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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Refractories and industrial ceramics 7 (1966), S. 721-726 
    ISSN: 1573-9139
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Conclusions Introducing 25% or more nonstabilized ZrO2 increases the spalling resistance of pressings made from prestabilized zirconia. Pressings containing 6 mole % CaO and with 7–10% monoclinic, and respectively 93–90% cubic forms, are relatively highly thermal-shock resistant. Increasing the content of monoclinic ZrO2 reduces the spalling resistance of the pressings, as with the production of pressings of monophase composition, although this single phase is a cubic solid solution. The basic temperature range, the cooling rate in which, affects the thermal-shock resistance of pressings, is 1000–800°C. The main method of increasing the thermal-shock resistance of pressings from zirconia is to create a microcracked structure, obtained by slow cooling in the range 1000–800°C. The microcracked structure also produces a significant reduction in coefficient of thermal expansion and the modulus of elasticity of the pressings, slowly cooled in the range 1000–800°C. The thermal-shock resistance of slowly cooled pressings of zirconia stabilized with CaO is at a maximum. The method developed for increasing the thermal-shock resistance of hot-pressed articles from zirconia, on account of the formation of the microcracked structure, is a general technique: it can be used for other methods of making articles from zirconia.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-9139
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Conclusions It has been established that the traditional parameters of the preparation of cast slips made from stabilized ZrO2 are unsuitable for the experimental composition ZrO2+25% CaO since the time required for washing of the hammered-on iron is sharply increased. The behavior of the hammered briquette of the experimental composition depends on the aggregation of fine particles having a well-developed surface and its dissolution in solutions of HCl, leading to the formation of a liquid solvated shell around a particle and thus preventing the deposition of the suspensions and the removal of iron chloride. Shortening the duration of the milling of the material from 21 to 4 h helps to speed up the deposition of the suspensions as a result of the coarser particle aggregates and the better removal of the iron chloride. In this case the working properties of the articles are not impaired.
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  • 3
    ISSN: 1573-9139
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Conclusions Using the method of simplex-grid experimental planning, the properties of the ZrO2-based solid electrolytes were optimized. The composition-property diagrams were plotted in a limited range of compositions. The relationship between the stabilizing additives facilitating the production of solid electrolytes possessing a high electrical conductivity and its stability during the process of isothermal dwells was established.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Refractories and industrial ceramics 8 (1967), S. 434-439 
    ISSN: 1573-9139
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Conclusions We studied the influence of temperature and heat process time for zirconium nitrate on the phase composition, dispersion of grains and crystalline lattice defects in the resulting zirconia, and also on its capacity for subsequent compaction during hot pressing. This capacity is connected with the formation, during a short heating period up to 400°C, of metastable tetragonal and cubic modifications having a highly defective crystalline lattice. We also studied the densification during hot pressing of active zirconia obtained by decomposing zirconium nitrate. During decomposition of zirconium nitrate at 400°C with a short soak we noted the formation of zirconium dioxide which was actively compacted at 1100°C and a pressure of 200 kg/cm2. We studied the influence of additions of CaO and the methods of adding it on the densification of active zirconia. An increase in the content of CaO leads to a reduction in the capacity of ZrO2 for compaction during hot pressing. It is necessary to introduce the additive to the nitrate before it decomposes. During hot pressing of active zirconia containing additions of CaO and Y2O3 at low temperatures (1100–1300°C) cubic solid solutions are not formed owing to the short process time, and the zirconia in the specimens consists of monoclinic form. Subsequent heating of the pressed specimens forms cubic solid solutions. It was found that the introduction of 10–20% additive of zirconia obtained by heat processing the nitrate to industrial ultrapure zirconium dioxide yields dense specimens with a reduction in the optimum pressing temperature of 200°C.
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Refractories and industrial ceramics 16 (1975), S. 296-299 
    ISSN: 1573-9139
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Conclusions The technology was developed for the manufacture of products from hafnium dioxide stabilized with 10 and 50 mole % Y2O3 in the form of slipcastings in gypsum molds from the briquetted, fired, and vibroground material. The conductivity of the products is purely ionic and it decreases with an increase in the percent stabilizing additive while the activation energy increases. An investigation of the thermal strength of zero-porosity specimens showed that it increases with the addition of Al2O3 or MgAl2O4 as a result of the formation of a microfissured structure. Products containing 1% added spinel possess the best properties. It was established that among the tested products, that consisting of 50 mole % HfO2 + 50 mole % Y2O3 is the most stable one to the melts and vapors of alkaline metals. Its stability is higher than that of zirconia products.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Refractories and industrial ceramics 5 (1964), S. 481-484 
    ISSN: 1573-9139
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Conclusions Anisotropy of sintering was established in specimens cast from alumina slip, due to the oriented arrangement of the grains during casting, when their shape was nonisometric. The shape and character of the surface of the grains of corundum and therefore the magnitude of shrinkage anisotropy of cast specimens depend on the temperature of presintering of the alumina, the method of grinding it, and the fineness obtained by grinding. High temperatures of firing for the alumina, wet grinding, and coarsening of the grains lead to anisotropy of shrinkage during sintering. The absence of substantial orientation of the crystals during semidry pressing of fine powders of corundum ensures that the articles sinter without anisotropic shrinkage. The use of staged heating for cast specimens ensures almost uniform shrinkage during sintering.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Refractories and industrial ceramics 9 (1968), S. 362-370 
    ISSN: 1573-9139
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Conclusions We investigated the sintering of zirconium dioxide as a function of the activity of the starting material. It was shown that preliminary firing or stabilization of zirconium dioxide reduces its capacity for densification at temperatures of up to 1500°C, while stabilizing it directly during sintering intensifies this capacity. The prestabilized zirconia has the lowest sintering rate. Introducing monoclinic unfired zirconia into the prestabilized material intensifies sintering; the optimal addition is 30%. It is established that the zirconia is sintered by volume diffusion of vacancies. We investigated the sintering of active zirconia obtained by decomposing zirconium nitrate. The greatest degree of densification is obtained with a preliminary short heat processing of the nitrate at 400°C. Activation is connected with the formation of metastable tetragonal and cubic modifications with defect crystal lattices. Increasing the heat-process temperature of the nitrate or prolonging the soak at 400°C, leading to the formation of stable monoclinic ZrO2 with an ordered crystalline lattice, impairs sintering. Incorporating small additions of active ZrO2 in the industrial material, and providing rapid firing in an oxidizing atmosphere, greatly increases the degree of sintering. Introducing stabilizing additives intensifies sintering. The maximum densification is obtained by the formation of 60–70% solid solution. Further increase in these additions reduces the shrinkage and densification of the specimens.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Refractories and industrial ceramics 36 (1995), S. 82-85 
    ISSN: 1573-9139
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Casting properties of concentrated aqueous dispersions of zirconia stabilized by Y2O3, Si2O3, or a mixture of them are investigated. Optimum values of the pH, temperature, and slip concentration for the production of thin-walled vacuum-tight articles are established.
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  • 9
    ISSN: 1573-9139
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Refractories and industrial ceramics 10 (1969), S. 179-181 
    ISSN: 1573-9139
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Conclusions Hot-pressing was used to obtain samples of products of zirconium dioxide with a density of 97–99% of the theoretical value. Their electrical conductivity was considerably greater than in the case of sintered samples with the corresponding stabilizing additive. In the temperature interval 1300–2000°C, it was lower than 1 Ω−1.cm−1 in all cases.
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