ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The coordination around the Cu-metal centre in the title compound, [CuBr(C15H24N2S)(C18H15P)2], is distorted tetrahedral with bond lengths Cu—S 2.367 (1), Cu—Br 2.469 (1), Cu—P(1) 2.279 (2) and Cu—P(2) 2.284 (2) Å, and bond angles S—Cu—Br 111.86 (5), S—Cu—P(1) 111.28 (6), S—Cu—P(2) 98.01 (6), Br—Cu—P(1) 103.08 (5), Br—Cu—P(2) 108.60 (5) and P(1)—Cu—P(2) 124.11 (6)°. The H atom of the NH group is intramolecularly hydrogen bonded to the Br atom, with an NH...Br distance of 2.411 Å.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270195006500
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