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  • 1
    Electronic Resource
    Electronic Resource
    Determination of tertiary amines in non-aqueous solvents in the presence of primary and secondary amines (1992)
    Springer
    Fresenius' Zeitschrift für analytische Chemie 342 (1992), S. 581-585 
    Details
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary In the formation of tertiary amines in the mechanism of the reaction of 1:3 BADGE/m-XDA (bisphenol A diglycidyl ether/m-xylylenediamine) equivalent ratio epoxy-amine formulations, we have used FAB mass spectrometry to confirm the different mechanisms of epoxy-amine reactions described by Shechter et al. (3) and have adapted a reaction to give a fluorescent adduct with tertiary amines for their colorimetric determination in the presence of primary and secondary amines, reporting several advantages over the previous method.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00321917
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  • 2
    Electronic Resource
    Electronic Resource
    Kinetics of the hydrolysis of bisphenol A diglycidyl ether (BADGE) in water-based food simulants (1993)
    Springer
    Fresenius' Zeitschrift für analytische Chemie 345 (1993), S. 527-532 
    Details
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The first-order degradation kinetics of bisphenol A diglycidyl ether (BADGE; CAS No. 1675-54-3) has been studied in three water-based food simulants (3% (W/V) acetic acid, distilled water and 15% (V/V) ethanol) at various temperatures. BADGE and its first and second hydrolysis products were determined by reversed-phase high-performance liquid chromatography with fluorescence detection. Nonlinear regression was used to fit the experimental data at 40, 50 and 60°C with the proposed kinetic equations; Arrhenius' equation was then fitted to the rate constants obtained and the kinetic models were tested by comparing experimental data obtained at 70°C with the kinetic curves calculated using the rate constants predicted for this temperature. The half-life of BADGE was longest in ethanol and shortest in acetic acid. The rings opening in acetic acid appears to happen by means of active hydrogens whereas in the other simulants it is mainly influenced by the formation of acid/base adducts. The results imply that resins which comply with existing legislation on the migration of unreacted monomer may still contaminate foodstuffs.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00326345
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  • 3
    Electronic Resource
    Electronic Resource
    Epoxy resins based on trimethylolpropane. I. Determination of chemical structres (1995)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 55 (1995), S. 225-232 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The chemical structure of an aliphatic epoxy resin was studied by using gel permeation chromatography (GPC), Fourier transform infrared (FTIR), FTIR-TGA (thermogravimetric analysis), mass spectrometry in fast atom bombardment (FAB) mode, and wet analysis. We found that when trimethylolpropane is used as starting monomer, only two OH groups are epoxidized. The resin and its different fractions have a functionality of two. Under the conditions of synthesis used by the supplier, three main products were found with masses of 246,339, and 430. No trifunctional product was detected. © 1995 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1995.070550205
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  • 4
    Electronic Resource
    Electronic Resource
    Epoxy resins based on trimethylolpropane. II. Kinetic and thermodynamic parameters of cure withm-XDA (1995)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 55 (1995), S. 1507-1516 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A study of cure of an epoxy resin based on trimethilolpropane (TMP) used as supplied and in purified form and m-xylylenediamine (m-XDA), as curing agent has been carried out. Thermodynamic functions such as activation energy, activation entropy, activation enthalpy, and free energy of activation were determinated. From kinetic study we have observed that there are two competitive mechanisms; autocatalyzed and n order, with the values of activation energy ranging between 52.9 and 64.6 kJ/mol. The overall order of reaction is found to be 2.5, and the order of reaction with respect to the hydroxyl group is clearly determined and equal to 1. Gelation study was carried out under two conditions: isothermal and adiabatic. From isothermal study we obtained the values of functionality of the resins (approximately two) and the apparent activation energy of the process. The adiabatic study allowed us the determination of the pot-life taking into account the theoretical model used, with reasonable theoretical/experimental agreements. The importance of n-order path for this kind of resins (with high OH contents) is well demonstrated through kinetic and thermodynamic parameters. The thermodynamic functions showed themselves as very sensitive parameters for the following and evolution of the reaction. © 1995 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1995.070551102
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