ISSN:
0887-624X
Keywords:
N-Substituted maleimide
;
monomer reactivity ratios
;
Q and e values
;
thermal stability
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Three types of novel N-[4-(N′-substituted aminocarbonyl)phenyl] maleimide (RPhMI: N-substituent (R) = phenyl, cyclohexyl, and cyclododecyl) were synthesized and homopolymerized under several conditions. In the copolymerizations of RPhMI (M1) with styrene (ST; M2) or methyl methacrylate (MMA; M2), monomer reactivity ratios and Alfrey-Price Q, e values were determined. All homopolymers decomposed without softening and melting points. The initial degradation temperatures (Td) of poly(RPhMI)s were over 320°C. The glass transition temperatures (Tg) of RPhMI copolymers were much higher than those of N-phenylmaleimide (PhMI)-ST, PhMI-MMA, N-cyclohexylmaleimide (CHMI)-ST, and CHMI-MMA copolymers. Thermal stability of the terpolymers of RPhMI with ST and acrylonitrile (AN) was higher than that of ST-AN copolymers, i.e., AS resin. © 1998 John Wiley & Sons, Inc. J. Polym. Sci. A Polym. Chem. 36: 2001-2012, 1998
Additional Material:
12 Ill.
Type of Medium:
Electronic Resource
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