydrogel film with embedded prestretched DNA molecules. [Phys. Rev. X 4, 021002] Published Thu Apr 03, 2014
    Electronic ISSN: 2160-3308
    Topics: Physics
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  • 4
    Publication Date: 2014-08-20
    Description: We study the elastic deformations in a cross-linked polymer network film triggered by the binding of submicron particles with a sticky surface, mimicking the interactions of viral pathogens with thin films of stimulus-responsive polymeric materials such as hydrogels. From extensive Langevin Dynamics simulations we quantify how far the network deformations propagate depending on the elasticity parameters of the network and the adhesion strength of the particles. We examine the dynamics of the collective area shrinkage of the network and obtain some simple relations for the associated characteristic decay lengths. A detailed analysis elucidates how the elastic energy of the network is distributed between stretching and compression modes in response to the particle binding. We also examine the force-distance curves of the repulsion or attraction interactions for a pair of sticky particles in the polymer network film as a function of the particle-particle separation. The results of this computational study provide new insight into collective phenomena in soft polymer network films and may, in particular, be applied to applications for visual detection of pathogens such as viruses via a macroscopic response of thin films of cross-linked hydrogels.
    Print ISSN: 0021-9606
    Electronic ISSN: 1089-7690
    Topics: Chemistry and Pharmacology , Physics
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  • 5
    Publication Date: 2014-08-20
    Description: We study the elastic deformations in a cross-linked polymer network film triggered by the binding of submicron particles with a sticky surface, mimicking the interactions of viral pathogens with thin films of stimulus-responsive polymeric materials such as hydrogels. From extensive Langevin Dynamics simulations we quantify how far the network deformations propagate depending on the elasticity parameters of the network and the adhesion strength of the particles. We examine the dynamics of the collective area shrinkage of the network and obtain some simple relations for the associated characteristic decay lengths. A detailed analysis elucidates how the elastic energy of the network is distributed between stretching and compression modes in response to the particle binding. We also examine the force-distance curves of the repulsion or attraction interactions for a pair of sticky particles in the polymer network film as a function of the particle-particle separation. The results of this computational study provide new insight into collective phenomena in soft polymer network films and may, in particular, be applied to applications for visual detection of pathogens such as viruses via a macroscopic response of thin films of cross-linked hydrogels.
    Electronic ISSN: 1931-9223
    Topics: Chemistry and Pharmacology , Physics
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  • 6
    Publication Date: 2018-08-08
    Description: Author(s): Takuma Akimoto, Andrey G. Cherstvy, and Ralf Metzler Bias plays an important role in the enhancement of diffusion in periodic potentials. Using the continuous-time random walk in the presence of a bias, we report on an interesting phenomenon for the enhancement of diffusion by the start of the measurement in a random energy landscape. When the varianc... [Phys. Rev. E 98, 022105] Published Tue Aug 07, 2018
    Keywords: Statistical Physics
    Print ISSN: 1539-3755
    Electronic ISSN: 1550-2376
    Topics: Physics
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  • 7
    Publication Date: 2017-02-08
    Description: The Journal of Physical Chemistry B DOI: 10.1021/acs.jpcb.6b12413
    Electronic ISSN: 1520-5207
    Topics: Chemistry and Pharmacology , Physics
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