ISSN:
0268-2605
Keywords:
Organotin determination
;
rotating disc voltammetry
;
dimethylformamide
;
acetonitrile
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The electrochemical behaviour of three series of organotin(IV) compounds having the general formula RySnX4-y (R = Me, nBu or Ph, y = 2 or 3, X = Cl; R = Me or Ph, y = 3, X = NO3, N3, NCS, NCO, OAc or OH) have been examined in the non-aqueous solvents dimethylformamide and acetonitrile, at rotating disc electrodes of glassy carbon and gold electrodes. The reduction of tin(IV) in the above series gave a single wave and obeyed the Levich plots at both electrodes in the two solvents. The electrode kinetic parameters and halfwave potentials have been determined, and the effect of solvents and substituents on these parameters have been explored.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aoc.590040208
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