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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Mineral stable isotopic and trace element studies in 2 GPa banded eclogites of the Tauern Window, eastern Alps, record mm- to cm-scale heterogeneities that reflect compositional variations in the accompanying metamorphic fluids. A close correlation between dolomite mode and dolomite δ18O is consistent with equilibrium partitioning among coexisting minerals and fluids. Small variations in dolomite δ13C values correspond with δ18O variations, but an overall decrease in dolomite δ13C by c. 1%o across a 12-cm sample is a relict feature that pre-dates eclogite equilibration. Garnet, omphacite, and clinozoisite rims show little systematic mineral-mineral partitioning behaviour for Ti, V, Cr, Y, Sr, or Zr; major elements, however, are well equilibrated among these same minerals. Despite the apparent lack of mineral-mineral trace element equilibration, most of the trace elements vary systematically with water activity calculated in each layer. Trace element behaviour during the eclogite metamorphism thus appears to have been controlled largely by mineral-fluid interactions along grain boundaries.Shallow structural levels in other subduction complexes (c. 10-45 km) typically exhibit fracture-controlled permeability and extensive metasomatism, but there is no field or geochemical evidence for extensive fluid advection during high-pressure metamorphism in the Tauern eclogites. Because most dewatering and devolatilization during tectonic burial occurs prior to eclogite conditions, the volumetric fluid/rock ratio in eclogites should generally be low. Low fluid/rock ratios, coupled with the possible non-wetting nature of the fluids, permits the production and preservation of fine-scale chemical heterogeneities in deeply subducted eclogites and associated fluids. However, the eventual breakdown at greater depth of volatile-bearing dolomite, phengite, clinozoisite, zoisite, or amphibole could lead to renewed fracture-controlled fluid release from the subducted rocks to regions appropriate for arc magma generation.
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of metamorphic geology 23 (2005), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Interlayered graphitic and non-graphitic schists from the Tauern Window, Eastern Alps, record contrasting mechanical behaviour during extensional exhumation. Graphitic schists contain mesoscale extension fractures, pervasive microcracks in garnet, and abundant secondary fluid inclusion planes; all three types of structures are oriented perpendicular to the stretching lineation. Crack spacings in garnet from graphitic samples are tightly clustered around a mean of 180 μm. Non-graphitic schists have fewer and more randomly oriented microcracks and fluid inclusion planes and maintained strain compatibility via crystal plasticity. The presence or absence of graphite appears to have exerted a fundamental control on rheology during unroofing. Calculations for a model graphitic rock at 500 °C and fO2 = 10−24 MPa show that the equilibrium metamorphic fluid evolves from XCO2 = 0.07 to 0.38 during decompression from 700 to 400 MPa, in agreement with microcrack fluid inclusion data that show a change from XCO2 〈 0.1 to 0.45 in graphitic samples over the same pressure interval. This compositional shift results in 〉60% expansion of the pore fluid during decompression. H2O-rich fluid in non-graphitic rocks expands 〈15% over the same pressure interval. The greater pore fluid expansion in low-permeability graphitic horizons likely promoted tensile failure during unroofing. These results suggest that microcracking should be an inevitable consequence of decompression in many graphitic schists, whereas rocks that lack graphite are less likely to undergo microcracking. Microseismicity is predicted to be more common in graphitic than non-graphitic rocks during unroofing of mountain belts.
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of metamorphic geology 21 (2003), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Micaceous quartzites from a subvertical shear zone in the Tauern Window contain abundant quartz clasts derived from dismembered quartz-tourmaline veins. Bulk plane strain deformation affected these rocks at amphibolite facies conditions. Shape changes suggest net shortening of the clasts by 11–64%, with a mean value of 35%. Quartz within the clasts accommodated this strain largely via dislocation creep processes. On the high-stress flanks of the clasts, however, quartz was removed via solution mass transfer (pressure solution) processes; the resulting change in bulk composition allowed growth of porphyroblastic staurolite + chlorite ± kyanite on the clast flanks. Matrix SiO2 contents decrease from c. 83 wt% away from the clasts to 49–58% in the selvages on the clast flanks. The chemical changes are consistent with c. 70% volume loss in the high-stress zones. Calculated shortening values within the clast flanks are similar to the volume-loss estimates, and are greatly in excess of the shortening values calculated from the clasts themselves. Flow laws for dislocation creep versus pressure solution imply large strain-rate gradients and/or differential stress gradients between the matrix and the clast selvages. In a rock containing a large proportion of semirigid clasts, weakening within the clast flanks could dominate rock rheology. In our samples, however, weakening within the selvages was self limiting: (1) growth of strong staurolite porphyroblasts in the selvages protected remaining quartz from dissolution; and (2) overall flattening of the quartz clasts probably decreased the resolved shear stress on the flanks to values near those of the matrix, which would have reduced the driving force for solution-transfer creep. Extreme chemical changes nonetheless occurred over short distances. The necessity of maintaining strain compatibility may lead to significant localized dissolution in rocks containing rheologic heterogeneities, and overall weakening of the rocks may result. Solution-transfer creep may be a major process whereby weakening and strain localization occur during deep-crustal metamorphism of polymineralic rocks.
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 9 (1991), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract Ductile shearing in the core of the Tauern Window, Austria, transformed metagranodiorite into Si-undersaturated garnet-chlorite-staurolite schist at a depth of c. 35–40 km during the Alpine orogeny. Four distinct zones have been recognized extending from the wallrock into the centre of the shear zone: Zone I—unaltered metagranodiorite with subordinate amphibolite; Zone II—biotite-white mica-garnet schist; Zone III—biotite-phengite schist; Zone IV—quartz-absent, garnet-chlorite-staurolite schist with garnets up to 10 cm across. Whole-rock analyses show a dramatic decrease in SiO2 from 〉65 wt% in Zone I to 〈35 wt% in Zone IV; Ca, Na, and Sr also decrease across the shear zone, whereas Al, Ti, Fe, Mg, P, Cr, Ni, Zn, and Rb all increase towards Zone IV. Mass-balance calculations indicate that shearing was accompanied by up to 60% volume loss near the centre of the shear zone. Comparison of the Tauern Window samples with other shear zones in granitic hosts indicates that silica loss accompanied by gains in Mg, Fe, and Ti is typical for volume-loss shear zones, but is distinctly different from the element behaviour exhibited in shear zones that are thought to represent approximately isovolumetric behaviour. In the samples studied here, volume loss appears to have resulted from channellized fluid flow during shearing, producing time-integrated fluid fluxes of ± 108 cm3 cm−2 in Zone IV. This large volume of fluid may have originated, in part, from dehydration of flysch carried beneath the metagranodiorites during Eocene movement on the North Penninic subduction zone. Development of an inverted thermal gradient during subduction would have allowed the fluid to scavenge large amounts of silica from the shear zone during ascent and heating.
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  • 5
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of metamorphic geology 22 (2004), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: The Greiner shear zone in the Tauern Window, Eastern Alps, changes from a zone of distributed (dominantly sinistral) shear in supracrustal rocks to a series of narrow, gully forming dextral splays where it enters basement gneisses. Within these splays, granodiorite is transformed into quartz-poor biotite and/or chlorite schists, reflecting hydration, removal of Si, Ca and Na, and concentration of Fe, Mg and Al. Stable isotope analyses show a prominent increase in δD and a decrease in δ18O from granodiorite into the shear zones. These changes indicate significant channelized flow of an externally derived, low-δ18O, high-δD fluid through the shear zones. The shear zone schists are chemically similar to blackwall zones developed around serpentinite bodies elsewhere in the Greiner zone and the stable isotope data support alteration via serpentinite-derived fluid. Monazite in schist from one shear zone yields spot dates of 29–20 Ma, indicating that the fluid influx and switch from sinistral to dextral shear occurred at or shortly after the thermal peak of the Alpine orogeny (c. 30 Ma). We suggest that Alpine metamorphism of serpentinites released large amounts of high-δD, low-δ18O, Si-undersaturated, Fe + Mg-saturated fluids that became channelized along prior zones of weakness in the granodiorite. Infiltration of this fluid facilitated growth of chlorite and biotite, which in turn localized later dextral strain in the narrow splays via cleavage-parallel slip. This dextral strain event can be linked to other structures that accommodated tectonic escape of major crustal blocks during dextral transpression in the Eastern Alps. This study shows that serpentinite devolatilization can play an important role in modifying both the chemistry and rheology of surrounding rocks during orogenesis.
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  • 6
    ISSN: 1432-1866
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Uranium deposits containing molybdenum and fluorite occur in the Central Mining Area, near Marysvale, Utah, and formed in an epithermal vein system that is part of a volcanic/hypabyssal complex. They represent a known, but uncommon, type of deposit; relative to other commonly described volcanic-related uranium deposits, they are young, well-exposed and well-documented. Hydrothermal uranium-bearing quartz and fluorite veins are exposed over a 300 m vertical range in the mines. Molybdenum, as jordisite (amorphous MoS2), together with fluorite and pyrite, increase with depth, and uranium decreases with depth. The veins cut 23-Ma quartz monzonite, 20-Ma granite, and 19-Ma rhyolite ash-flow tuff. The veins formed at 19-18 Ma in a 1 km2 area, above a cupola of a composite, recurrent, magma chamber at least 24 × 5 km across that fed a sequence of 21- to 14-Ma hypabyssal granitic stocks, rhyolite lava flows, ash-flow tuffs, and volcanic domes. Formation of the Central Mining Area began when the intrusion of a rhyolite stock, and related molybdenite-bearing, uranium-rich, glassy rhyolite dikes, lifted the fractured roof above the stock. A breccia pipe formed and relieved magmatic pressures, and as blocks of the fractured roof began to settle back in place, flat-lying, concave-downward, “pull-apart” fractures were formed. Uranium-bearing, quartz and fluorite veins were deposited by a shallow hydrothermal system in the disarticulated carapace. The veins, which filled open spaces along the high-angle fault zones and flat-lying fractures, were deposited within 115 m of the ground surface above the concealed rhyolite stock. Hydrothermal fluids with temperatures near 200 °C, 18OH2O∼−1.5, DH2O∼−130, log f O2 about −47 to −50, and pH about 6 to 7, permeated the fractured rocks; these fluids were rich in fluorine, molybdenum, potassium, and hydrogen sulfide, and contained uranium as fluoride complexes. The hydrothermal fluids reacted with the wallrock resulting in precipitation of uranium minerals. At the deepest exposed levels, wallrocks were altered to sericite; and uraninite, coffinite, jordisite, fluorite, molybdenite, quartz, and pyrite were deposited in the veins. The fluids were progressively oxidized and cooled at higher levels in the system by boiling and degassing; iron-bearing minerals in wall rocks were oxidized to hematite, and quartz, fluorite, minor siderite, and uraninite were deposited in the veins. Near the ground surface, the fluids were acidified by condensation of volatiles and oxidation of hydrogen sulfide in near-surface, steam-heated, ground waters; wall rocks were altered to kaolinite, and quartz, fluorite, and uraninite were deposited in veins. Secondary uranium minerals, hematite, and gypsum formed during supergene alteration later in the Cenozoic when the upper part of the mineralized system was exposed by erosion.
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  • 7
    ISSN: 1432-1866
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
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  • 8
  • 9
    Publication Date: 2015-12-02
    Description: Many large-slip faults, such as the San Andreas fault and low-angle normal faults (LANFs), appear to be weak relative to their surroundings or to laboratory friction measurements, and to be poorly oriented for slip in the regional stress field. Several models seek to explain the mechanics of slip and/or formation of such faults. Other models explain damage around faults as due to fault or earthquake rupture propagation or slip on nonplanar faults. Most of these models explicitly predict the near-fault stress field. Exhumed footwalls of low-angle normal faults are advantageous natural laboratories for testing such models because they expose rocks that passed through the brittle-plastic transition and all or part of the seismogenic crust. We present reduced paleostress tensors derived from inversion of fracture and slip-line orientation data taken mainly from the fault cores and fractured damage zones in the upper footwalls of two LANFs, the Whipple and West Salton detachment faults of southern California. Frictionally weak materials probably were not significant along these faults except in the uppermost few kilometers of the crust, and pore-fluid pressure probably never approached lithostatic values. Most results show that the faults were at a high angle to the near-fault maximum compressive stress ( 1 ) direction, in general accord with Andersonian extensional stress fields. Our results support a "strong-sandwich" mechanical model for slip in the upper crust, in which normal-friction LANFs are embedded in stronger surroundings and slip at high angles to 1 and models of stress rotation across the thickness of the brittle crust, with moderately plunging 1 near the brittle-plastic transition, provided that some mechanism allows the faults to propagate through the brittle crust at gentle dips as the footwalls are exhumed. Paleo- 1 vectors oriented at moderate angles to the faults are sparse and may reflect early damage formed in the midcrust, while the angle between 1 and the detachment was moderate or during along-strike LANF or earthquake rupture propagation. Coulomb plasticity due to granular flow, which predicts faults at ~45° to 1 , is not well supported because many paleo- 1 vectors with moderate angles to the LANFs are from fractures below the cataclastic fault cores. Our results are inconsistent with "weak-sandwich" models that predict reorientation of 1 to low angles (~30°) to the fault within the damage zone and/or fault core due to local pore-fluid pressure or elasticity changes. Fracturing due to slip on non-planar faults is generally consistent with our paleostress results. However, the roughness of the LANFs studied is not known, but they may have very low roughness. The stress state used in this wavy-fault model to constrain the expected damage region is nearly identical to that inferred in the strong-sandwich model from field measurements. Fractures in the damage zone probably do not record up-dip fault or earthquake rupture propagation, which is expected especially for earthquake propagation, but along-strike propagation may have controlled fracturing at some sites. Some paleostress fields are probably related to folding of the detachments about slip-parallel axes.
    Electronic ISSN: 1553-040X
    Topics: Geosciences
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  • 10
    Publication Date: 2013-04-01
    Print ISSN: 0016-7037
    Electronic ISSN: 1872-9533
    Topics: Chemistry and Pharmacology , Geosciences
    Published by Elsevier
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