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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 70 (1999), S. 2719-2727 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A novel multiwavelength analysis of the radiation emitted by a hot Lambertian surface is presented allowing a reliable measurement of its surface temperature even in the presence of interfering external light sources. For the separation of thermally emitted and reflected external radiation, an accurate knowledge of the spectral emittance/reflectance of the sample is required. In our procedure, this quantity is determined in situ by performing a second measurement with additional light, e.g., from a strong electric flash. The strength of the flash and the relative spectrum of the interfering external radiation are probed with a cooled Lambertian reflectance reference near the sample. In a first step, the spectral reflectance of the sample is determined from spectra recorded with and without flash. The temperature and the total incoming irradiance are then obtained from a least-square fit of the input spectra with an analytical model of the emitted thermal plus the superimposed reflected external radiation. The method delivers also estimates for the statistical accuracy of the measured temperature and irradiance values. It causes no problem to measure temperatures through a window of sufficient optical quality and effects of absorbing gases or vapors may be minimized by an appropriate choice of the spectral intervals used for the analysis. In order to indicate statistical and systematic errors of the method under different operating conditions, extensive numerical simulations were performed. They reveal that a good statistical accuracy of the recorded spectra is crucial for a proper separation of the emitted from the reflected external radiation if one part dominates. In contrast, this separation is not affected by an erroneous calibration of the optical detection system. Finally, the question is discussed if one can dispense with the flash. Without external radiation, the "no-flash" method is equivalent to quotient pyrometry and subject to the same principal limitations. With external radiation, reasonably accurate temperatures can be expected only if thermal radiation clearly dominates or if emittance values are available from other sources. © 1999 American Institute of Physics.
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  • 2
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] A camera consisting of 109 fast photomultipliers with a pixel size of 0.25° at the 10-metre reflector at the Fred Lawrence Whipple Observatory1'2 images Cherenkov radiation from air showers. Image processing techniques refined using detailed Monte Carlo simulations2"4 and frequent observations ...
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 56 (1993), S. 363-366 
    ISSN: 1432-0649
    Keywords: 78.55 ; 82.50
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The temperature dependence of the luminescence quantum yield of powdered titaniumdioxide in vacuum, nitrogen, and water vapor, respectively, was measured in the temperature range 300 K to 800 K. The observed luminescence is attributed to luminescence from surface states. We find that the luminescence is thermally quenched, as predicted by a simple model. Furthermore, the luminescence is shifted towards shorter wavelengths with increasing temperature. We also observed that the luminescence in vacuum is weakly quenched in the presence of nitrogen or water vapor.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 60 (1995), S. 581-587 
    ISSN: 1432-0630
    Keywords: PACS82.40; 78.65
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract. Conversion of solar energy into chemical fuels has been a field of intense research for many years. It is usually attempted as a thermochemical reaction under highly concentrated solar irradiation, e.g. in a solar furnace. Special interest has been addressed to the question of whether concentrated light drives the reaction differently than heat. One effect of irradiation might be a decrease of the reaction temperature. To observe such an influence it is important to monitor the chemical process and the surface temperature of the sample under irradiation. In this paper we propose a method to measure the temperature, the irradiation and the reflectivity/emissivity distribution on an irradiated sample surface simultaneously. We first outline the computational background of the method and discuss its accuracy. We then report on laboratory measurements as well as on experiments performed in a solar furnace.
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 60 (1995), S. 581-587 
    ISSN: 1432-0630
    Keywords: 82.40 ; 78.65
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Conversion of solar energy into chemical fuels has been a field of intense research for many years. It is usually attempted as a thermochemical reaction under highly concentrated solar irradiation, e.g. in a solar furnace. Special interest has been addressed to the question of whether concentrated light drives the reaction differently than heat. One effect of irradiation might be a decrease of the reaction temperature. To observe such an influence it is important to monitor the chemical process and the surface temperature of the sample under irradiation. In this paper we propose a method to measure the temperature, the irradiation and the reflectivity/emissivity distribution on an irradiated sample surface simultaneously. We first outline the computational background of the method and discuss its accuracy. We then report on laboratory measurements as well as on experiments performed in a solar furnace.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 64 (1996), S. 109-113 
    ISSN: 1432-0630
    Keywords: PACS82.40; 82.50
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract. Direct conversion of solar radiation into useful, storable and transportable chemical products is the primary goal of solar chemistry. In this paper we discuss some fundamental aspects of photochemistry at elevated temperatures. We show that luminescence can serve as an indicator of the potential use of a system as a photoconverter. As an example we present experimental data on the chemical potential and on the lifetime of the excited states of ZnO. The low luminescence quantum yield together with a lifetime of about 200 ps indicate that an efficient photochemical conversion on ZnO is highly improbable. We believe this to be a general feature of chemical systems based on a semiconductor photocatalyst, in particular of photoreactions at a solid/gas interface.
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  • 7
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The very-high-energy y-ray telescope10 at the Whipple Observatory images Cerenkov light from air showers on a two-dimensional array of 109 fast photomultipliers with a pixel size of 0.25°. Monte Carlo simulations13'14 and repeated observations of the Crab Nebula15'16 demonstrate that the ...
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 61 (2000), S. 1005-1011 
    ISSN: 1572-8943
    Keywords: activation energy ; modulated TG ; model free kinetics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Recently, model free kinetic analysis of sinusoidal modulated TG-curves has been presented. In this contribution we compare the activation energies resulting from model free analysis of modulated TG-curves and from Vyazovkin's model free kinetic analysis of non-modulated TG-curves. We used polytetrafluorethylene and manganese oxide as samples. As a result we find, that both methods deliver similar activation energies for polytetrafluorethylene. However, the activation energies of manganese oxide deviate substantially. The main purpose of kinetic analysis is its potential for predictions of the temporal behavior of materials under certain thermal conditions. Analysis of modulated TG-curves allows a model free determination of the temperature dependence of the activation energy. However, in order to make predictions, one still has to rely on kinetic models such as e.g. first order kinetics. This is in contrast to Vyazovkin's approach, which allows a model free description of kinetic processes in terms of a conversion dependent activation energy. This function can then be used to make kinetic predictions without any further assumptions with respect to reaction models. In this paper we further discuss this fundamental difference.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 61 (2000), S. 91-98 
    ISSN: 1572-8943
    Keywords: DSC ; heat flow calibration ; temperature calibration
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Thermoanalytical instruments are extensively used in R&D as well as in industrial quality control. A quantitative analysis of the data of a thermoanalytical measurement requires a careful calibration of the instrument. In differential scanning calorimetry (DSC) the quantities that have to be calibrated are the temperature and the heat flow. These two quantities are usually calibrated by evaluating melting or solid-solid transitions of some reference materials with well known transition enthalpies and temperatures. In this contribution we investigate temperature and heat flow calibration in the temperature range between −100 and 160°C. We included 9 different samples for the analysis and established some general rules for the calibration process. As a result we found that with a well calibrated instrument the heat flow can be measured with 90% confidence to about ± 3% accuracy in this temperature range. With respect to temperature calibration we find that accuracies of ±0.8°C (90% confidence) may be expected. These values represent general accuracy limitations of DSC’s due to varying heat transfer conditions within the samples.
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  • 10
    ISSN: 1434-6052
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The combined analysis of the final event set of data on neutrino interactions inside the detector, upward going stopping muons and horizontal muons recorded in the Fréjus experiment is presented. The absolute atmospheric neutrino spectra in the energy range $$320{\rm M}eV〈 E_{v_e }〈 30GeV$$ for electron neutrinos and $$320{\rm M}eV〈 E_{v_\mu }〈 30GeV$$ for muon neutrinos are determined. Based on the parameterization of Volkova for thev µ a spectral index of γ=2.66±0.05 is obtained from the ratio of horizontal muons over upward going stopping muons and from the measurement of the energy loss of horizontal muons inside the detector. The neutrino spectra are compared with various flux calculations. They do not show any evidence for neutrino oscillations in agreement with earlier analyses of the Fréjus data.
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