Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
82 (1985), S. 4500-4508
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The Eisenbud–Wigner time delay matrix is used to study the dynamics of reaction close to vibrationally adiabatic barrier energies. Maxima in the time delay are predicted and are found to be in excellent agreement with vibrationally adiabatic barrier energies determined by quantized pods. The actual time spent in the vicinity of the barriers is estimated by separating out the free particle time. This "real time'' is then used to analyze the validity of the adiabatic and sudden approaches to reactive scattering in the 3D H+H2 and D+H2 reactions.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.448704
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