ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
In this work we present a theoretical and experimental study of the i 3Π−g→b 3∑+u transition dipole moment in molecular hydrogen. By means of translational spectroscopy the functional dependence on internuclear distance of the transition dipole moment was directly probed. Selective excitation of the i 3Π−g, N=1 level, being unaffected by rotational couplings with other 3d singly excited states, allows for straightforward comparison with ab initio calculations. Excellent agreement is found.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.458774
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