ISSN:
1572-8943
Keywords:
bismuth
;
calorimetry
;
dithiocarbamate
;
enthalpy
;
phosphorous
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The standard molar enthalpy of formation of crystalline di-isobutyldithiocarbamate complexes of P, As, Sb and Bi(III) has been derived by solution calorimetry at 298.15 K. The corresponding standard molar enthalpies of sublimation were estimated by means of differential scanning calorimetry. From the standard molar enthalpies of formation of the gaseous chelates the homolytic and heterolytic mean metal-sulphur bond-dissociation enthalpies were calculated.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01996751
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