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  • 1
    Publication Date: 2019
    Description: Abstract Noble gases in ice cores enable reconstructions of past mean ocean temperature. A recent result from the clathrate‐containing WAIS Divide Ice Core showed tight covariation between ocean and Antarctic temperatures throughout the last deglaciation, except for the Younger Dryas interval. In the beginning of this interval, oceans warmed at 2.5 °C/kyr—three times greater than estimates of modern warming. If valid, this challenges our understanding of the mechanisms controlling ocean heat uptake. Here we reconstruct mean ocean temperature with clathrate‐free ice samples from Taylor Glacier to test these findings. The two records agree in net temperature change over the Younger Dryas, but the Taylor Glacier record suggests sustained warming at the more modest rate of 1.1 ± 0.2°C/kyr. We explore mechanisms to explain differences between records and suggest that the noble gas content for the Younger Dryas interval of WAIS Divide may have been altered by a decimeter‐scale fractionation during bubble‐clathrate transformation.
    Print ISSN: 0094-8276
    Electronic ISSN: 1944-8007
    Topics: Geosciences , Physics
    Published by Wiley on behalf of American Geophysical Union (AGU).
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  • 2
    Publication Date: 2014-12-17
    Description: Nitrous oxide (N2O) is an important greenhouse gas and ozone-depleting substance that has anthropogenic as well as natural marine and terrestrial sources. The tropospheric N2O concentrations have varied substantially in the past in concert with changing climate on glacial-interglacial and millennial timescales. It is not well understood, however, how N2O emissions from marine and terrestrial sources change in response to varying environmental conditions. The distinct isotopic compositions of marine and terrestrial N2O sources can help disentangle the relative changes in marine and terrestrial N2O emissions during past climate variations. Here we present N2O concentration and isotopic data for the last deglaciation, from 16,000 to 10,000 years before present, retrieved from air bubbles trapped in polar ice at Taylor Glacier, Antarctica. With the help of our data and a box model of the N2O cycle, we find a 30 per cent increase in total N2O emissions from the late glacial to the interglacial, with terrestrial and marine emissions contributing equally to the overall increase and generally evolving in parallel over the last deglaciation, even though there is no a priori connection between the drivers of the two sources. However, we find that terrestrial emissions dominated on centennial timescales, consistent with a state-of-the-art dynamic global vegetation and land surface process model that suggests that during the last deglaciation emission changes were strongly influenced by temperature and precipitation patterns over land surfaces. The results improve our understanding of the drivers of natural N2O emissions and are consistent with the idea that natural N2O emissions will probably increase in response to anthropogenic warming.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Schilt, Adrian -- Brook, Edward J -- Bauska, Thomas K -- Baggenstos, Daniel -- Fischer, Hubertus -- Joos, Fortunat -- Petrenko, Vasilii V -- Schaefer, Hinrich -- Schmitt, Jochen -- Severinghaus, Jeffrey P -- Spahni, Renato -- Stocker, Thomas F -- England -- Nature. 2014 Dec 11;516(7530):234-7. doi: 10.1038/nature13971.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉1] College of Earth, Ocean, and Atmospheric Sciences, Oregon State University, Corvallis, Oregon 97331, USA [2] Climate and Environmental Physics, Physics Institute, and Oeschger Centre for Climate Change Research, University of Bern, 3012 Bern, Switzerland. ; College of Earth, Ocean, and Atmospheric Sciences, Oregon State University, Corvallis, Oregon 97331, USA. ; Scripps Institution of Oceanography, University of California, San Diego, California 92037, USA. ; Climate and Environmental Physics, Physics Institute, and Oeschger Centre for Climate Change Research, University of Bern, 3012 Bern, Switzerland. ; Department of Earth and Environmental Sciences, University of Rochester, Rochester, New York 14627, USA. ; National Institute of Water and Atmospheric Research, Wellington 6021, New Zealand.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/25503236" target="_blank"〉PubMed〈/a〉
    Keywords: Antarctic Regions ; Aquatic Organisms/*metabolism ; Atmosphere/*chemistry ; Global Warming ; History, Ancient ; *Ice Cover ; Nitrogen Isotopes/analysis ; Nitrous Oxide/analysis/history/*metabolism ; Oxygen Isotopes/analysis ; Rain ; Temperature ; Time Factors
    Print ISSN: 0028-0836
    Electronic ISSN: 1476-4687
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
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  • 3
    Publication Date: 2014-10-31
    Description: Global climate and the concentration of atmospheric carbon dioxide (CO2) are correlated over recent glacial cycles. The combination of processes responsible for a rise in atmospheric CO2 at the last glacial termination (23,000 to 9,000 years ago), however, remains uncertain. Establishing the timing and rate of CO2 changes in the past provides critical insight into the mechanisms that influence the carbon cycle and helps put present and future anthropogenic emissions in context. Here we present CO2 and methane (CH4) records of the last deglaciation from a new high-accumulation West Antarctic ice core with unprecedented temporal resolution and precise chronology. We show that although low-frequency CO2 variations parallel changes in Antarctic temperature, abrupt CO2 changes occur that have a clear relationship with abrupt climate changes in the Northern Hemisphere. A significant proportion of the direct radiative forcing associated with the rise in atmospheric CO2 occurred in three sudden steps, each of 10 to 15 parts per million. Every step took place in less than two centuries and was followed by no notable change in atmospheric CO2 for about 1,000 to 1,500 years. Slow, millennial-scale ventilation of Southern Ocean CO2-rich, deep-ocean water masses is thought to have been fundamental to the rise in atmospheric CO2 associated with the glacial termination, given the strong covariance of CO2 levels and Antarctic temperatures. Our data establish a contribution from an abrupt, centennial-scale mode of CO2 variability that is not directly related to Antarctic temperature. We suggest that processes operating on centennial timescales, probably involving the Atlantic meridional overturning circulation, seem to be influencing global carbon-cycle dynamics and are at present not widely considered in Earth system models.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Marcott, Shaun A -- Bauska, Thomas K -- Buizert, Christo -- Steig, Eric J -- Rosen, Julia L -- Cuffey, Kurt M -- Fudge, T J -- Severinghaus, Jeffery P -- Ahn, Jinho -- Kalk, Michael L -- McConnell, Joseph R -- Sowers, Todd -- Taylor, Kendrick C -- White, James W C -- Brook, Edward J -- England -- Nature. 2014 Oct 30;514(7524):616-9. doi: 10.1038/nature13799.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉1] College of Earth, Ocean, and Atmospheric Sciences, Oregon State University, Corvallis, Oregon 97331, USA [2] Department of Geoscience, University of Wisconsin-Madison, Madison, Wisconsin 53706, USA. ; College of Earth, Ocean, and Atmospheric Sciences, Oregon State University, Corvallis, Oregon 97331, USA. ; Department of Earth and Space Sciences, University of Washington, Seattle, Washington 98195, USA. ; Department of Geography, University of California, Berkeley, California 94720, USA. ; Scripps Institution of Oceanography, University of California, San Diego, California 92037, USA. ; School of Earth and Environmental Sciences, Seoul National University, Seoul 151-742, South Korea. ; Desert Research Institute, Nevada System of Higher Education, Reno, Nevada 89512, USA. ; Earth and Environmental Systems Institute, Pennsylvania State University, University Park, Pennsylvania 16802, USA. ; INSTAAR, University of Colorado, Boulder, Colorado 80309, USA.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/25355363" target="_blank"〉PubMed〈/a〉
    Keywords: Antarctic Regions ; Atmosphere/chemistry ; *Carbon Cycle ; Carbon Dioxide/analysis ; Greenhouse Effect ; Greenland ; History, Ancient ; Ice Cover ; Isotopes ; Methane/analysis ; Oceans and Seas ; Water/analysis/chemistry
    Print ISSN: 0028-0836
    Electronic ISSN: 1476-4687
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
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  • 4
    Publication Date: 2017-12-21
    Description: Analytical Chemistry DOI: 10.1021/acs.analchem.7b03136
    Print ISSN: 0003-2700
    Electronic ISSN: 1520-6882
    Topics: Chemistry and Pharmacology
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  • 5
    Publication Date: 2018-08-03
    Description: The demise of Lowland Classic Maya civilization during the Terminal Classic Period (~800 to 1000 CE) is a well-cited example of how past climate may have affected ancient societies. Attempts to estimate the magnitude of hydrologic change, however, have met with equivocal success because of the qualitative and indirect nature of available climate proxy data. We reconstructed the past isotopic composition ( 18 O, D, 17 O-excess, and d-excess) of water in Lake Chichancanab, Mexico, using a technique that involves isotopic analysis of the structurally bound water in sedimentary gypsum, which was deposited under drought conditions. The triple oxygen and hydrogen isotope data provide a direct measure of past changes in lake hydrology. We modeled the data and conclude that annual precipitation decreased between 41 and 54% (with intervals of up to 70% rainfall reduction during peak drought conditions) and that relative humidity declined by 2 to 7% compared to present-day conditions.
    Keywords: Geochemistry, Geophysics
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 6
    Publication Date: 2016-03-30
    Description: An understanding of the mechanisms that control CO2 change during glacial–interglacial cycles remains elusive. Here we help to constrain changing sources with a high-precision, high-resolution deglacial record of the stable isotopic composition of carbon in CO2 (δ13C-CO2) in air extracted from ice samples from Taylor Glacier, Antarctica. During the initial...
    Print ISSN: 0027-8424
    Electronic ISSN: 1091-6490
    Topics: Biology , Medicine , Natural Sciences in General
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  • 7
    Publication Date: 2018-07-11
    Description: Changes in atmospheric CO2 on millennial-to-centennial timescales are key components of past climate variability during the last glacial and deglacial periods (70–10 ka), yet the sources and mechanisms responsible for the CO2 fluctuations remain largely obscure. Here we report the 13C/12C ratio of atmospheric CO2 during a key interval of the last glacial period at submillennial resolution, with coeval histories of atmospheric CO2, CH4, and N2O concentrations. The carbon isotope data suggest that the millennial-scale CO2 variability in Marine Isotope Stage 3 is driven largely by changes in the organic carbon cycle, most likely by sequestration of respired carbon in the deep ocean. Centennial-scale CO2 variations, distinguished by carbon isotope signatures, are associated with both abrupt hydrological change in the tropics (e.g., Heinrich events) and rapid increases in Northern Hemisphere temperature (Dansgaard-Oeschger events). These events can be linked to modes of variability during the last deglaciation, thus suggesting that drivers of millennial and centennial CO2 variability during both periods are intimately linked to abrupt climate variability. ©2018. American Geophysical Union. All Rights Reserved.
    Print ISSN: 0094-8276
    Electronic ISSN: 1944-8007
    Topics: Geosciences , Physics
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  • 8
    Publication Date: 2017-12-19
    Print ISSN: 0003-2700
    Electronic ISSN: 1520-6882
    Topics: Chemistry and Pharmacology
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  • 9
    Publication Date: 2014-07-03
    Description: An important constraint on mechanisms of past carbon cycle variability is provided by the stable isotopic composition of carbon in atmospheric carbon dioxide (δ13C-CO2) trapped in polar ice cores, but obtaining very precise measurements has proven to be a significant analytical challenge. Here we describe a new technique to determine the δ13C of CO2 at exceptional precision, as well as measuring the CO2 and N2O mixing ratios. In this method, ancient air is extracted from relatively large ice samples (~ 400 grams) with a dry-extraction "ice-grater" device. The liberated air is cryogenically purified to a CO2 and N2O mixture and analyzed with a micro-volume equipped dual-inlet IRMS (Thermo MAT 253). The reproducibility of the method, based on replicate analysis of ice core samples, is 0.02‰ for δ13C-CO2 and 2 ppm and 4 ppb for the CO2 and N2O mixing ratios, respectively (1-sigma pooled standard deviation). Our experiments show that minimizing water vapor pressure in the extraction vessel by housing the grating apparatus in a ultra-low temperature freezer (−60 °C) improves the precision and decreases the experimental blank of the method. We describe techniques for accurate calibration of small samples and the application of a mass spectrometric method based on source fragmentation for reconstructing the N2O history of the atmosphere. The oxygen isotopic composition of CO2 is also investigated, confirming previous observations of oxygen exchange between gaseous CO2 and solid H2O within the ice archive. These data offer a possible constraint on oxygen isotopic fractionation during H2O and CO2 exchange below the H2O bulk melting temperature.
    Electronic ISSN: 1867-8610
    Topics: Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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  • 10
    Publication Date: 2014-11-19
    Description: An important constraint on mechanisms of past carbon cycle variability is provided by the stable isotopic composition of carbon in atmospheric carbon dioxide (δ13C-CO2) trapped in polar ice cores, but obtaining very precise measurements has proven to be a significant analytical challenge. Here we describe a new technique to determine the δ13C of CO2 at very high precision, as well as measuring the CO2 and N2O mixing ratios. In this method, ancient air is extracted from relatively large ice samples (~400 g) with a dry-extraction "ice grater" device. The liberated air is cryogenically purified to a CO2 and N2O mixture and analyzed with a microvolume-equipped dual-inlet IRMS (Thermo MAT 253). The reproducibility of the method, based on replicate analysis of ice core samples, is 0.02‰ for δ13C-CO2 and 2 ppm and 4 ppb for the CO2 and N2O mixing ratios, respectively (1σ pooled standard deviation). Our experiments show that minimizing water vapor pressure in the extraction vessel by housing the grating apparatus in a ultralow-temperature freezer (−60 °C) improves the precision and decreases the experimental blank of the method to −0.07 ± 0.04‰. We describe techniques for accurate calibration of small samples and the application of a mass-spectrometric method based on source fragmentation for reconstructing the N2O history of the atmosphere. The oxygen isotopic composition of CO2 is also investigated, confirming previous observations of oxygen exchange between gaseous CO2 and solid H2O within the ice archive. These data offer a possible constraint on oxygen isotopic fractionation during H2O and CO2 exchange below the H2O bulk melting temperature.
    Print ISSN: 1867-1381
    Electronic ISSN: 1867-8548
    Topics: Geosciences
    Published by Copernicus on behalf of European Geosciences Union.
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