ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Disproportionation-combination rate constant ratios, kd/kc, have been determined for R + RCH2CHCl and for the auto disproportionation-combination of RCH2CHCl radicals, R = CF3, C2F5, and C3F7. The kd/kc for R = CF3 and to a lesser degree for R = C2F5 and C3F7 were very sensitive to the surface/volume ratio of the reaction vessel suggesting a heterogeneous component for disproportionation.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550190503
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