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  • 1
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    In:  EPIC3The Ocean Carbon Cycle at a Time of Change: Synthesis and Vulnerabilities, 14-16 September 2011, UNESCO, Paris, France, 2011-09-14
    Publication Date: 2019-07-17
    Repository Name: EPIC Alfred Wegener Institut
    Type: Conference , notRev
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  • 2
    Publication Date: 2019-07-17
    Description: The Southern Ocean (44–75°S) plays a critical role in the global carbon cycle, yet remains one of the most poorly sampled ocean regions. Different approaches have been used to estimate sea–air CO2 fluxes in this region: synthesis of surface ocean observations, ocean biogeochemical models, and atmospheric and ocean inversions. As part of the RECCAP (REgional Carbon Cycle Assessment and Processes) project, we combine these different approaches to quantify and assess the magnitude and variability in Southern Ocean sea–air CO2 fluxes between 1990–2009. Using all models and inversions (26), the integrated median annual sea–air CO2 flux of −0.42 ± 0.07 PgC yr−1 for the 44–75°S region, is consistent with the −0.27 ± 0.13 PgC yr−1 calculated using surface observations. The circumpolar region south of 58°S has a small net annual flux (model and inversion median: −0.04 ± 0.07 PgC yr−1 and observations: +0.04 ± 0.02 PgC yr−1), with most of the net annual flux located in the 44 to 58°S circumpolar band (model and inversion median: −0.36 ± 0.09 PgC yr−1 and observations: −0.35 ± 0.09 PgC yr−1). Seasonally, in the 44–58°S region, the median of 5 ocean biogeochemical models captures the observed sea–air CO2 flux seasonal cycle, while the median of 11 atmospheric inversions shows little seasonal change in the net flux. South of 58°S, neither atmospheric inversions nor ocean biogeochemical models reproduce the phase and amplitude of the observed seasonal sea–air CO2 flux, particularly in the AustralWinter. Importantly, no individual atmospheric inversion or ocean biogeochemical model is capable of reproducing both the observed annual mean uptake and the observed seasonal cycle. This raises concerns about projecting future changes in Southern Ocean CO2 fluxes. The median interannual variability from atmospheric inversions and ocean biogeochemical models is substantial in the Southern Ocean; up to 25% of the annual mean flux, with 25% of this interannual variability attributed to the region south of 58°S. Resolving long-term trends is difficult due to the large interannual variability and short time frame (1990–2009) of this study; this is particularly evident from the large spread in trends from inversions and ocean biogeochemical models. Nevertheless, in the period 1990–2009 ocean biogeochemical models do show increasing oceanic uptake consistent with the expected increase of −0.05 PgC yr−1 decade−1. In contrast, atmospheric inversions suggest little change in the strength of the CO2 sink broadly consistent with the results of Le Quéré et al. (2007).
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 3
    Publication Date: 2022-05-25
    Description: © The Author(s), 2013. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Biogeosciences 19 (2013): 4037-4054, doi:10.5194/bg-10-4037-2013.
    Description: The Southern Ocean (44–75° S) plays a critical role in the global carbon cycle, yet remains one of the most poorly sampled ocean regions. Different approaches have been used to estimate sea–air CO2 fluxes in this region: synthesis of surface ocean observations, ocean biogeochemical models, and atmospheric and ocean inversions. As part of the RECCAP (REgional Carbon Cycle Assessment and Processes) project, we combine these different approaches to quantify and assess the magnitude and variability in Southern Ocean sea–air CO2 fluxes between 1990–2009. Using all models and inversions (26), the integrated median annual sea–air CO2 flux of −0.42 ± 0.07 Pg C yr−1 for the 44–75° S region, is consistent with the −0.27 ± 0.13 Pg C yr−1 calculated using surface observations. The circumpolar region south of 58° S has a small net annual flux (model and inversion median: −0.04 ± 0.07 Pg C yr−1 and observations: +0.04 ± 0.02 Pg C yr−1), with most of the net annual flux located in the 44 to 58° S circumpolar band (model and inversion median: −0.36 ± 0.09 Pg C yr−1 and observations: −0.35 ± 0.09 Pg C yr−1). Seasonally, in the 44–58° S region, the median of 5 ocean biogeochemical models captures the observed sea–air CO2 flux seasonal cycle, while the median of 11 atmospheric inversions shows little seasonal change in the net flux. South of 58° S, neither atmospheric inversions nor ocean biogeochemical models reproduce the phase and amplitude of the observed seasonal sea–air CO2 flux, particularly in the Austral Winter. Importantly, no individual atmospheric inversion or ocean biogeochemical model is capable of reproducing both the observed annual mean uptake and the observed seasonal cycle. This raises concerns about projecting future changes in Southern Ocean CO2 fluxes. The median interannual variability from atmospheric inversions and ocean biogeochemical models is substantial in the Southern Ocean; up to 25% of the annual mean flux, with 25% of this interannual variability attributed to the region south of 58° S. Resolving long-term trends is difficult due to the large interannual variability and short time frame (1990–2009) of this study; this is particularly evident from the large spread in trends from inversions and ocean biogeochemical models. Nevertheless, in the period 1990–2009 ocean biogeochemical models do show increasing oceanic uptake consistent with the expected increase of −0.05 Pg C yr−1 decade−1. In contrast, atmospheric inversions suggest little change in the strength of the CO2 sink broadly consistent with the results of Le Quéré et al. (2007).
    Description: A. Lenton, B. Tilbrook, R. J. Matear and R. M. Law were funded by the Australian Climate Change Science Program and theWealth from Oceans National Research Flagship. S. C. Doney acknowledges support from the National Science Foundation (OPP-0823101), T. Takahashi is supported by grants from United States NOAA (NA08OAR4320754) and National Science Foundation (ANT 06-36879). D. Baker, N. Gruber, M. Hoppema, N. Metzl acknowledge the support of EU FP7 project CARBOCHANGE (264879). S. C. Doney acknowledges support from the National Science Foundation (OPP-0823101). N. S. Lovenduski is grateful for support from NSF (OCE-1155240) and NOAA (NA12OAR4310058). This study is also a contribution to the international IMBER/SOLAS Projects. C. Sweeney acknowledges support from the United States NOAA (NA12OAR4310058) and National Science Foundation (0944761).
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 58 (1985), S. 3708-3711 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A new type of dichroic reflector has been developed for the far-infrared region of the spectrum, based on n-type germanium with a diffused conduction layer. A 111-axis single-crystal plate of 40-Ω cm optical-grade germanium was implanted with 5×1014 As+ ions/cm2 by ion bombardment at 200 keV; the donor impurity ions were subsequently diffused into the substrate at a temperature of 850 °C (held for 20 h). The measured power-reflection spectrum displayed a shallow minimum at ∼70 cm−1, rising steeply below 50 cm−1 to reach 80% reflectivity at 10 cm−1. Computer modeling of the infrared reflectance of a thermally diffused conducting layer in n-type germanium—with the assumption of Conwell–Weisskopf mobility variation for the conduction electrons—gave an excellent fit to the observed reflection spectrum for an integrated column density of 1014 cm−2 and 10-μm half width, the latter being in good agreement with the value (square root of)Dt=11 μm calculated for thermal diffusion under the conditions indicated.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Biochemistry 12 (1973), S. 3244-3253 
    ISSN: 1520-4995
    Source: ACS Legacy Archives
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Biochemistry 12 (1973), S. 3254-3259 
    ISSN: 1520-4995
    Source: ACS Legacy Archives
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 0167-7799
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Enzyme and Microbial Technology 16 (1994), S. 223-228 
    ISSN: 0141-0229
    Keywords: NH"4^+, sucrose inhibition ; Scleroglucan ; supplemented batch fermentation
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Applied microbiology and biotechnology 43 (1995), S. 440-444 
    ISSN: 1432-0614
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Abstract The effective diffusivity of O2 inside immobilised cell particles has been much discussed. Most reported estimates are based on fitting a mass-transfer reaction model to measured total oxygen uptake rates. The particle diameter has the largest single influence in such models, but its accurate measurement has probably recieved insufficient attention. We have studied sorbitol and glucose oxidation by cells of Gluconobacter suboxydans entrapped in calcium alginate gel beads. These beads were found to shrink rapidly in air, so that size measurement under water is essential. By comparison with rigid particles of similar known size, it was shown that measurement of the microscopic image gives a systematic underestimate. In consequence, the fitted oxygen diffusivity will be around 20% too low. Careful attention to size measurement gave good agreement between diffusivity estimates from beads with different mean sizes and cell loadings, with a best value of 2.51 × 109 m2s−1, 92% of the value for pure water. The estimated diffusivity is not significantly affected by a distribution of bead sizes with up to 10% standard deviation about the same mean.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Applied microbiology and biotechnology 50 (1998), S. 291-298 
    ISSN: 1432-0614
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Abstract The inhibitory effects of elevated CO2 in submerged fermentation processes involving bacteria and yeasts have been extensively examined. However, until recently, there have been few similar studies involving filamentous fungi, despite the economic importance of this group of organisms. Many of the investigations that have been carried out have involved inappropriate simulation methods and, as a result, may have overestimated the morphogenetic and biochemical effects of elevated CO2 on filamentous fungi. Recent studies, involving continuous culture of Aspergillus niger and the use of computerised image analysis systems, have allowed a more detailed and accurate description of elevated CO2 inhibition and quantification of the subtler morphogenetic effects. A critical evaluation of the various experimental methods that have been used to simulate, at laboratory scale, what is assumed to occur in large-scale bioreactors is necessary. The review of simulation methods employed has much broader relevance to many other microbial and cell culture systems, emphasising the need to think about the appropriateness and relevance of experimental design.
    Type of Medium: Electronic Resource
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