ALBERT

Description: Continents are long-term storage sites for sedimentary carbonates. Global flare-ups in continental arc volcanism, when arc magmas intersect and interact with stored carbonates, thus have the potential for elevating the global baseline of deep Earth carbon inputs into the atmosphere, leading to long-lived greenhouse conditions. Decarbonation residues, known as skarns, are ubiquitously associated with the eroded remnants of ancient batholiths, attesting to the potential link between continental arc magmatism and enhanced global CO 2 inputs to the atmosphere.

Description: The Ash Mountain Complex (AMC) in the western Sierra Nevada batholith (SNB; California, USA) is an exposure of six compositionally diverse intrusive lithologies with clear crosscutting relationships that permit a focused investigation of magma source characteristics and the relative roles of petrogenetic processes on the evolution of the system. We use new field observations, zircon U-Pb dates, major and trace element data, and Sr-Nd-Pb isotopic data to develop a model that can be applied to similar SNB intrusive suites. Stage 1 units, emplaced ca. 105 Ma, consist of two gabbros, a gabbrodiorite, and a granite. Stage 2 and stage 3 units were emplaced ca. 104 Ma and ca. 103 Ma, respectively, and are granites. We suggest that stage 1 gabbroids were derived by partial melting of lithospheric mantle, whereas coeval felsic magmas were derived by partial melting of a mafic, juvenile crustal source. Stage 2 and stage 3 granitoids were derived from similar sources that generated stage 1 granitoids, but there was greater input from evolved crust. Fractionation and/or assimilation played only a minor role in system evolution. Past studies of SNB magmas have come to conflicting conclusions about the petrogenesis of intermediate magmas that dominate the batholith; we hypothesize that mafic and felsic end members of the AMC could represent end members in mixing processes that generate these magmas. The timing of emplacement of the AMC coincides with a transition of magmatic style in the SNB, from smaller volume magmatic suites with mixed mantle and crustal sources to larger volume magmatic suites derived from greater proportions of crust.

Description: Garnet from skarns exposed at Empire Mountain, Sierra Nevada (California, United States) batholith, have variable 18 O values including the lowest known 18 O values of skarn garnet (–4.0) in North America. Such values indicate that surface-derived meteoric water was a significant component of the fluid budget of the skarn-forming hydrothermal system, which developed in response to shallow emplacement (~3.3 km) of the 109 Ma quartz diorite of Empire Mountain. Values of 18 O, measured in situ across single garnet crystals by secondary ion mass spectrometry, vary considerably (up to 7) and sometimes abruptly, indicating variable mixing of meteoric, magmatic, and metamorphic water. Brecciation in the skarns and alteration of the Empire Mountain pluton suggests that fracture-enhanced permeability was a critical control on the depth to which surface waters penetrated to form skarns and later alter the pluton. Compared to other Sierran systems, much greater volumes of skarn rock suggest an exceptionally vigorous hydrothermal system that saw unusually high levels of decarbonation reaction progress, likely a consequence of the magma intruding relatively cold wallrocks inboard of the main locus of magmatism in the Sierran arc at that time.

Description: Rare earth element (REE) ore-bearing carbonatite dikes and a stock at Mountain Pass, California, are spatially associated with a suite of ultrapotassic plutonic rocks, and it has been proposed that the two are genetically related. This hypothesis is problematic, given that existing geochronological constraints indicate that the carbonatite is ~15–25 Myr younger than the ultrapotassic rocks, requiring alternative models for the formation of the REE ore-bearing carbonatite during a separate event and/or via a different mechanism. New laser ablation split-stream inductively coupled plasma mass spectrometry (LASS-ICP-MS) petrochronological data from ultrapotassic intrusive rocks from Mountain Pass yield titanite and zircon U–Pb dates from 1429 ± 10 to 1385 ± 18 Ma, expanding the age range of the ultrapotassic rocks in the complex by ~20 Myr. The ages of the youngest ultrapotassic rocks overlap monazite Th–Pb ages from a carbonatite dike and the main carbonatite ore body (1396 ± 16 and 1371 ± 10 Ma, respectively). The Hf isotope compositions of zircon in the ultrapotassic rocks are uniform, both within and between samples, with a weighted mean Hf i of 1·9 ± 0·2 (MSWD = 0·9), indicating derivation from a common, isotopically homogeneous source. In contrast, in situ Nd isotopic data for titanite in the ultrapotassic rocks are variable (Nd i = –3·5 to –12), suggesting variable contamination by an isotopically enriched source. The most primitive Nd i isotopic signatures, however, do overlap Nd i from monazite (Nd i = –2·8 ± 0·2) and bastnäsite (Nd i = –3·2 ± 0·3) in the ore-bearing carbonatite, suggesting derivation from a common source. The data presented here indicate that ultrapotassic magmatism occurred in up to three phases at Mountain Pass (~1425, ~1405, and ~1380 Ma). The latter two stages were coeval with carbonatite magmatism, revealing previously unrecognized synchronicity in ultrapotassic and carbonatite magmatism at Mountain Pass. Despite this temporal overlap, major and trace element geochemical data are inconsistent with derivation of the carbonatite and ultrapotassic rocks by liquid immiscibility or fractional crystallization from common parental magma. Instead, we propose that the carbonatite was generated as a primary melt from the same source as the ultrapotassic rocks, and that although it is unique, the Mountain Pass ultrapotassic and carbonatite suite is broadly similar to other alkaline silicate–carbonatite occurrences in which the two rock types were generated as separate mantle melts.

Description: The Cretaceous to early Paleogene (ca. 140–50 Ma) was characterized by a greenhouse baseline climate, driven by elevated concentrations of atmospheric CO 2 . Hypotheses for the elevated CO 2 concentrations invoke an increase in volcanic CO 2 production due to higher oceanic crust production rates, higher frequency of large igneous provinces, or increases in pelagic carbonate deposition, the last leading to enhanced carbonate subduction into the mantle source regions of arc volcanoes. However, these are not the only volcanic sources of CO 2 during this time interval. We show here that ocean-continent subduction zones, manifested as a global chain of continental arc volcanoes, were as much as 200% longer in the Cretaceous and early Paleogene than in the late Paleogene to present, when a cooler climate prevailed. In particular, many of these continental arcs, unlike island arcs, intersected ancient continental platform carbonates stored on the continental upper plate. We show that the greater length of Cretaceous–Paleogene continental arcs, specifically carbonate-intersecting arcs, could have increased global production of CO 2 by at least 3.7–5.5 times that of the present day. This magmatically driven crustal decarbonation flux of CO 2 through continental arcs exceeds that delivered by Cretaceous oceanic crust production, and was sufficient to drive Cretaceous–Paleogene greenhouse conditions. Thus, carbonate-intersecting continental arc volcanoes likely played an important role in driving greenhouse conditions in the Cretaceous–Paleogene. If so, the waning of North American and Eurasian continental arcs in the Late Cretaceous to early Paleogene, followed by a fundamental shift in western Pacific subduction zones ca. 52 Ma to an island arc–dominated regime, would have been manifested as a decline in global volcanic CO 2 production, prompting a return to an icehouse baseline in the Neogene. Our analysis leads us to speculate that long-term (〉50 m.y.) greenhouse-icehouse oscillations may be linked to fluctuations between continental- and island arc–dominated states. These tectonic fluctuations may result from large-scale changes in the nature of subduction zones, changes we speculate may be tied to the assembly and dispersal of continents. Specifically, dispersal of continents may drive the leading edge of continents to override subduction zones, resulting in continental arc volcanism, whereas assembly of continents or closing of large ocean basins may be manifested as large-scale slab rollback, resulting in the development of intraoceanic volcanic arcs. We suggest that greenhouse-icehouse oscillations are a natural consequence of plate tectonics operating in the presence of continental masses, serving as a large capacitor of carbonates that can be episodically purged during global flare-ups in continental arcs. Importantly, if the global crustal carbonate reservoir has grown with time, as might be expected because platform carbonates on continents do not generally subduct, the greenhouse-driving potential of continental arcs would have been small during the Archean, but would have increased in the Neoproterozoic and Phanerozoic after a significant reservoir of crustal carbonates had formed in response to the evolution of life and the growth of continents.

Description: Magmatism in the southern Grenville Province records a collisional and postcollisional history during the period 1.20–1.15 Ga in the Adirondack Lowlands (New York State, USA) and the Frontenac terrane (Ontario, Canada). The 1.20 Ga bimodal Antwerp-Rossie suite of the Adirondack Lowlands was produced by subduction in the Trans-Adirondack backarc basin. This was followed by intrusion of the 1.18 Ga alkalic to calc-alkalic Hermon granite, which may have been generated by melting of metasomatized mantle during collision of the Adirondack Lowlands and Frontenac terrane during the Shawinigan orogeny. The Hyde School gneiss plutons intruded the Adirondack Lowlands at 1.17 Ga, and Rockport granite intruded into the Adirondack Lowlands and Frontenac terrane, stitching the Black Lake shear zone, which marks the boundary between these terranes. Subsequent extensional collapse and lithospheric delamination caused voluminous anorthosite-mangerite-charnockite-granite plutonism. In the Frontenac terrane, this event is represented by the 1.18–1.15 Ga Frontenac suite, which is composed predominately of ferroan granitoids produced from melting of the lower crust by underplating mafic magmas. The Edwardsville, Honey Hill, and Beaver Creek plutons are newly recognized members of this suite in the Adirondack Lowlands. High oxygen isotope ratios of this suite in the central Frontenac terrane and western Adirondack Lowlands point to the presence of underthrust altered oceanic rocks in the lower crust. Oxygen isotopes of the Frontenac suite in both terranes preclude its derivation from mantle melts alone.

Description: The Mineral King pendant in the Sierra Nevada batholith (California, USA) contains at least four rhyolite units that record high-silica volcanism during magmatic lulls in the Sierran magmatic arc. U-Th-Pb, trace element (single crystal spot analyses via sensitive high-resolution ion microprobe–reverse geometry, SHRIMP-RG), and bulk oxygen isotope analyses of zircon from these units provide a record of the age and compositional properties of the magmas that is not available from whole-rock analysis because of intense hydrothermal alteration of the pendant. U-Pb spot ages reveal that the Mineral King rhyolites are from two periods, the Early Jurassic (197 Ma) and the Early Cretaceous (134–136 Ma). These two rhyolite packages have zircons with distinct compositional trends for trace elements and 18 O; the Early Jurassic rhyolite shows less evidence of crustal influences on the rhyolites and the Early Cretaceous rhyolite shows evidence of increasing crustal influences and crystal recycling. These rhyolites capture evidence of magmatism during two periods of low magmatic flux in the Sierran Arc; however, they still show that magmas were derived from interactions of maturing continental crust, increasing from the Early to Late Jurassic. This finding likely reflects the transition of the North America margin from one of docking island arcs in the Early Jurassic to one of a more mature continental arc in the Early Cretaceous. This also shows the utility in examining zircon spot ages combined with trace element and bulk isotopic composition to unlock the petrogenetic history of altered volcanic rocks.